Investigation of the New Room Temperature Ionic Liquid of Al(NO3)3.9H2O with Urea CO(NH2)2 Nidhal M. Hasan | Hadi M.A.Abood | Mahasin F. Alias

Main Article Content

Baghdad Science Journal

Abstract

Mixing aluminum nitrate nonahydrate with urea produced room temperatures clear colorless ionic liquid with lowest freezing temperature at (1: 1.2) mole ratio respectively. Freezing point phase diagram was determined and density, viscosity and conductivity were measured at room temperature. It showed physical properties similar to other ionic liquids. FT-IR,UV-Vis, 1H NMR and 13C NMR were used to study the interaction between its species where - CO ??? Al- bond was suggested and basic ion [Al(NO3)4]? and acidic ions [Al(NO3)2. xU]+ were proposed. Water molecule believed to interact with both ions. Redox potential was determined to be about 2 Volt from – 0.6 to + 1.4 Volt with thermal stability up to 326 ?.

Downloads

Download data is not yet available.

Article Details

How to Cite
1.
Journal BS. Investigation of the New Room Temperature Ionic Liquid of Al(NO3)3.9H2O with Urea CO(NH2)2. BSJ [Internet]. 4Sep.2016 [cited 12Aug.2020];13(3):0489. Available from: http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2295
Section
article

Most read articles by the same author(s)

1 2 3 4 5 6 7 8 9 10 > >>