Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand

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Muna A. Hadi
Layla A. Mohammad
Amar A. Hussein

Abstract

The New Schiff base ligand 4,4'-[(1,1'-Biphenyl)-4,4'-diyl,bis-(azo)-bis-[2-Salicylidene thiosemicarbazide](HL)(BASTSC)and its complexes with Co(II), Ni(II), and Cu(II) were prepared and characterized by elemental analysis, electronic, FTIR, magnetic susceptibility measurements. The analytical and spectral data showed, the stiochiometry of the complexes to be 1:1 (metal: ligand). FTIR spectral data showed that the ligand behaves as dibasic hexadentate molecule with (N, S, O) donor sequence towards metal ions. The octahedral geometry for Co(II), Ni(II), and Cu(II) complexes and non electrolyte behavior was suggested according to the analysis data.

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Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand. Baghdad Sci.J [Internet]. 2014 Mar. 2 [cited 2024 Mar. 28];11(1):158-65. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/1546
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How to Cite

1.
Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand. Baghdad Sci.J [Internet]. 2014 Mar. 2 [cited 2024 Mar. 28];11(1):158-65. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/1546

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