Synthesis, characterization and bioactivity Study from azo – ligand derived frommethyl-2-amino benzoatewith some metal ions

Authors

DOI:

https://doi.org/10.21123/bsj.2022.6584

Keywords:

Bioactivity, complexes, ethanol, Molar conductivity, Transition Metals

Abstract

A Ligand (ECA) methyl 2-((1-cyano-2-ethoxy-2-oxoethyl)diazenyl)benzoate with metals of (Co2+, Ni2+, Cu2+) were prepared and characterization using H-NMR, atomic absorption spectroscopy, ultra violet (UV) visible, magnetic moments measurements, bioactivity, and Molar conductivity measurements in soluble ethanol. Complexes have been prepared using a general formula which was suggested as [M (ECA)2] Cl2, where M = (Cobalt(II), Nickel(II) and Copper(II), the geometry shape of the complexes is octahedral.

References

Geersing A, Ségaud N, Monique G P, Van der Wijst

M G, Rots M G , Roelfes G, Importance of metalion exchange for the biological activity of

coordination complexes of the biomimetic ligand

N4Py. Inorg.Chem. 2018; 57(13), 7748-7756.

Yousif Q I, Alia F M ,Synthesis,Strctural study

Antimicrobial activity and theoretical treatment of

d-metal complexes involiving schuff base of

piperonal derivative AJPS. 2018;13(1):1-13

Sodhi R K, Paul S , Metal Complexes in Medicine an

Overview and Update from Drug Design

Perspective. Cancer Ther Oncol Int J. 2019; 14(1),

-32.

Karwan O A, Hikmat A M, Synthesis,

Characterization, and Antibacterial Activity of Ni(II),

Pd(II), and Pt(II) Complexes with 2-

benzoylthiobenzimidazole. Zanco J Pure Appl .2020;

(2): 15-23.

Ana A B, Supramolecular Assembly of Benzimidazole

Derivatives and Applications., DOI:

5772/intechopen . 2019; 85333 (Review).

Husain A, Varshney M, Rashid M , Akhter A,

benzimidazole : A Valuable Insight into the recent

Advances and Biological Activities J.Pharm Rese.

; 4(2) ,413-419.

Waleed A , Israa H , Synthesis and Spectral Analysis

of Mn(II), Cu(II) Ni (II) and Cd(II) Complexes with

Mixed Ligand containing 1,10- phenanthroline and

Schiff base derived of 4- aminoantipyrine. Baghdad

Sci J . 2014 ; 11(4): 1519-1521.

Hawraa M, Maha AL-T , Israa H,Muna S , Surfactant

Cloud Point Extraction as a Procedure of

Preconcentrating for Metoclopramide Determination

Using Spectro Analytical Technique, Baghdad Sci J .

; 17(1): 57-65.

Mahasn F A , Doaa H M , 2015.Synthesis , Spectral

Study and Theoretical Treatment of Mixing

Benzimidazole Derivatives and Phenanthroline

Complexe.ANJS.2016;19 :6056-6068.

A-Hammdani A, Al –Zoubi W,New metal complexes

N3 tridentate ligand Synthesis ,spectral studies and

biological activity .Spectrochim Acta A Mol Biomol

Spectrosc. 2016; 137: 75-89.

Anamm M, Sinan M, Rehab A, Muna A,

Synthesizing Structure and Characterizing

Bioactivites of Cr (III), La(III) and Ce(III)Complexes

with Nitrogen ,Oxygen and Sulpher donor bidentate

Schiff base ligands. Baghdad Sci.J. 2021; 18 (4)

Devi O,Basavaiah K, Vinay K, Revanasiddappa H,

Sensitive spectrophotometric determination of

metoclopramide hydrochloric in dosage forms and

spiked human urine using vanilline .Arab J Chem.

; 9: S64-S72.

Sahar S H, Nidhal M H , Shaymaa RB, Asmaa MS ,

Biological Evalution and Therotical Studay of Bidentate Ligand for Amoxicilline Derivative with

Some Metal Ions .Baghdad Sci.J. 2021; 18 (4)1269.

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Published

2023-02-01

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1.
Synthesis, characterization and bioactivity Study from azo – ligand derived frommethyl-2-amino benzoatewith some metal ions. Baghdad Sci.J [Internet]. 2023 Feb. 1 [cited 2024 Nov. 24];20(1):0114. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6584

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