Abstract
New series of metal ions complexes have been prepared from the new ligand 1,5-Dimethyl-4-(5-oxohexan-2-ylideneamino)-2-phenyl-1H-pyrazol-3 (2H)-one derived from 2,5-hexandione and 4-aminophenazone. Then, its V(IV), Ni(II), Cu(II), Pd(II), Re(V) and Pt(IV) complexes were prepared. The compounds have been characterized by FT-IR, UV-Vis, mass and 1H and 13C-NMR spectra, TGA curve, magnetic moment, elemental microanalyses (C.H.N.O.), chloride containing, Atomic absorption and molar conductance. HyperChem-8 program has been used to predict structural geometries of compounds in gas phase, the heat of formation, (binding, total and electronic energy) and dipole moment at 298 K.
Keywords
Schiff base Ligands, 2, 5-Hexandione, Metal Complexes.
Article Type
Article
How to Cite this Article
Al-Hamdani, Abbas Ali Salih and Hamoodah, Rehab Ghalib
(2016)
"Transition Metal Complexes with Tridentate Ligand: Preparation, Spectroscopic Characterization, Thermal Analysis and Structural Studies,"
Baghdad Science Journal: Vol. 13:
Iss.
4, Article 13.
DOI: https://doi.org/10.21123/bsj.2016.13.4.0770
