Synthesis and Characterization of (Fe(II),Co(II),Ni(II) and Cu(II)) Complexes with Schiff Base derived from [benzoyl hydrazine] with [benzyl mono oxime]

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Ahmad Thabet Numan
Suhad Shakir Muhmmed
Eman I. Abdulkarim

Abstract

The reaction of [Benzoyl hydrazine] with [Diphenyl mono oxime] and Glacial acetic acid was carried out in methanol gave a new tridentate ligand [Benzoic acid (2-hydroxyimino- 1, 2-diphyneylethylidene) - hydrazide]. This ligand was reacted with some metal ions (Fe(II), Co(II), Ni(II), and Cu(II)) in methanol with (1:1) metal : ligand ratio to give a series of new complexes of the general formula [M(L)Cl2.H2O], where M= Fe(11), Co(11), Ni(11) and Cu(11).
All compounds were characterized by spectroscopic methods (I.R, UV-Vis), elemental microanalysis (C.H.N), atomic absorption, magnetic susceptibility, and conductivity measurements. From the obtained data the proposed molecular structures were suggested for the complexes of Fe (II), Co (II), Ni (II) and Cu (II) are of geometric octahedral.

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Synthesis and Characterization of (Fe(II),Co(II),Ni(II) and Cu(II)) Complexes with Schiff Base derived from [benzoyl hydrazine] with [benzyl mono oxime]. Baghdad Sci.J [Internet]. 2009 Dec. 6 [cited 2024 Dec. 25];6(4):748-56. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/1040
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How to Cite

1.
Synthesis and Characterization of (Fe(II),Co(II),Ni(II) and Cu(II)) Complexes with Schiff Base derived from [benzoyl hydrazine] with [benzyl mono oxime]. Baghdad Sci.J [Internet]. 2009 Dec. 6 [cited 2024 Dec. 25];6(4):748-56. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/1040

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