Synthesis, Characterization and Study of Thermal Properties of New Silicone Polymers and Their Nanocomposites
DOI:
https://doi.org/10.21123/bsj.2024.10810Keywords:
Dichlorodimethylsilane, Nanocomposite, Silicone polymer, Silver nanoparticles, Thermal analysis.Abstract
This study aims to synthesize a new class of silicon polymers P1-P4 were synthesized based on dichlorodimethylsilane (DCDMS) with some organic compounds containing terminal hydroxyl groups were synthesized for the first time[M1-M4] via condensation polymerization .Also, their nanocomposites P′1-P′4 were prepared in the presence of 0.7% the silver nanoparticles (Ag-NPs) using the solution casting method. The structures of all monomers and polymers were characterized by FTIR and 1H-NMR spectroscopy, which allowed to identify functional groups of monomers and silicone polymers. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) test were performed to analyze thermal behavior and effect of the presence of silver nanoparticles. The results of thermal analysis showed that the presence of phenyl rings demonstrated the thermal stability of pure silicon polymers, and the introduction of silver nanoparticles of 7% weight showed an improvement in the thermal performance of nanocomposites P′1-P′4 compared to pure silicon polymers. Which means that the temperature for weight loss (TGA) was higher for the most nanocomposite P′1-P′4, where the TGA for polymers increased from 127 for polymer P2 to 196 for its nanocomposite P′2, this may be due to filling the free voids between the Polymerized chains by silver nanoparticles. The silver nanoparticles were characterized and analyzed using X-ray diffraction XRD and scanning electron microscopy. The X-ray study showed the presence of silver nanoparticles and the average size of nanoparticles ranged from 20 -30 nanometers. The surface study was performed using scanning electron microscopy which showed a fairly uniform shape for the silver nanocomposites.
Received 28/01/2024
Revised 26/05/2024
Accepted 28/05/2024
Published Online First 20/10/2024
References
Coyolicaltzin PG, Aurelio RH, Gustavo RP, Alejandro AS, Andres AC, Gerardo GG. et al. Synthesis and Characterization of the Starch/silicone Oil Composite and Elaboration of its Films. Silicon. 2022; 14(8): 4157-4167. https://doi.org/10.1007/s12633-021-01209-x
Guodong Su, Aili W, Mingming Zh, Hengbo Y, Guoxi Wang. Selective Synthesis of Triethoxysilane and Tetraethoxysilane through Direct Reaction between Ethanol and Silicon Catalyzed by CuCl and Metallic Cu0 Nanoparticles in Fixed-bed Reactor. Silicon. 2022; 14(2): 573–580. https://doi.org/10.1007/s12633-020-00830-6
Navarut P, Kasimanat V, Makoto O. Heterostructural transformation of mesoporous silica–titania hybrids. Sci Rep. 2021; 11(3210): 1-12. https://doi.org/10.1038/s41598-020-80584-8
Chayma O, Manel E, Giuseppe B, Sonia A, Antonio. S, Zouhaier A. Structural, vibrational, optical properties and theoretical studies of new noncentrosymmetric material: Bis (2-Amino-5-(methylthio)-1,3,4-thiadiazol-3-ium) Pentachloroantimonate. J Mol Struct. 2021; 1240(130538): 1-14. https://doi.org/10.1016/j.molstruc.2021.130538
Hiroki I, Shuta H, Shigeru S. Skillful Control of Dispersion and 3D Network Structures: Advances in Functional Organic–Inorganic Nano-Hybrid Materials Prepared Using the Sol-Gel Method. Polymers. 2022; 14(16): 3247. https://doi.org/10.3390/polym14163247
Arunkumar L, Vaibhav M, Manjunath KP, Sangappa KG. Synthesis, characterization and studies of BaFe2O4/PMMA nanocomposite. Polym Bull. 2021; 78(4): 5905–5921. https://doi.org/10.1007/s00289-020-03403-0
Rui H, Jinshui Y, Qiuhong M, Dan P, Hui Z, Zhizhou Y. Study on the Synthesis and Thermal Stability of Silicone Resin Containing Trifluorovinyl Ether Groups. Polymers. 2020; 12(10): 2284. https://doi.org/10.3390/polym12102284
Chenwei S, Dan W, Caihong X, Wenyi Ch, Zongbo Z. Comparative study on polysilazane and silicone resins as high-temperature-resistant coatings. High Perfrom Polym. 2022; 34(4): 474 -486. https://doi.org/10.1177/09540083211069041
Elizaveta S, Mati D, Valdek M, Sergei B. Comparative study of perhydropolysilazane protective films. Surf Eng. 2022; 38(7): 769-777. https://doi.org/10.1080/02670844.2022.2155445
Ying Z, Ralf G, Wei L, Farhan J, Ralf R. Evaluation of mechanical properties and hydrophobicity of room-temperature, moisture-curable polysilazane coatings. J Appl Polym. Sci. 2021; 138(21): 50469. https://doi.org/10.1002/app.50469
Amira AM, Abeer AN, Sadeek AS, Hazem SE. Synthesis and Spectral, Thermal and Antimicrobial Investigation of Mixed LigandMetal Complexes of N-Salicylidene Anilineand 1,10-Phenanthroline. Compounds. 2023; 3(1): 298–309. https://doi.org/10.3390/compounds3010022
Nisreen H Karam, Jumbad H Tomma, Ammar HD, Nasreen R Jber. Synthesis And Liquid Crystalline Behaviour of New Series Containing 1, 3-Oxazepine And 1, 3-Thiazole Rings. ANJS. 2014; 17(4): 67-75. JIARM
Nisreen HK, Alaa K Sh, Ammar HD. Synthesis, characterization and study of mesomorphic behavior of new bent and linear core compounds containing heterocyclic rings, Mol Cryst Liq Cryst. 2021; 731(1): 66.79. https://doi.org/10.1080/15421406.2021.1966871
Ahmed BJ,Maida HS,Fadhel SM. Synthesis and Study of the Antimicrobial Activity of Modified Polyvinyl Alcohol Films Incorporated with Silver Nanoparticles. Baghdad Sci J. 2023; 20(5): 1643-1653. https://dx.doi.org/10.21123/bsj.2023.7471
Khalil T,Alireza K, Ali D, Milad Kh. Efficient RuIII-catalyzed synthesis of 9-aryl-9H-xanthene-3,6-diols as precursors to fluorones. Chin Chem Lett. 2012; 23(2): 165–168. https://doi.org/10.1016/j.cclet.2011.11.012
Anupam GB, Lata PK, Piyoosh A Sh, Asha BT, Rabindra K N, Sushant K Sh. et al. A facile microwave assisted one pot synthesis of novel xanthene derivatives as potential anti-inflammatory and analgesic agents. Arab J Chem. 2016; 9(1): S480–S489. https://doi.org/10.1016/j.arabjc.2011.06.001
Ridzuan M, Mohammad B O, Hanafi I, Zulkifli A. Synthesis and characterization of rigid aromatic-based epoxy resin. M P J. 2009; 4 (2): 68-75.
Nebras MJ, Dhuha FH, Jumbad HT. Synthesis and Characterization New Schiff Bases, Pyrazole and Pyrazoline Compounds Derived From Acid Hydrazide Containing Isoxazoline Ring. Ibn al-Haitham J Pure Appl Sci. 2014; 27 (3): 435-447.
Mengqiu J, Chaobo W, Wei L, Dahai G. Synthesis and characterization of a silicone resin with silphenylene units in Si-O-Si backbones. J Appl Polym Sci. 2009; 114(2): 971-977. https://doi.org/10.1002/app.30635
Hileuskaya KS. et al. Hydrothermal Synthesis and Properties of Chitosan–Silver Nanocomposites. Russ J Inorg Chem.2021; 66(8): 1128–1134. https://doi.org/10.1134/S0036023621080064
Maida HS, Ahmed BJ. Synthesis, characterization and Study Bioactivity of Silver Nanocomposites. Int J Pharm Res. 2020; 12 (4): 766-772. https://doi.org/10.31838/ijpr/2020.12.04.134
Zhizhou Y, Shuang H, Rong Z, Shengyu F, Changqiao Z, Shengyou Z. Effects of silphenylene units on the thermal stability of silicone resins. Polym Degrad Stab. 2011; 96(12): 2145-2151. https://doi.org/10.1016/j.polymdegradstab.2011.09.014
Balqees M Al, Hanaa J K. Nano composites of PAM Reinforced with Al2O3. Baghdad Sci J.2022; 20(6): 2300-2306. https://doi.org/10.21123/bsj.2023.7353
Jumbad H T, Omar B O, Ammar H D.A new thiazoldinone and triazole derivatives: Synthesis, characterization and liquid crystalline properties, J Mol Struct. 2022; 1270(5): 133817. https://doi.org/10.1016/j.molstruc.2022.133817.
Wasan M. H, Jumbad H. T, Rajaa K. Synthesis and Study the Biological Activity of New Heterocyclic Compounds Derived From Hydrazide Derivatives. Indian J Forensic Med Toxicol. 2020; 14 (4): 1881-1887. https://doi.org/10.37506/ijfmt.v14i4.11819
Ilaria C, Elena F, Debora P, Jose M K, Francesca N. Effect of silver nanoparticles and cellulose nanocrystals onelectrospun poly(lactic) acid mats: Morphology, thermal propertiesand mechanical behavior. Carbohydr Polym. 2014; 103(1): 22– 31. https://doi.org/10.1016/j.carbpol.2013.11.052
Vikneswari S, Mohamed Th H, Radzi AM, Ahmad AS, Ain U M, Syafiqah N A. et al. Effect of Silver Nanopowder on Mechanical, Thermal and Antimicrobial Properties of Kenaf/HDPE Composites. Polymers. 2021; 13(22): 3928. https://doi.org/10.3390/polym13223928.
Shaker Q, Hadee M N, Suhad M A, Hemn U A, Husam A, Jawad A. et al. Fly Ash-Based Geopolymer Composites: A Review of the Compressive Strength and Microstructure Analysis. Mater. (Basel). 2022; 15(20): 7098. https://doi.org/10.3390/ma15207098
Muhammad F A , Mohd M M , Zaidah Z A , Irwan S , Muhammad S M, Muhammad A A. Synthesis, Characterisation and Antibacterial Properties of Silicone–Silver Thin Film for the Potential of Medical Device Applications , Polymers. 2021; 13 (21): 3822. https://doi.org/10.3390/polym13213822.
Downloads
Issue
Section
License
Copyright (c) 2024 Thikra A. Naif , Basma J. Ahmed
This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
