Some new transition metal complexes of bis (2-methyl furfuraldene)-4,4`-methylene bis (cyclohexylamine) ligand Rana A.S.Al-Quaba | Maher A.M . Al-Ta'yy

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Baghdad Science Journal

Abstract

New Fe(II),Co(II),Ni(II),Cu(II) and Zn(II) Schiff base complexes which have the molar ratio 2:1 metal to ligand of the general formula [M2( L) X4] (where L=bis(2-methyl furfuraldene)-4-4`-methylene bis(cyclo-hexylamine) ) were prepared by the reaction of the metal salts with the ligand of Schiff base derived from the condensation of 2:1 molar ratio of 2-acetyl furan and 4-4`-methylene bis (cyclohexylamine). The complexes were characterized by elemental analysis using atomic absorption spectrophotometer ,molar conductance measurements, infrared, electronic spectra,and magnetic susceptibility measurement. These studies revealed binuclear omplexes. The metal(II) ion in these complexes have four coordination sites giving the most expected tetrahedral structure and square planar for Cu(II)ion.

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Journal BS. Some new transition metal complexes of bis (2-methyl furfuraldene)-4,4`-methylene bis (cyclohexylamine) ligand: Rana A.S.Al-Quaba | Maher A.M . Al-Ta’yy. Baghdad Sci.J [Internet]. 2013Sep.1 [cited 2021Aug.2];10(3):569-82. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2572
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