Synthesis and characterization of novel metal complexes of (pentulose-?-lactone-2,3-enedibenzoate barbituric acid) with some metal ions Abdul-Jabbar A. Mukhlis|Basima M. Sarhan|Rasmia M. Rumez

Main Article Content

Baghdad Science Journal

Abstract

New (pentulose-?-lactone-2,3-enedibenzoate barbituric acid) (L) have been synthesized by reaction of (5-C-dimethyl malonyl-pentulose-?-lactone-2,3-enedibenzoate) with urea in alkaline media (sodium methoxide). (Ca+2, Co+2, Ni+2, Cu+2, Zn+2, Cd+2 and Hg+2) complexes of (pentulose-?-lactone-2,3-enedibenzoate barbituric acid) (L) have been prepared and characterized by (1H and 13CNMR), FTIR, (U.V-Vis) spectroscopy, Atomic absorption spectrophotometer (A.A.S), Molar conductivity measurements and Magnetic moment measurements, and the following general formula has been given for the prepared complexes [MLCl2(H2O)].XH2O, where M = (Ca+2, Co+2, Ni+2, Cu+2, Zn+2, Cd+2, Hg+2), X = five molecules with (Cd+2) complex, L = (pentulose-?-lactone-2,3-enedibenzoate barbituric acid).

Downloads

Download data is not yet available.

Article Details

How to Cite
1.
Journal BS. Synthesis and characterization of novel metal complexes of (pentulose-?-lactone-2,3-enedibenzoate barbituric acid) with some metal ions: Abdul-Jabbar A. Mukhlis|Basima M. Sarhan|Rasmia M. Rumez. Baghdad Sci.J [Internet]. 2013Sep.1 [cited 2021Dec.4];10(3):597-606. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2574
Section
article

Most read articles by the same author(s)

1 2 3 4 5 6 7 8 9 10 > >>