Synthesis ,spectroscopic study of Antipyryl azo 2-Naphthol and use it as new reagent for determination of Co(II) and Cu(II) Hussain.J. Mohammed|Azhar.Y. Muhi |Fatema. Abbas

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Baghdad Science Journal

Abstract

A simple ,accurate and sensitive spectrophotometric method has been developed the determination of Cobalt(II) and Cupper (II) .The method is based on the chelation of Co(II) and Cu(II) ions with 4-(4´-pyrazolon azo) -2-Naphthol(APAN) in aqueous medium . The complexes have a maximum absorption at (513) and (506) nm and ? max 0.531×10 4 and 0.12×10 5 L.mol -1.cm -1 for Co(II) and Cu(II) respectively .The reagent and two complexes have been prepared in ethanolic solution.The stoichiometry of both complexes were found to be 1:2 (metal :legend) .The effects of various cations and anions on Co(II) and Cu(II) determination have been investigated .The stability constants and standard deviations for Co(II) and Cu(II) 0.291 x107 ,0.909X108 L.mol -1 ,(0.291) and (0.332) respectively .The optimum condition for full color development for described methods were applied satisfactorily to synthetic samples.

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Journal BS. Synthesis ,spectroscopic study of Antipyryl azo 2-Naphthol and use it as new reagent for determination of Co(II) and Cu(II): Hussain.J. Mohammed|Azhar.Y. Muhi |Fatema. Abbas. Baghdad Sci.J [Internet]. 2013Sep.1 [cited 2021Aug.2];10(3):977-85. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2608
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