Study the Inhibition Effect of Amoxicillin Drug for Corrosion of Carbon Steel in Saline Media

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Zeena Sh. Mahmoud
Abeer K. Shams
Taghried Ali Salman

Abstract

          Potentiostatic polarization and weight loss methods have been used to investigate the corrosion behavior of carbon steel in sodium chloride solution at different concentrations (0.1, 0.4 and 0.6) M under the influence of temperatures ( 293, 298, 303, 308 and 313) K. The inhibition efficiency of the amoxicillin drug on carbon steel in 0.6 M NaCl has also been studied based on concentration and temperature. The corrosion rate showed that all salt concentrations ( NaCl solution) resulted in corrosion of carbon steel in varying ratio and 0.6 M of salt solution  was the highest rate (50.46 g/m².d). The results also indicate that the rate of corrosion increases at a temperature of 313 K.. Potentiodynamic polarization studies showed that the examined inhibitor suppress both anodic and cathodic process and behave as mixed type inhibitor. The adsorption of amoxicillin was found to obey Langmuir isotherm model. Arrhenius equation and transition state theory were used to calculate kinetic and thermodynamic parameter. Results obtained showed that corrosion reaction of carbon steel in NaCl is spontaneous and there is a good agreement between the data got from the both techniques employed. SEM analysis was performed to study the film persistency of the inhibitor.

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Mahmoud ZS, Shams AK, Salman TA. Study the Inhibition Effect of Amoxicillin Drug for Corrosion of Carbon Steel in Saline Media. Baghdad Sci.J [Internet]. [cited 2021Dec.4];19(1):0121. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/4940
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References

Kinlen PJ, Kendig M. Smart Corrosion Protective Coatings, Smart Materials. Schwartz M, Ed, CRC Press, Boca Raton, F. 2009 :1 - 16.

Liang J, BalaSrinivasan P, Blawert C, Dietzel W. Influence of chloride ion concentration on the electrochemical corrosion behavior of plasma electrolytic oxidation coated AM50 magnesium alloy. J. Electrochim. Acta. 2015; 55: 6802– 6811.

Waheed A, Badawya H, Nadia H, Nady H. Electrochemical behavior of Mg and some Mg alloys in aqueous solutions of different pH. J. Electrochimica Act. 2010; 55: 1880- 1887.

Yi TF, Liu HP, Zhu YR, Jiang LJ, Xie Y, Zhu RS. Water soluble conducting polymer composite of polyvinyl alcohol and leucine: an effective acid corrosion inhibitor for mild steel. J. Power Sources. 2012: 215-258.

Lian PC, Zhu XF, Xiang HF, Li Z, Yang WS, Wang H.H. Corrosion control of carbon steel in phosphoric acid by purpald – Weight loss, electrochemical and XPS studies. Electrochim. Acta. 2016; 56: 834-841.

Mahbuboo RC, Ming-Kai H, Radisav DV, David AD. Thiadiazolesas Corrosion Inhibitors for Carbon Steel in H2SO4 Solutions. Ind. Eng. Chem. Res. 2012; 51: 4230-4237.

Eddy NO. Green corrosion chemistry and engineering: opportunities and challenges. John Wiley & Sons; 2011 Dec 2.

Kumar S H. Inhibition Effect of Amoxicillin drug on the Corrosion of Mild Steel in 1N Hydrochloric acid Solution. "Int. J. Chemtech Res . 2012;4: 1077-1084.

Salman T A, Zinad DS, Jaber SH, Ghezi M, Mahal A, Takriff MS, et al. Effect of 1,3,4-thiadiazole scaffold on the corrosion inhibition of mild steel in acidic medium: an experimental and computational study. J. Bio- Tribo-Corros. 2019; 5;2:48-56.

Salman T A, Al-Amiery A A, Shaker L M, Kadhum A H , Takriff M S. A study on the inhibition of mild steel corrosion in hydrochloric acid environment by 4-methyl-2-(pyridin-3-yl)thiazole-5- carbohydrazide. Int. J. Corros. Scale Inhib. 2019; 8:4: 1035–1059.

Quraishi MA, Ambrish S, Vinod K S, Dileep K Y, Ashish K S. Green approach to corrosion inhibition of mild steel in hydrochloric acid and sulphuric acid by the extract of Murraya koenigii leaves. Mater. Chem. Phys. 2010;122 :1: 114–122.

Salman T A, Al-Azawi K F, Mohammed I M, Al-Baghdadi S B , Al-Amiery A A, Gaaz T S, et al. Experimental studies on inhibition of mild steel corrosion by novel synthesized inhibitor complemented with quantum chemical calculations. Resul. in Phys. 2018; 10: 291-296.

Salman T A, Samawi K A, Shneine J K. Electrochemical and computational studies for mild steel corrosion inhibition by Benzaldehydethiosemicarbazone in acidic medium. Portugaliae Electrochimica Acta. 2019; 37:4: 241-255.

Hong S, Chen W, Luo H Q, Li N B. Inhibition effect of 4-amino-antipyrine on the corrosion of copper in 3 wt.% NaCl solution. Corros. Sci. 2012; 57: 270–278.

Kubba RM, Mohammed M. Synthesis, Identification, Theoretical and experimental studies of carbon steel corrosion inhibition in seawater by some new diazine derivatives linked to 5-nitroisatin moiety. IJS. 2018;59(3B):1347-1365.

Emeka E O. Evaluation of the inhibitive effect of some plant extracts on the acidcorrosion of mild steel. Corros. Sci. 2008; 50 : 2993–2998.

Cheyad M S, Salman T A, Characterization and Study the Inhibition Activity of Pomegranate Peel Extract for α-Brass Corrosion in H2SO4 Solution. Orient. J. Chem. 2017; 33(3):1241-1251.

Salman T A, Mohammed A B. Inhibiting effects of L-Tryptophan on the carbon steel corrosion in alkaline saline solution. Rasayan J.Chem. 2017; 10(3) :815-824.

Liu Y, Wang Z, Wei Y. Influence of seawater on the carbon steel initial corrosion behavior. Int. J. Electrochem. Sci. 2019;14:1147–1162.