Synthesis, Characterization and Gas Sensor Application of New Composite Based on MWCNTs:CoPc:Metal Oxide

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Mohanad Mousa Kareem, Dr.
Burak Yahya Kadem, Dr.
Emman J. Mohammad, Dr.
Abbas Jassim Atiyah, Dr.

Abstract

The synthesis of new substituted cobalt Phthalocyanine (CoPc) was carried out using starting materials Naphthalene-1,4,5, tetracarbonic acid dianhydride (NDI) employing dry process method. Metal oxides (MO) alloy of (60%Ni3O4 40%-Co3O4 ) have been functionalized with multiwall carbon nanotubes (F-MWCNTs) to produce (F-MWCNTs/MO) nanocomposite (E2) and mixed with  CoPc to yield (F-MWCNT/CoPc/MO) (E3). These composites were investigated using different analytical and spectrophotometric methods such as 1H-NMR (0-18 ppm), FTIR spectroscopy in the range of (400-4000cm-1), powder X-rays diffraction (PXRD, 2θ o = 10-80), Raman spectroscopy (0-4000 cm-1), and UV-Visible spectrophotometry (0-800 nm). Then the activity of these materials was investigated as a gas sensing of (Ammonia, Methanol and Acetone). For each case, 0.2 mg/.mL of the prepared Copc, Copc/MWCNT, Copc/MWCNTs–MO was dispersed in 1m of ammonia, methanol and acetone at 298K. The surface morphology of the prepared materials was heterogeneous.

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Kareem MM, Kadem BY, Mohammad EJ, Atiyah AJ. Synthesis, Characterization and Gas Sensor Application of New Composite Based on MWCNTs:CoPc:Metal Oxide. Baghdad Sci.J [Internet]. [cited 2021Apr.17];18(2):0384. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/5073
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