Using some Natural Minerals to Remove Cadmium from Polluted Water

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Monier M. Wahba
Wafaa M. Hashesh
Nesreen H. Abou-Baker
https://orcid.org/0000-0003-3986-7501

Abstract

Water scarcity is one of the most important problems facing humanity in various fields such as economics, industry, agriculture, and tourism. This may push people to use low-quality water like industrial-wastewater. The application of some chemical compounds to get rid of heavy metals such as cadmium is an environmentally harmful approach. It is well-known that heavy metals as cadmium may induce harmful problems when present in water and invade to soil, plants and food chain of a human being. In this case, man will be forced to use the low quality water in irrigation. Application of natural materials instead of chemicals to remove cadmium from polluted water is an environmental friendly approach. Attention was drawn in this research work to use some natural minerals as zeolite, bentonite and montmorillonite to adsorb cadmium element from polluted water. Various concentrations of cadmium in solutions 10, 30 and 50 ppm were treated with three different ratios of each mineral; 1, 3 and 5% (W/V). The obtained results proved that increasing the ratio of amendments to 5% increased Cd adsorption from solution particularly at 50ppm Cd. Zeolite obtained the highest ratio of adsorption (47.90 ppm), followed by montmorillonite (44.99 ppm) and the lowest was bentonite (38.97 ppm). Therefore, it can be recommended that addition of zeolite is the most favorable material to remove Cd element from polluted water.

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Wahba MM, Hashesh WM, Abou-Baker NH. Using some Natural Minerals to Remove Cadmium from Polluted Water. Baghdad Sci.J [Internet]. 2022 Oct. 1 [cited 2022 Nov. 30];19(5):1008. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/5385
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References

Maleki A, Mahvi AH, Zazouli MA, Izanloo H, Barati AH. Aqueous cadmium removal by adsorption on barley hull and barley hull ash. Chem. Asian J. 2011; 23(3): 1373-1376.

Ibrahim WM, Mutawie HH. Bioremoval of heavy metals from industrial effluent by fixed-bed column of red macroalgae. ToxicolInd Health. 2013; 29(1): 38-42.

Mata Y, Blázquez M, Ballester A, González F, Munoz J. Biosorption of cadmium, lead and copper with calcium alginate xerogels and immobilized Fucusvesiculosus.J. Hazard. Mater. 2009; 163(2-3): 555-562.

Tanzifi M, KolbadiNezhad M, Karimipour K. Kinetic and isotherm studies of cadmium adsorption on polypyrrole/titanium dioxide nanocomposite. J Water Environ Nanotechnol. 2017; 2(4): 265-277.

Barsbay M, KavaklPA, Tilki S, Kavaklı C, Güven O. Porous cellulosic adsorbent for the removal of Cd (II), Pb (II) and Cu (II) ions from aqueous media. Radiat. Phys. Chem. 2018; 142: 70-6.

Hashesh WM, Habib F, Wahba M, Noufal EH, Abou-Baker NH. Removal of lead from polluted water by using clay minerals. Zagazig J Agric Res. 2017; 44(6): 2097-2103.

Atkovska K, Lisichkov K, Ruseska G, DimitrovAT, Grozdanov A. Removal of heavy metal ions from wastewater using conventional and nanosorbents: a review. J ChemTechnol Metall. 2018; 53(2): 202-219.

Taamneh Y, Sharadqah S. The removal of heavy metals from aqueous solution using natural Jordanian zeolite. Appl water sci. 2017; 7(4): 2021-2028.

Abadeh ZA, Irannajad M. Removal of Ni and Cd ions from aqueous solution using iron dust-zeolite composite: Analysis by thermodynamic, kinetic and isotherm studies. Chem Res Chin Univ . 2017; 33(2): 318-326.

Abou-Baker NH, Ibrahim EA, Abd-Eladl MM. Biozeolite for improving bean production under abiotic stress conditions. Bull. Transilv. Univ. Bras. II: For. Wood Ind. Agric. Food Eng.. 2017;10(59):151-170.

Abd El-Zaher FH, Lashein A, Abou-Baker NH. Application of zeolite as a rhizobial carrier under saline conditions. Biosci Res. 2018;15(2):1319-33.

Khachatryan SV. Heavy metal adsorption by armenian natural zeolite from natural aqueous solutions. Chem. Biol. 2014; 2: 31-35.

Tuaimah SK, Al-Nasri SK, Al-Rahmani AA. Using Dates Leaves Midribs to Prepare Hierarchical Structures Incorporating Porous Carbon and Zeolite A Composites for Cesium137Cs Ion Exchange. Baghdad sci J. 2020 Jul 16; 17(3): 818-825.

Ugal JR, Kareem SH, Hassan SS. Adsorption of hydrogen sulphide on the zeolite type Asynthezied from Iraqi kaoline. Baghdad SciJ . 2013; 10: 1023-1033.‎

Abd El-Azim H, Mourad FA. Removal of Heavy Metals Cd (II), Fe (III) and Ni (II), from aqueous solutions by natural (clinoptilolite) zeolites and application to industrial wastewater. Asian J Environ Sci. 2018:1-13.

Guerra D, Mello I, Resende R, Silva R. Application as absorbents of natural and functionalized Brazilian bentonite in Pb2+ adsorption: Equilibrium, kinetic, pH, and thermodynamic effects. Water Resour Ind. 2013; 4: 32-50.

Burham N, Sayed M. Adsorption behavior of Cd2+ and Zn2+ onto natural Egyptian bentonitic clay. Minerals. 2016; 6(4): 129.

Abou-Baker NH, El-Ashry MS, Wahba MM, Habib FM, Noufal EHA, Hashesh WM. Evaluating the Application of some Natural Amendments to Hinder the Pollution of Barley Plants by Heavy Metals. Sci J King Faisal Univ. 2019, 20 (2-1441H): 55-68.

Cottenie A, Verloo M, Kiekens L, Velghe G, Camerlynch R. Chemical analysis of plants and soils. Laboratory of Analytical and Agrochemistry State University, Ghent Belgium. 1982. Article No. 42, 80-284

Bu X, Feng P, Stucky GD. Large-cage zeolite structures with multidimensional 12-ring channels. Science. 1997; 278(5346): 2080-2085.‏

Dstan L, Dehghani M. Removal of cadmium from industrial waste water by adsorption zeolite clinoptilolite. BiosciBiotechnolRes Commun. 2016;9(4):865-871.

Pariente PJ, Sanchez MC. Zeolites and ordered porous solids: fundamentals and applications: Editorial UniversitatPolitècnica de València; 2011. http://hdl.handle.net/10251/11205

Talaat H, El Defrawy N, Abulnour A, Hani H, Tawfik A. Evaluation of heavy metals removal using some Egyptian clays.2nd International Conference on Environmental Science and Technology. IACSIT Press, Singapore. IPCBEE. 2011; 6: 37-42.

Kraepiel AML, Kellers K, Morel FMM. A model for metal adsorption on montmorillonite. J Colloid Interface Sci.1999; 210(1):43-54.

Ranga S. Bentonite used as natural coagulant and adsorbent: A review. J Pharm Innov. 2018; 7(7): 155-157.

Ghomri F, Lahsini A, Laajeb A, Addaou A. The removal of heavy metal ions (copper, zinc, nickel and cobalt) by natural bentonite. Larhyss j.2013(12). P-ISSN 1112-3680/E-ISSN 2521-9782..

Hamidpour M, Kalbasi M, Afyuni M, Shariatmadari H, Holm PE, Hansen HC. Sorption hysteresis of Cd(II) and Pb(II) on natural zeolite and bentonite. J Hazard Mater. 2010; 181: 686–691.