Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol

Main Article Content

Rasha KhiderHussain Al-Daffaay

Abstract

The ligand 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol, derived from 1-hydroxy-2-naphthaldehyde and 2-(1H-indol-3-yl)ethylamine, was used to produce a new sequence of metal ions complexes. Thus ligand reactions with NiCl2.6H2O, PdCl2, FeCl3.6H2O and H2PtCl6.6H2O were sequentially made to collect mono-nuclear Ni(II), Pd(II), Fe (III), and Pt(IV). (IR or FTIR), Ultraviolet Reflective (UV–visible), Mass Spectra analysis, Bohr-magnetic (B.M.), metal content, chloride content and molar conductivity have been the defining features of the composites. The Fe(III) and Pt(IV) complexes have octahedral geometries, while the Ni(II) complex has tetrahedral geometry and the Pd (II) complex has square planer geometry, according to these findings.

Article Details

How to Cite
1.
Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol. Baghdad Sci.J [Internet]. 2022 Oct. 1 [cited 2024 Mar. 28];19(5):1036. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6162
Section
article

How to Cite

1.
Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol. Baghdad Sci.J [Internet]. 2022 Oct. 1 [cited 2024 Mar. 28];19(5):1036. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6162

References

May JK, Al-Hamdani AAS, Vian YJ, Mohammad EK, Abdul WAand Al Zoubi W..Preparation, spectroscopic study of Schiff base derived from dopamine and metal Ni(II), Pd(II), and Pt(IV) complexes,and activity determination as antioxidants. J Phys Org Chem. 2020 Nov; 34 (3): 1–15.

May JK, Al-Hamdani AAS, Young GK, Al Zoubi W, Saad GM. Synthesis, characterization, and determination antioxidant activities for new Schiff base complexes derived from 2-(1H-indol-3-yl)-ethylamine and metal ion complexes. J Mol Struc. 2021 May; 1231:30.

Mohammed BH, MosabNouraldein MH. Synthesis and antibacterial activity of 3-nitrobenzaldehyde semicarbazone ligand and its Ni (II) and Cu (II) Complexes. J Microbiol Exp. 2020; 8(5): 163‒165.

Al-Hamdani AAS, Al Zoubi W. New metal complexes of N3 tridentate ligand: Synthesis, spectral studies and biological activity. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2015 Feb 25;137: 75-89.

Jirjees VY, Suleman VT, Al-Hamdani AAS, Ahmed SD. Preparation, Spectroscopic Characterization and Theoretical Studies of Transition Metal Complexes with 1-[(2-(1H-indol-3-yl) ethylimino) methyl] naphthalene-2-ol Ligand. Asian J Chem. 2019; 31(11):2430-8.

Al Zoubi W, Kim MJ, Al‐Hamdani AAS, Kim YG, Ko YG. Phosphorus‐based Schiff bases and their complexes as nontoxic antioxidants: Structure–activity relationship and mechanism of action. Appl. Organomet Chem. 2019; 33(1): 1-16.

Al-Hamdani AAS, Balkhi AM, Falah A, Shaker SA. Synthesis and investigation of thermal properties of vanadyl complexes with azo-containing Schiff-base dyes. J Saudi Chem Soc. 2016; 20: 487–501.

Al-Hamdani AAS, Balkhi A, Falah A, Shaker ShA. New Azo-Schiff base derived with Ni (II), Co (II), Cu (II), Pd (II) and Pt (II) complexes: preparation, spectroscopic investigation, structural studies and biological activity. J Chil Chem Soc. 2015 Mar;60(1):2774-85.

ObaidSh M H, Sultan J Sh, Al-Hamdani AAS. Synthesis, Characterization and Biological Efficacies from Some New Dinuclear Metal Complexes for Base 3-(3, 4-Dihydroxy-phenyl)-2-[(2-hydroxy-3-methylperoxy-benzylidene)-amino]-2-methyl Propionic Acid. Indones J Chem. 2020, 20(6): 1311-1322.

Silverstein RM, Webster FX, Kiemle DJ. Silverstein-Spectrometric Identification of Organic Compounds. 7th ed. JW.A.: INC; 2005. 1-550.

Al-Zoubi W, Saad GM, Al-Hamdani AAS, Agastya PM, Young GK. Acyclic and cyclic imines and their metal complexes: recent progress in biomaterials and corrosion applications. R Soc Chem. 2018; 8(41): 23294-23318.

Al-Hamdani AAS, Hasan ZA. Spectroscopic studies and thermal analysis of new azo dyes ligands and their complexes with some transition of metal ions. Baghdad Sc. J. 2016;13(3): 511-523.

Jirjees VY, Al‐Hamdani AAS, Wannas NM,Farqad AR, Adnan D, Al-Zoubi W.Spectroscopic characterization for new model from Schiff base and its complexes. J. Phys. Org. Chem. 2021 April, 34(4) e4169.

Al-Hamdani AAS, Hamoodah RG. Transition metal complexes with tridentate ligand: preparation, spectroscopic characterization, thermal analysis and structural studies. Baghdad Sc J. 2016 ;13(4): 770-781.

Shayma A Sh, Mohammed H.A, Al-Hamdani AAS. Preparation, Physico-Chemical and Spectroscopic Investigation of Thiacetazone and Quinalizarin Complexes with Mn(II), Fe(II),Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II). Aust. J. Basic & Appl. Sci · 2010;4(10): 5178-5183.

Noor MW, Al-Hamdani AAS, Al-Zoubi W. Spectroscopic characterization for new complexes with 2,2'- (5,5-dimethylcyclohexane-1,3-diylidene) bis(azan-1-yl-1-ylidene) dibenzoic acid. J. Phys. Org. Chem. 2020Jul; 33(11):1-12.

Al-Hamdani A A S. Metal complexes of multidentate Schiff base-azo ligand: synthesis, characterization and biological activity. Dirasat Pure Sci. 2013,39(1):61-72.

Kazuo N. Infrared and Raman Spectra of Inorganic Coordination Compounds. 5th ed. New York: Wiley Interscience; 1997. ch 2

Al Zoubi W, Al‐Hamdani A A S, Duraid Ahmed S, Basheer HM, Al‐Luhaibi RS, Dib A, Ko YG. Synthesis, characterization, and antioxidant activities of imine compounds. J Phys Org Chem. 2019 Mar; 32(3): e3916.

Al-Hamdani AAS, Al-Luhaibi RS. Determination Antioxidant Activity for Metal Ion Complexes and Theoretical Treatment. Res J Pharm Biol Chem Sci. 2017 Sep1; 8(5): 164-77.

Al-Hamdani AAS. Synthesis, Characterization, Theoretical, thermal Studies and Bio Activities of Metal Complexes with Schiff base mannich ligand. Res J Pharm Biol Chem Sci. 2017 may 1; 8(3): 2119-32.

Al Zoubi W, Al-Hamdani AAS, Mosab K. Synthesis and antioxidant activities of Schiff bases and their complexes: review Appl. Organomet. Chem. 2016; 30 (10): 810-817.

Moharram HA, Youssef M M. Methods for Determining the Antioxidant Activity: A Review. Afr J Food Sci. 2014; 11(1): 31-42.

Ahmed SM, Salih KM, Ahmad HO, Jawhar ZH, Hamad DH. Synthesis, spectroscopic characterization and antibacterial activity of new series of Schiff base derived from 4-aminoantipyrine and 2-amino benzimidazole. Zanco J Med Sci. 2019 Aug 1; 23(2):206-16.

Similar Articles

You may also start an advanced similarity search for this article.