Kinetic and Theoretical Study of Removal Gentian Violet from Aqueous Solution Using Stachy Plant
DOI:
https://doi.org/10.21123/bsj.2023.7066Keywords:
Adsorption, Gentian Violet, kinetic, Stachy plant, Temkin modelsAbstract
The main parameters and methods influencing the removal of Gentian Violet (GV) dye from aqueous media were investigated using a stachy plant in this study. The surface of the stachy plant was determined using FTIR spectra. Adsorption is influenced by the adsorbent's characteristic groups. The research took into account the usual conditions for GV dye adsorption by the stachy plant, such as the impact of contact time. Mass dosage , after 0.3 g the amount of adsorbed dye declines. Study pH and ionic strength, the results obtained showed that at pH 3 the largest adsorption of (GV) was seen, while at pH 9, the lowest adsorption was observed at 298 K, the adsorption kinetics and equilibrium constants were achieved, and the equilibrium data was fitted using the Langmuir, Freundlich, and Temkin models. The pseudo-first-order and pseudo-second-order kinetic models were used to investigate the adsorption process of gentian violet. The adsorption kinetics was discovered to be governed by a pseudo-second-order kinetic model with a determination coefficient (R2) of 0. 0.9943. Study the theoretical electrostatics of Gentian Violet dye was measured and plotted as a 2D and 3D contour and the program hyperchem-8.07 was used for semi-empirical and molecular mechanic calculations in the gas phase to estimate the total energy.
Received 17/2/2022
Accepted 26/6/2022
Published Online First 20/1/2023
References
Ebrahim A S, Tarek A F, Marwa N, Mohamed D. A Comparative Study for Adsorption of Methylene Blue Dyefrom Wastewater onto Three Different Types of Rice Ash. J Pharm Appl Chem. 2018; 4 (1): 99-107.
Haipeng Z, Mengjun C, Huan W, Zhenhua W, Jiajing C, Liu F, et al. Transcriptomic and metabolomic analyses provide insight into the volatile compounds of citrus leaves and flowers. BMC Plant Biol. 2020; 20(7): 1-14.
Ayed L, Chaieb K, Cheref A. Biodegradation of Triphenylmethane Dye Malachite Green By sphingomonas Paucimobilis. World J Microbiol. Biotechnol. 2009; 25(4): 705.
Mittal A, Mittal J, Malviya A, Gupta V K. Removal and recovery of Chrysoidine Y from aqueous solutions by waste materials. J Colloid Interface Sci. 2010; 344 (2): 497–507.
Alkaram F, Mukhlis A. The removal of phenol from aqueous solutions by adsorption using surfactant-modified bentonite and kaolinite. J Hazard Mater. 2009; 169 (1-3): 324-332.
Sughosh M, Arif A, Amit K, Jyoti K, Joginder C, Sanjeev S, et al. Water pollutants: sources and impact on the environment and human health. Sensors in Water Pollutants Monitoring: Role of Material. Springer, Singapore, October. 2019;43-62.
Sandeep P, Sukanta M, Dilip K C, Chetan K D, Sanjay K S, Kumar A. Vinod. Effect of coal fly ash's particle size on U adsorption in water samples and thermodynamic study on adsorption. Environ Chem Ecotoxicol. 2020; 2. 32-38.
Tran H Tu , Phan Thi Ngoc Cam, Le Van Trong Huy , Mai Thanh Phong , Hoang Minh Nam,Nguyen Huu Hieu. Synthesis and application of graphene oxide aerogel as an adsorbent for removal of dyes from water. Mater Lett. 2018;238: 134-137.
Aljeboree Aseel M, Alshirifi Abbas N, Alkaim Ayad F. Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon. Arab J Chem. 2017; 10 (2): S3381–S3393.
ShanHo Y, Augustine E. Ofomaja. Kinetic studies of copper ion adsorption on palm kernel fibre .J Hazard Mater. 2006; 137 (3). 1796-1802.
Oğuzhan K, Bilal A. Adsorption of basic green 4 from aqueous solution by olive pomace and commercial activated carbon: process design, isotherm, kinetic and thermodynamic studies. Desalination Water Treat. 2016; 57 (35). 16653-16669.
Murugan T, Vasugi K, Praphakaran P, Prabhu P. A Study of Adsorption Dynamics of Biologically Active Plants. Int J Res Appl Eng Sci Tech. 2021; 9 (X): 1466- 1479.
Yasemin B, Haluk A. A kinetics and thermodynamics study of methylene blue adsorption on wheat shells. Desalination. 2006; January.194 (1–3). 259-267.
Cazetta AL, Vargas AM., Nogami EM., Kunita MH, Guilherme MR., Martins AC, et al. NaOH-activated carbon of high surface area produced from coconut shell: Kinetics and equilibrium studies from the methylene blue adsorption. Chem Eng J. 2011; 174 (1): 117–125.
Wanyonyi WC, Mmari JO, Mwanza PS. Adsorption of congo red dye from aqueous solutions using roots of eichhornia crassipes: kinetic and equilibrium studies. Energy Procedia. 2014; 2. 862 – 869.
Hameed BH, Mahmoud DK. Sorption of basic dye from aqueous solution by pomelo (Citrus grandis) peel in a batch system .Colloids Surf A Physicochem Eng Asp. 2008; March. 316 : (1–3). 78-84.
Karla A G, Leandro VA, Tânia Márcia SM, Laurent FG. Adsorption studies of methylene blue and gentian violet on sugarcane bagasse modified with EDTA dianhydride (EDTAD) in aqueous solutions: Kinetic and equilibrium aspects. J Environ Manage. 2013; 30 (118): 135- 143.
Indra D M , Vimal C S, Nitin K A, Indra M M. Removal of congo red from aqueous solution by bagasse fly ash and activated carbon: kinetic study and equilibrium isotherm analyses. Chemosphere. 2005; 61 ( 4): 492-501.
Jain R, Shrivastava M. Adsorptive studies of hazardous dye Tropaeoline 000 from an aqueous phase onto coconut-husk. J Hazard Mater. 2008; 158 (2-3): 549–556.
Shaymaa K G, Intidhar D S, Najwa I A. Adsorption of Congo Red Dye from Aqueous Solution onto Natural and Modified Bauxite Clays. Baghdad Sci J. 2017; March. 14(1): 167- 180. https://doi.org/10.21123/bsj.2017.14.1.0167
Khulood A, Dunya E, Huda N. Using Phragmites australis (Iraqi plant) to remove the Lead (II) Ions form Aqueous solution. Baghdad Sci J. 2017; March. 14(1): 148- 156. https://doi.org/10.21123/bsj.2017.14.1.0148
Hameed, KS, Muthirulan, P, Meenakshi, SM. Adsorption of chromotrope dye onto activated carbons obtained from the seeds of various plants: Equilibrium and kinetics studies. Arabian J Chem. May. 2017; 10 (2): S2225–S2233.
Malik RR, DS, Wate SR. Adsorption of malachite green on groundnut shell waste based powdered activated carbon. J Waste Manage. 2007; 27 (9): 1129–1138.
Ahlam M. F, Ahlam M Z, Hussein I A. Adsorption Study of Rhodamine –B Dye on Plant (Citrus Leaves). Baghdad Sci J. 2022; January.4: 838- 847.
Inaam H A, Removal of Congo Red Dye From Aqueous Solution Using Eco-Friendly Adsorbent of Nanosilica. . Baghdad Sci J. 2021; January.18 (2): 366- 373.
Figgis, B, Hitchman M. Ligand Field Theory and Its Applications. John-Weily Heyden. 2000; Ltd, New York, London, 225 pp.
Downloads
Published
Issue
Section
License
Copyright (c) 2023 Baghdad Science Journal
This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
