Corrosion Inhibition of Medium Carbon Steel in the Acidic Medium Using Alcoholic and Aqueous Extract of Kujarat Tea Plant

Authors

  • Suhad S. Mohammed Department of Chemistry, College of Education for pure Sciences, Ibn Al-Haitham, University of Baghdad, Baghdad, Iraq.
  • Layla A. Aljebur Department of Chemistry, College of Science, Tikrit University, Salahaddin, Iraq. https://orcid.org/0000-0003-2829-4066

DOI:

https://doi.org/10.21123/bsj.2023.7256

Keywords:

Extracted, Inhibitor, Oxidation, Reduction, Tafel curves

Abstract

This study deals with the corrosion inhibition of metal corrosion process of medium carbon steel using 1M HCl for kinetic studies and rate reaction determination. The weight loss method is applied to pieces of Medium carbon steel divided to Cubans with dimensions (0.4*2*2.4) cm , and use Tafel Extrapolation Method, the samples were polished using carbide silicon paper with dimensions of (180,200,400,600,800,1000). The samples were immersed in the alcoholic medium ethanol at a temperature 293K for 3hr. Natural inhibitor Kujarat Tea (Hibiscus sabdarriffa L.) is used which is extracted in aqueous and alcoholic medium, different concentrations (1000،2000, 3000) ppm have been used ; The best concentration found through the results is a concentration found that is 1000 and 2000 ppm, the results indicate that the highest degree of inhibition for aqueous extract is 93.3% with the concentration of 2000 ppm and 90.5% with 1000 ppm at293K. While the alcoholic inhibitor shows the highest efficiency 92.4% with a concentration of 2000 ppm and 88.6% with a concentration of 1000 ppm respectively. The structure of the inhibitor was investigated using infrared spectroscopy (FTIR), and the surface morphology of the tested samples was investigated using a scanning electron microscope (SEM).

References

Al-Turkustani AM, Arab ST, Al-Qarni LS. Medicago Sative plant as safe inhibitor on the corrosion of steel in 2.0 M H2SO4 solution. J Saudi Chem Soc. 2011 Jan 1;15(1):73-82.

Sathishkumar P, Kumaravelan V. Dhivya priya D. Comparative study of mild steel corrosion using hydrochloric acid and phosphoric acid medium with ocimum tenuiflorum (l) plant extract. Int J Adv Res. 2015; 3(4): 643-51.

Ajeel A, Mohammed Waadulah H, Sultan DA. Effects of H2SO4 and HCL concentration on the corrosion resistance of protected low carbon steel. AREJ. 2012 Dec 28; 20(6): 70-6.

Trivedi V, Saxena V, Srivastav A. Scanning Electron Micrographic Investigation of Explanted (Used) Metallic Biomedical Implants for Corrosion and Other Mechanical Damage Responsible for Failure. Mater Sci Appl. 2015; 6(10): 869.

Nnanna LA, Owate IO, Oguzie EE. Inhibition of mild steel corrosion in HCl solution by pentaclethra macrophylla bentham extract. Int J Mater Sci. 2014; 4(5): 171-9.

Revie RW. Corrosion and corrosion control: an introduction to corrosion science and engineering. John Wiley & Sons;4th Ed, 2008:1-43.

Mwakalesi AJ. Corrosion inhibition of Mild steel in Sulphuric Acid solution with Tetradenia riparia leaves aqueous extract: Kinetics and Thermodynamics. Biointerface Res Appl Chem. 2022 ; 13(1): 1-13.

Faraj L, Khan GM. Application of Natural Product Extracts as Green Corrosion Inhibitors for Metals and Alloys in Acid Pickling Processes-A. Int J Electrochem Sci. 2015; 10: 6120-34.

Khayatkashani M, Soltani N, Tavakkoli N, Nejatian A, Ebrahimian J, Mahdi MA, Salavati-Niasari M. Insight into the corrosion inhibition of Biebersteinia multifida root extract for carbon steel in acidic medium. Sci Total Environ. 2022 August ; 836(25): 155527.

Merimi I, Bitari A, Kaddouri Y, Rezki N, Mohamed M, Touzani R, Hammouti B. Metal corrosion inhibition by triazoles: A review. Int J Corros Scale Inhib. . 2022; 11(2): 524-40.

Habeeb HJ, Luaibi HM, Dakhil RM, Kadhum AA, Al-Amiery AA, Gaaz TS. Development of new corrosion inhibitor tested on mild steel supported by electrochemical study. Results Phys. 2018 Mar 1; 8: 1260-7.

Mothilal KK, Perumal S, Muthumanickam S, Elangovan A, Muniyappan N. Inhibition of mild steel corrosion in 1n hcl and 1n h2so4 by leaves extract of gossypium herbaceum J Adv Sci Res. 2022 Apr 30; 13(03): 151-60.

Khadom AA. Dual function of benzotriazole as copper alloy corrosion inhibitor and hydrochloric acid flow improver. Surf Eng Appl Electrochem. 2014 Mar; 50(2): 157-72.

Faraj L, Khan GM. Application of Natural Product Extracts as Green Corrosion Inhibitors for Metals and Alloys in Acid Pickling Processes-A. Int J Electrochem. Sci. 2015; 10: 6120-34.

Ameer MA, Fekry AM. Corrosion inhibition of mild steel by natural product compound. Prog Org Coat. 2011 Aug 1; 71(4): 343-9.

Dahmani M, Et-Touhami A, Al-Deyab SS, Hammouti B, Bouyanzer A. Corrosion inhibition of C38 steel in 1 M HCl: A comparative study of black pepper extract and its isolated piperine. Int J Electrochem Sci. 2010 Aug 1; 5(8): 1060-9.

Mahmoud ZS, Shams AK, Salman TA. Study the Inhibition Effect of Amoxicillin Drug for Corrosion of Carbon Steel in Saline Media. Baghdad Sci.J. 2022; 19(1): 0121. https://doi.org/10.21123/bsj.2022.19.1.0121

Jassim RA, Kadhim NJ, Farhan AM. Experimental and Theoretical Study of Neomycin Sulfate as Corrosion Protection for Titanium in Acid Media. Baghdad Sci J. 2021; 18(2). https://doi.org/10.21123/bsj.2021.18.2.0374

Gadow HS, Motawea MM. Investigation of the corrosion inhibition of carbon steel in hydrochloric acid solution by using ginger roots extract. Rsc Adv. 2017; 7(40): 24576-88.

Majeed, Jafar Ghani, Basim Ajel Sadkhan. Comparison of the Corrosion Inhibition Efficiencies of Low Carbon Steel In Different Acidic Mediums Using Some Polyethylene Glycols. JEASD .2013; 17(4): 165-181.‏

Hamdy A, El-Gendy NS. Thermodynamic, adsorption and electrochemical studies for corrosion inhibition of carbon steel by henna extract in acid medium. Egypt J Pet. 2013 Jun 1; 22(1): 17-25.

Isa WA, Ahmed ZW. Corrosion Inhibition of Aluminium in Acidic Medium using Amino Acid (Methionine). Ibn al-Haitham J Pure Appl Sci. 2017 Mar 9; 28(3).

Ali EH, Himdan TA, Ahmed ZW. Gallic acid as corrosion inhibitor for aluminum 6061 in alkali solutions. Ibn al-Haitham J Pure Appl Sci.2019 Jan 20; 32(1): 17-27.

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Published

2023-08-01

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Corrosion Inhibition of Medium Carbon Steel in the Acidic Medium Using Alcoholic and Aqueous Extract of Kujarat Tea Plant. Baghdad Sci.J [Internet]. 2023 Aug. 1 [cited 2024 May 1];20(4):1297. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/7256

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