Mn(II),Fe(III),Co(II)and Rh(III) complexes with azo ligand: Synthesis, characterization, thermal analysis and bioactivity
DOI:
https://doi.org/10.21123/bsj.2022.7289Keywords:
Azo complexes, Bioactivity, Mass spectroscopy, Spectroscopic studies, Thermal analysisAbstract
New series of metal ions complexes have been prepared from the new ligand [4-Amino-N-(5-methyl-isaxazol-3-yl)-benzenesulfonamide] derived from Sulfamethoxazole and 3-aminophenol. Accordingly, mono-nuclear Mn(II), Fe(III), Co (II), and Rh(III) complexes were prepared by the reaction of previous ligand with MnCl2.4H2O, CoCl2.6H2O, FeCl3.6H2O and RhCl3H2O, respectively. The compounds have been characterized by Fourier-transform infrared (FTIR), ultraviolet–visible (UV–vis), mass, 1H-, and 13C-nuclear magnetic resonance (NMR) spectra and thermo gravimetric analysis (TGA& DSC) curve, Bohr magnetic (B.M.), elemental microanalyses, metal ions, chloride containing, and molar conductance.These reviews uncovered octahedral geometries for complexes. The investigation of complexes development by means at molar proportion andoccupation strategy in DMF solution has been researched, and results were reliable to those found in the solid complexes with a proportion of (M:L) as (1:2).
Received 4/4/2022
Accepted 22/5/2022
Published Online First 20/11/2022
References
Al-Hamdani AAS, Zainab AAH. Spectroscopic Studies and Thermal Analysis of New Azo Dyes Ligands and their Complexes with some Transition of Metal Ions. Baghdad Sci. J. 2016; 13(3): 511-523.
Al Zoubi W, Kim MJ, Yoon DK, Al-Hamdani AAS, Kim YG, Ko YG. Effect of organic compounds and rough inorganic layer formed by plasma electrolytic oxidation on photocatalytic performance. J Alloys Compd. 2020 May 15; 823: 153787.
Al Zoubi W, Al-Hamdani AAS, Mosab K. Synthesis and antioxidant activities of Schiff bases and their complexes: a review. Appl. Organomet. Chem. 2016; 30: 810–817.
Al-Hamdani AAS, Abdel MB, Falah A, Shayma AS. Synthesis and investigation of thermal properties of vanadyl complexes with azo-containing. J. Saudi Chem. Soc. 2016; 20(5): 487-501.
Abdeltawab MS, Shaikha SA, Ibrahim MA. Anticancer activity of novel Schiff bases and azo dyes derived from 3-amino-4-hydroxy-2H-pyrano[3,2-c]quinoline-2,5(6H)-dione. Heterocycl Commun. 2020; 26: 192–205.
Al-Hamdani AAS, Abdel MB, Ahmad F, Shayma AS. New azo-Schiff Base derived with Ni(II), Co(II), Cu(II), Pd(II) and Pt(II) complexes: preparation, spectroscopic investigation, structural studies and biological activity. J Chil Chem Soc. 2015; 60(1): 2774-2785.
Wannas NM, Al-Hamdani AAS, Al-Zoubi W. Spectroscopic characterization for new complexes with 2,2'- (5,5-dimethylcyclohexane-1,3-diylidene)bis(azan-1-yl- 1-ylidene) dibenzoic acid. J Phys Org Chem. 2020; 33(11): 1-12.
Moamen SR, AltalhiT., Safyah BB, Ghaferah HA and Kehkashan A. New Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Zn(II), Cd(II),and Hg(II) Gibberellate Complexes: Synthesis, Structure,and Inhibitory Activity Against COVID-19 Protease. Russ J Gen Chem. 2021; 91(5): 890–896.
Fadhel AM, Al-Hamdani AAS. Synthesis, spectroscopic, characterization and biological studies for new complexes with N1,N5-Bis (3 hydroxyphenyl)- 2-oxopentanediamide. Turkish J Phys Reh 2021; 32(3): 11864-11876.
Al-Hamdani AAS. Synthesis, Characterization, Theoretical, thermal Studies and Bio Activities of Metal Complexes with Schiff base mannich ligand. Res J Pharm. Biol. Chem. Sci. 2017 May 1; 8(3): 2119-2132.
Rana AK, May MJA, Tagreed NAO. Synthesis, Characterization and Antimicrobial Evaluation of New Azo Compounds Derived from Sulfonamides and Isatin Schiff Base. Int J Drug Deliv Technol. 2020; 10(1): 150-155.
Suleman VT, Al-Hamdani AAS, Ahmed SD, Jirjees VY, Khan ME, Adnan Dib. Phosphorus Schiff base ligand and its complexes: Experimental and theoretical investigations. Appl. Organomet. Chem. 2020; 34(4), 1-16.
Blumich, B. Essential NMR.5th ed Springer Berlin Heidelberg New York, Printed in Germany.2005: 203-215.
Hasan M. Synthesis, Identification, and Biological Study for Some Complexes of Azo Dye Having Theophylline. Sci World J. 2021; 2021(Article ID 9943763): 1-9.
Marwa AD Amer JJ. Synthesis, Characterization and biological evaluation of thiazolylazo ligand complexes with some metal ions. J Phys Conf. 2020; 1664 (012090): 1-18.
Lever ABP. Inorganic Electronic Spectroscopy, Elsevier PublishingCompany: Amsterdam, London, 6th ed. 1968: 121-201
Al Zoubi W, Al‐Hamdani AAS, Susan DA, Hassan MB, Al‐Luhaibi RSA, Dib A, Young GK. Synthesis, characterization, and antioxidant activities of imine compounds. J Phys Org Chem. 2019; 32(3): e3916. https://doi.org/10.1002/poc.3916
Al Zoubi W, Kim MJ, Al‐Hamdani AAS, Young GK Y. Phosphorus‐based Schiff bases and their complexes as nontoxic antioxidants: Structure–activity relationship and mechanism of action. Appl Organomet Chem. 2019; 33(11): e5210. https://doi.org/10.1002/aoc.5210
Al Zoubi W, Al‐Hamdani AAS, Susan DA, Young GK. Synthesis, characterization, and biological activity of Schiff bases metal complexes. J Phys Org Chem. 2018; 31(2): e3752. https://doi.org/10.1002/poc.3752
Obaid SMH, Sultan JS, Al-Hamdani AAS. Synthesis, Characterization and Biological Efficacies from Some New Dinuclear Metal Complexes for Base 3-(3, 4-Dihydroxy-phenyl)-2-[(2-hydroxy-3-methylperoxy-benzylidene)-amino]-2-methyl Propionic Acid. Indones J Chem. 2020; 20(6): 1311-1322.
Al-Hamdani AAS, Al Zoubi W. New metal complexes of N3 tridentate ligand: Synthesis, spectral studies and biological activity. Spectrochim Acta- A: Mol Biomol Spectrosc. 2015; 137: 75-89. https://doi.org/10.1016/j.saa.2014.07.057
Silverstein, R. M.; Bassler, G. C. and Morrill, T. C.(1981). Spectroscopic identification of organic compounds. 4th Ed., John Wiley and Sons. ; NJ. USA. : 112-132.
Jirjees VY, Al‐Hamdani AAS, Wannas NM, Farqad AR, Adnan D, Al-Zoubi W. Spectroscopic characterization for new model from Schiff base and its complexes. J Phys. Org. Chem. 2021 April, 34(4): e4169.
Silverstein RM, Webster FX, Kiemle DJ. Spectrometric Identification of Organic Compounds.7th ed. J W. A. INC; 2005. 1-550.
Sarhan WM, Al-Kubaisai HMM, Al-Hamdani AAS. Synthesis, Spectral, Bioactive And Theoretical Studies Of New Schiff Base And Metal Complexes. Res J Pharm Biol Chem Sci. 2018 Sep1; 9(5): 1512-1522.
Al-Hamdani AAS, Al-Khafaji NR, Shaalan ND. Preparation, spectral, thermal and bio activity studies of azo dyes complexes.Res J Pharm Biol Chem Sci. 2017 May1; 8(3): 740-750.
Kareem MJ, Al-Hamdani AAS, Ko YG, Al Zoubi W, Mohammed SG. Synthesis, characterization, and determination antioxidant activities for new Schiff base complexes derived from 2-(1H-indol-3-yl)-ethylamine and metal ion complexes. J Mol Struc. 2021; 1231(5): 1-30.
Al Zoubi W, Kamil MP, Fatimah S, Nashrah N, Ko YG. Recent advances in hybrid organic-inorganic materials with spatial architecture for state-of-the-art applications. Prog Mater Sci. 2020 Jul 1; 112: 100663.
Al Zoubi W, Al-Hamdani AAS, Young GK. Schiff bases and their complexes: Recent progress in thermal analysis. Sep Sci Technol. 2017; 52(6): 1052–1069.
Kareem MJ, Al-Hamdani AAS, JirjeesVY, Khan ME, Allaf AW and Al Zoubi W. Preparation, spectroscopic study of Schiff base derived from dopamine and metal Ni (II), Pd (II), and Pt (IV) complexes, and activity determination as antioxidants. J Phys Org Chem. 2020; 34(3): 1-15.
Al Zoubi W, VianYJ, Veyan TS, Al‐Hamdani AAS, Ahmed AD, Yang GK. Synthesis and bioactivity studies of novel Schiff bases and their complexes. J phys org chem. 2019; e4004: 1-7.
Al Zoubi W, Mohamed SG, Al-Hamdani AAS, Mahendradhany AP, Yang GK. Acyclic and cyclic imines and their metal complexes: recent progress in biomaterials and corrosion applications. RSC Adv. 2018; 8(41): 23294-23318.
Selma B,Sedat SB. Cobalt(II) and Manganese(II) Complexes of NovelSchiff Bases, Synthesis, Charcterization, and Thermal, Antimicrobial, Electronic, and Catalytic Features. Adv Chem. 2014; 2014(506851): 1-12.
Al-Hamdani AAS, Hamoodah RG. Transition metal complexes with tridentate ligand: preparation, spectroscopic characterization, thermal analysis and structural studies. Baghdad Sci J. 2016; 13(4): 770-781.
Samy ME, Moamen SR, FawziahAA,Reham ZH. Situ Neutral System Synthesis, Spectroscopic, and Biological Interpretations of Magnesium(II), Calcium(II), Chromium(III),Zinc(II), Copper(II) and Selenium(IV) Sitagliptin Complexes. Int JEnviron Res Public Health. 2021; 18(8030): 1-19.
Obaid SM, Amer JJ, Al-Hamdani AAS. Synthesis, Characterization and Biological Activity of Mixed Ligand Metal Salts Complexes with Various Ligands. J Phys Conf Ser. 2020; 1660 (012028): 1-14
Jirjees VY, Suleman VT, Al-Hamdani AAS, Ahmed SD. Preparation, Spectroscopic Characterization and Theoretical Studies of Transition Metal Complexes with 1-[(2-(1H-indol-3-yl) ethylimino) methyl] naphthalene-2-ol Ligand. Asian J Chem. 2019; 31(11): 2430-8.
Al-Hamdani AAS, Al-Luhaibi RS. Determination Antioxidant Activity for Metal Ion Complexes and Theoretical Treatment. Res J Pharm. Biol Chem Sci. 2017 Sep1; 8(5): 164-77.
Downloads
Published
Issue
Section
License
Copyright (c) 2022 Baghdad Science Journal
This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
