Synthesis and investigation of structural and optical properties of CdO: Ag nanoparticles of various concentrations
DOI:
https://doi.org/10.21123/bsj.2023.7292Keywords:
Keywords: AFM, CdO Nanoparticles Doped Ag , FTIR, method of Precipitation , UV, SEM.Abstract
This study discussed the effects of doping with silver (Ag) on the optical and structural properties of
CdO nanoparticles at different concentrations 0, 1, 2, 3, 4, 5 wt% prepared by the precipitation method. The
materials were annealed at 550˚C for 1 h. The structural, topographical, and optical properties were
diagnosed by X-ray diffraction analysis, atomic force instrument, and visible and ultraviolet spectrometers.
The results show that the average diameter of the grains depends on the percentage of added silver to the
material, as the diameter decreased from 88.8 to 59.7 nm, and it was found that the roughness increased from
5.56 to 26.5. When studying the optical properties, it was noted that the energy gap was 2.53ev for the pure
sample and decreased to 2.38 When 5% of silver concentration was added to cadmium oxide
Received 5/4/2022
Revised 4/9/2022
Accepted 5/9/2022
Published Online First 20/3/2023
References
Madeeha N, Faiza Z G, Saad H, Abdul Mannan, Sania N, Joham S A and Muhammad Z . Green and Chemical Syntheses of CdO NPs: A Comparative Study for Yield Attributes, Biological Characteristics, and Toxicity Concerns. ACS Omega.2020;5:5739-5747.
-Dutta D, Das B. Scope of green nanotechnology towards the amalgamation of green chemistry for a cleaner environment: A review on synthesis and applications of green nanoparticles.Monitoring and Management .2021;15:100418.
- Dinparvar S, Bagirova M, Allahverdiyev A, Abamor E, Safarov T, Aydogdu M, et al. Nanotechnology-based new approach in the treatment of breast cancer: Biosynthesized silver nanoparticles using Cuminum cyminum L. seed extract.Journal of Photochemistry and Photobiology B: Biology .2020; 208:111902.
- Bhosale H,Kambale A,Kokate A,Rajpure K.Structural, optical and electrical properties of chemically sprayed CdO thin films.Materials Science and Engineering :B.2005;122(1):67-71.
- Pugazhendhi A,Shobana S,Nguyen D.Banu J,Sivagurunathan P,Chang SW,et al.Application of nanotechnology (nanoparticles) in dark fermentative hydrogen production.International Journal of Hydrogen Eergy.2019;44(3):1431-1440.
- Fall A,Sackey J,Mayedwa N,Ngom BD. Investigation of structural and optical properties of CdO nanoparticles via peel of Citrus x sinensis.Material Today: Proceedings.2021;36:298-302.
- K.Mohanraj K, Balasubramaniana D, Chandrasekaran J. Synthesis and characterization of ruthenium-doped CdO nanoparticle and its n-RuCdO/p-Si junction diode application. Journal of Alloys and Compounds.2019;779: 762-775.
- Wang T, Kou X, Zhao I, Sun P, Liu C, Wang Y, et al. Flower-like ZnO hollow microspheres loaded with CdO nanoparticles as a high-performance sensing material for gas sensors.sensors and Actuators B: Chemical.2017;250:692-702.
- Anitha M, Saravanakumar K, Anitha N, Amalraj L. Influence of a novel co-doping (Zn + F) on the physical properties of nanostructured (1 1 1) oriented CdO thin films applicable for window layer of the solar cell. Applied Surface Science.2018;443: 55-67.
- Xaba T, Moloto MJ, Malik M, Moloto N. The Influence of Temperature on the Formation of Cubic Structured CdO Nanoparticles and Their Thin Films from Bis(2-hydroxy-1-naphtha aldehyde)cadmium(II) Complex via Thermal Decomposition Technique. Journal of Nanotechnology .2017;2017:1-11
Wongcharoen N, Gaewdang T, Wongcharoen T. Electrical Properties of Al-Doped CdO Thin Films Prepared by Thermal Evaporation in Vacuum. Energy Procedia. 2012, 15, 361–370.
Alam M,Uddin MT, Abdullah M , Mohammed M, Islam M. Detection of L-Tyrosine by the electrochemical method based on binary mixed CdO/SnO2 nanoparticles. Measurement .2020;163 :107990.
Thambidurai M, Muthukumarasamy N, Ranjitha A, Velauthapillai D. Structural and optical properties of Ga-doped CdO nanocrystalline thin films. Superlattices Microstruct. 2015, 86, 559–563.
Zheng B, Hu W. Influence of substrate temperature on the structural and properties of In-doped CdO films prepared by PLD. J. Semicond. 2013, 34, 053003.
-Jeevitesh K, Trilok K, Vinod K, Swart H ,and Purohit L. Controlled sol-gel synthesis of oxygen sensing CdO: ZnO hexagonal particles for different annealing temperatures.The Royal Society of Chemistry .2019; 9: 31316–31324.
Yüksel M, ¸Sahin B, Bayansal F. Nanostructured CdO films grown by the SILAR method: Influence of silver-doping on the morphological, structural and optical properties. Ceram. Int. 2016, 42, 6010–6014.
Malachová K, Praus P, Rybková Z, Kozák O. Antibacterial and antifungal activities of silver, copper and zinc montmorillonites. Appl. Clay Sci. 2011, 53, 642–645.
Saravanakumar K, Muthuraj V, Jeyaraj M. The design of novel visible-light-driven Ag/CdO as smart nanocomposite for photodegradation of different dye contaminants. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 2018, 188, 291–300.
Mohammed A, Bachtiar D, Siregar J, Rejab M. Effect of sodium hydroxide on the tensile properties of sugar palm fibre reinforced thermo plastic polyurethane composites. J Mech Eng Sci. 2016; 10(1): 1765–77.
Muliyadi L, Doyan A, Susilawati S, Hakim S. Synthesis of SnO2 Thin Layer with a Doping Fluorine by Sol-Gel Spin Coating Method. JPPIPA. 2019;5(2):175–8. https://dx.doi.org/10.29303/jppipa.v5i2.257
Thoms J, Sreekanth P, Philip R, Abraham K. Morphology dependent nanosecond and ultrafast optical power limiting of CdO Nnomorphology types. RSC Adv.2015; 5: 3517-35025.
Salem A. Silver-doped cadmium oxide nanoparticles: Synthesis, structural and optical properties. Eur Phys J Plus .2014; 129: 263
Laith A, Asmaa H, Ehssan S . Silver and Cadmium Mattel segment Doping by DC Sputtering. IOP Conference Series, Materials Science and Engineering. IOP Conf Ser Mater Sci Eng. 2020;928: 072075.
Praveen P,Jothibas M,Elayaraja M. Experimental investigation of the inhibitory behaviour of CdOnanoparticles on co-precipitation method.JASC.2018;5(10):451-459.
Mustapha S, Tijani J, Ndamitso M, Abdulkareem A, Shuaib D T, Amigun A T. Facile synthesis and characterization of TiO 2 nanoparticles: X-ray peak profile analysis using Williamson–Hall and Debye–Scherrer methods. International Nano Letters.2021 April;11: 241-261
Mandal R, Purkayastha M, Majumder T, Kumar M, Tapas M, Moushumi D. Silver modified cadmium oxide-A novel material for enhanced photodegradation of malachite green. Optik. 2019; 180:174-182.
Anitha M, Tamilnayagam V, Anitha N, Pakiyaraj K, Amalr L. Temperature dependence of general properties of CdO thin films prepared by nebulized spray pyrolysis technique. Int J Adv Res Manag. Architecture Tech En. 2016; 20: 204-213.
Duha S, Nada K, Ruqayah A. Preparation and study of the Structural, Morphological and Optical properties of pure Tin Oxide Nanoparticle doped with Cu. Baghdad Sci J. 2021: 660-668. http://dx.doi.org/10.21123/bsj.2022.19.3.0660.
Haneen S, Nada K. Preparing and Studying Structural and Optical Properties of Pb1-xCdxS
Nanoparticles of Solar Cells Applications. Baghdad Sci.J. 2021; 18(3): 640-648.
Dahman Y.functioal materials for engineers. 1St ed. Elsevier. Ch.1, an introduction to Nanotecnology. 2017; 14: P .282.
Iniya M, Lawrence M. Synthesis of pure Cu and Zn doped CdO nanoparticles by co-precipitation method for supercapacitor applications.Vacuum.2019; 162: 208-213.DOI: 10.1016/j.vacuum.2019.01.042
Rajathi S, Kirubavathi K,and Selvaraju K.Preparation of nanocrystalline Cd-doped PbJS thin films and their structural and opyical properties .Journal of Taibah University Science. 2017;11:1296-1305.
Xinming Y, Meng Z, Pingfang H, Xiaoping L. Synthesis and Characterization of Cdo Nanoparticles Prepared via Chemical Precipitation and Sol-Gel Techniques.Pharm. Chem. J. 2018; 5(1): 232-239.
Ranjith K, Albert A, Jayakumar G, Dhayal A, Karthick S. Properties of CdO and Fe doped CdO Nanoparticles. Mate Today: proc. 2016; 3(6): 1378-1382.
Tripathi R, Dutta A,Das S, Kumar A , Sinha T. Dielectric relaxation of CdO nanoparticles .Appl Nanosci. 2016; 6: 175-181.
Aldwayyan AS, Al-Jekhedab FM, Hammouti M, Hadda B, Suleiman TB, Ward I. Synthesis and characterization of CdO nanoparticles starting from organometallic dampen-CdI2 complex. Int J Electrochem Sci.2013;8(10506): e10514.
Nada K. Abbas, Al-Ogaidi I, Alsalmani M, Sara T. microwave-assisted synthesis of ZnS&ZnS-Ag nanoparticles and its antibacterial activity. GJBB. 2017; 6 (4): 677-682.
Shamaila S ,Bano T ,Sajjad A. Efficient visible light magnetic modified iron oxide photocatalysts. Ceram Int. 2017;43(17):14672–7.
Ziad T, Mohammed A. Growth and characterization of ZnO nanostructures using a pulsed laser. J Opt. 2013; 42: 194–202.
Vijaykarthik D, Kirithika M, Prithivikumaran N, and Jeyakumaran N. Synthesis and characterization of Cadmium Oxide nanoparticles for antimicrobial activity. J.Nano Dimens.2014; 5(6): 557-562.
Downloads
Published
Issue
Section
License
Copyright (c) 2023 Baghdad Science Journal
This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
