Eco-Friendly Synthesized of CuO Nanoparticles Using Anchusa strigosa L. Flowers and Study its Adsorption Activity
DOI:
https://doi.org/10.21123/bsj.2023.7444Keywords:
Anchusa strig1osa L, Congo Red dye, Freundlich Isotherm, Halsey Isotherm, Langmuir Isotherm, Temkin Isotherm.Abstract
Environmentally friendly copper oxide nanoparticles (CuO NPs) were prepared with a green synthesis route via Anchusa strigosa L. Flowers extract. These nanoparticles were further characterized by FTIR, XRD and SEM techniques. Removing of Gongo red from water was applied successfully by using synthesized CuO NPs which used as an adsorbent material. It was validated that the CuO NPs eliminate Congo red by means of adsorption, and the best efficiency of adsorption was gained at pH (3). The maximum adsorption capacity of CuO NPs for Congo red was observed at (35) mg/g. The equilibrium information for adsorption have been outfitted to the Langmuir, Freundlich, Temkin and Halsey adsorption isotherm types. The temperature thermodynamic parameters like ΔG°, ΔH° and ΔS° have been calculated.
Received 22/5/2022, Accepted 26/7/2022, Published Online First 20/1/2023
References
Amanuel L, Adefris D, Ajaw E, Bekele N, Abinet A. Dye extraction and cotton dyeing from Peach leaf. Curr Trends Fashion Technol Textile Eng 2019; 5(3): 68-74.
Bick R, Halsey E, Ekenga CC. The global environmental injustice of fast fashion. Environ. Health. 2018; 17(1): 1-4.
Ali IH. Removal of Congo Red Dye From Aqueous Solution Using Eco-Friendly Adsorbent of Nanosilica. Baghdad Sci J. 2021; 18(2): 0366-.
Mafu LD, Mamba BB, Msagati TA. Synthesis and characterization of ion imprinted polymeric adsorbents for the selective recognition and removal of arsenic and selenium in wastewater samples. J Saudi Chem Soc. 2016; 20(5): 594-605.
Janin A, Zaviska F, Drogui P, Blais J-F, Mercier G. Selective recovery of metals in leachate from chromated copper arsenate treated wastes using electrochemical technology and chemical precipitation. Hydromet. 2009; 96(4): 318-26.
Mohan D, Pittman Jr CU. Arsenic removal from water/wastewater using adsorbents—a critical review. J Hazard. Mater. 2007;142(1-2):1-53.
Han B, Runnells T, Zimbron J, Wickramasinghe R. Arsenic removal from drinking water by flocculation and microfiltration. Desalination. 2002; 145(1-3): 293-8.
Pous N, Casentini B, Rossetti S, Fazi S, Puig S, Aulenta F. Anaerobic arsenite oxidation with an electrode serving as the sole electron acceptor: a novel approach to the bioremediation of arsenic-polluted groundwater. J Hazard Mater. 2015; 283: 617-22.
Al-Mahmoud SM. Adsorption of Some Alephatic Dicarboxylic Acids on Zinc Oxide: A kinetic and Thermodynamic Study. Baghdad Sci J. 2019; 16(4): 0892-.
Usman M, Katsoyiannis I, Rodrigues JH, Ernst M. Arsenate removal from drinking water using by-products from conventional iron oxyhydroxides production as adsorbents coupled with submerged microfiltration unit. Environ Sci Pollut Res. 2021; 28(42): 59063-75.
Verma N, Kumar N. Synthesis and biomedical applications of copper oxide nanoparticles: an expanding horizon. ACS Biomater Sci Eng . 2019; 5(3): 1170-88.
Akintelu SA, Folorunso AS, Folorunso FA, Oyebamiji AK. Green synthesis of copper oxide nanoparticles for biomedical application and environmental remediation. Heliyon. 2020; 6(7): e04508.
Adil SF, Assal ME, Khan M, Al-Warthan A, Siddiqui MRH, Liz-Marzán LM. Biogenic synthesis of metallic nanoparticles and prospects toward green chemistry. Dalton Trans 2015;44(21):9709-17.
Shaik MR, Albalawi GH, Khan ST, Khan M, Adil SF, Kuniyil M, et al. “Miswak” based green synthesis of silver nanoparticles: evaluation and comparison of their microbicidal activities with the chemical synthesis. Molecules. 2016; 21(11): 1478.
Saif S, Tahir A, Asim T, Chen Y. Plant mediated green synthesis of CuO nanoparticles: comparison of toxicity of engineered and plant mediated CuO nanoparticles towards Daphnia magna. Nanomaterials. 2016; 6(11): 205.
Zahid A. Review of Arsenic Contamination in the Shallow Groundwater of the Bengal Basin, Bangladesh. J Water Sci Eng 2020; 1(5): 1-7.
Abdullabass HK, Jawad AM, Aljamali NM. Synthesis of drugs derivatives as inhibitors of cancerous cells. Biochem Cell Arch. 2020; 20(2): 5315-22.
Taghavi Fardood S, Moradnia F, Ramazani A. Green synthesis and characterisation of ZnMn2O4 nanoparticles for photocatalytic degradation of Congo red dye and kinetic study. Micro Nano Lett 2019; 14(9): 986-91.
Akinyeye OJ, Ibigbami TB, Odeja O. Effect of chitosan powder prepared from snail shells to remove lead (II) ion and nickel (II) ion from aqueous solution and its adsorption isotherm model. Am J Appl Chem. 2016; 4: 146.
De Castro MLFA, Abad MLB, Sumalinog DAG, Abarca RRM, Paoprasert P, de Luna MDG. Adsorption of methylene blue dye and Cu (II) ions on EDTA-modified bentonite: isotherm, kinetic and thermodynamic studies. Sustain Environ Res .2018; 28(5): 197-205.
Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum.J Am Chem soc. 1918; 40(9): 1361-403.
Freundlich H. Über die adsorption in lösungen. Z phys Chem .1907; 57(1): 385-470.
Temkin M, Pyzhev V. Recent modifications to Langmuir isotherms. Acta Physiochim URSS. 1940; 12: 217- 225
Halsey G. Physical adsorption on non‐uniform surfaces. J chem phys. 1948; 16(10): 931-7.
Downloads
Published
Issue
Section
License
Copyright (c) 2023 Baghdad Science Journal
This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
