Effect of Chromium (VI) on the Oxidation of Methylene Blue Dye by Fe3O4/ Chitosan Composite

Main Article Content

Yaman K. Sadiq
https://orcid.org/0000-0002-1651-786X
Khulood A. Saleh
https://orcid.org/0000-0002-5118-7392

Abstract

     Heavy metal ion removal from industrial wastewater treatment systems is still difficult because it contains organic contaminants. In this study, functional composite hydrogels with photo Fenton reaction activity were used to decompose organic contaminants. Fe3O4 Nanoparticle, chitosan (CS), and other materials make up the hydrogel. There are different factors that affected Photo-Fenton activity including (pH, H2O2 conc., temp., and exposure period). Atomic force microscopy was used to examine the morphology of the composite and its average diameter (AFM). After 60 minutes of exposure to UV radiation, CS/ Fe3O4 hydrogel composite had degraded methylene blue (M.B.) dye by 92 percent. In the meantime, following an 1hour of visible irradiation, COD (Chemical Oxygen Demand) dropped to 6.1 mg/l.

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1.
Effect of Chromium (VI) on the Oxidation of Methylene Blue Dye by Fe3O4/ Chitosan Composite. Baghdad Sci.J [Internet]. 2023 Dec. 1 [cited 2024 Dec. 24];20(6). Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/7678
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How to Cite

1.
Effect of Chromium (VI) on the Oxidation of Methylene Blue Dye by Fe3O4/ Chitosan Composite. Baghdad Sci.J [Internet]. 2023 Dec. 1 [cited 2024 Dec. 24];20(6). Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/7678

References

Su Dihan, J Liu, Y Zhong. Enhancing mechanical properties of silk fibroin hydrogel through restricting the growth of β-sheet domains. ACS Appl Mater Interfaces. 2017; 9(20): 17489-17498. ‏

https://doi.org/10.1021/acsami.7b04623

Mohammed Eman A, Souad A Mousa. Degradation of Dazomet by thermal Fenton and photo-Fenton processes under UV and sun lights at different temperatures. Baghdad Sci J. 2018; 15.2: 158-168. ‏

https://doi.org/10.21123/bsj.2018.15.2.0158

Sharma Abha, Ahmad Javed A, Flora S J S. Application of advanced oxidation processes and toxicity assessment of transformation products. Environ Res. 2018; 167: 223-233. ‏

https://doi.org/10.1016/j.envres.2018.07.010

‏Rueda Márquez, Juan José, Manuel M. Toxicity reduction of industrial and municipal wastewater by advanced oxidation processes (Photo-Fenton, UVC/H2O2, Electro-Fenton and Galvanic Fenton): a review. Catalysts. 2020; 10(6): 612. ‏ https://doi.org/10.3390/catal10060612

Al-Saade Khulood Abid Saleh; Al-Saidi Shatha Fadel; Juad Hamdia Hateem. Degradation of brilliant green by using a bentonite clay-based fe nanocomposite film as a heterogeneous photo-fenton catalyst. Baghdad Sci J. 2016; 13(3): 524-530. http://dx.doi.org/10.21123/bsj.2016.13.3.0524

Bibi Sidra, Awais A, Mohsin A. Photocatalytic degradation of malachite green and methylene blue over reduced graphene oxide (rGO) based metal oxides (rGO-Fe3O4/TiO2) Nanocomposite under UV-visible light irradiation. J Environ Chem Eng. 2021; 9(4): 105580. ‏

https://doi.org/10.1016/j.jece.2021.105580

Cazetta A L, Vargas A M, Nogami E M, Kunita M H, Guilherme M R, Martins A C, et al. NaOH-activated carbon of high surface area produced from coconut shell: Kinetics and equilibrium studies from the methylene blue adsorption. J Chem Eng. 2011; 174(1): 117-125. ‏

https://doi.org/10.1016/j.cej.2011.08.058

Freire T M, Dutra L, Queiroz D, Ricardo S, Barreto K, Denardin J C, et al. Fast ultrasound assisted synthesis of chitosan-based magnetite nanocomposites as a modified electrode sensor. Carbohyd Polym. 2016; 151: 760-769.

https://doi.org/10.1016/j.carbpol.2016.05.095

Muhi-Alden Yasser Yousef, Khulood A Saleh. Removing of Methylene Blue Dye from its Aqueous Solutions Using Polyacrylonitrile/Iron Oxide/Graphene Oxide. Iraqi J Sci. 2022; 2320-2330. https://doi.org/10.24996/ijs.2022.63.6.1

Kadhim Hakim H, Khulood A Saleh. Removing of copper ions from industrial wastewater using graphene oxide/chitosan nanocomposite. Iraqi J Sci. 2022; 1894-1908. ‏ https://doi.org/10.24996/ijs.2022.63.5.4

Sahib Saddam, Zaman W, F Ullah. Organometallic assembling of Chitosan‐Iron oxide nanoparticles with their antifungal evaluation against Rhizopus oryzae. Appl Organomet Chem. 2019; 33(11): e5190.

https://doi.org/10.1002/aoc.5190

Kadhim Hakim H, Khulood A Saleh. Removing cobalt ions from industrial wastewater using chitosan. Iraqi J Sci. 2022; 3251-3263. https://doi.org/10.24996/ijs.2022.63.8.1

Akbari Abbas, Sadani M. Managing sulfate ions produced by sulfate radical-advanced oxidation process using sulfate-reducing bacteria for the subsequent biological treatment. J Environ Chem Eng. 2018; 6(5): 5929-5937. ‏

https://doi.org/10.1016/j.jece.2018.09.004

Heidari Maryam, Sadeghi M. Degradation of diazinon from aqueous solutions by electro-Fenton process: effect of operating parameters, intermediate identification, degradation pathway, and optimization using response surface methodology (RSM). Sep Sci Technol. 2021; 56(13): 2287-2299. ‏

https://doi.org/10.1080/01496395.2020.1821060

Vinu R, Giridhar Madras. Kinetics of sonophotocatalytic degradation of anionic dyes with nano-TiO2. Environ Sci Technol. 2009; 43(2): 473-479. ‏https://doi.org/10.1021/es8025648

Arrhenius Svante. Über die Dissociationswärme und den Einfluss der Temperature auf den Dissociations grad der Elektrolyte. ZPC. 1889; 4(1): 96-116.

https://doi.org/10.1515/zpch-1889-0408

Behin Jamshid, Mahmoudi M. Sodium hypochlorite as an alternative to hydrogen peroxide in Fenton process for industrial scale. Water Res. 2017; 121: 120-128. ‏

https://doi.org/10.1016/j.watres.2017.05.015

Zhang Kai,W Yang, K Zhang. Laccase immobilized on chitosan-coated Fe3O4 nanoparticles as reusable biocatalyst for degradation of chlorophenol. J Mol Struct. 2020; 1220: 128769. ‏https://doi.org/10.1016/j.molstruc.2020.128769

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