Eco-Friendly Method for Removal of Some Heavy Metals in Water; Physical and Analytical Study

Authors

  • Khaled Elgendy Department of Chemistry, Faculty of Science, Zagazig University, Zagazig, Egypt.
  • Mounir Saad Department of Chemistry, Faculty of Science, Zagazig University, Zagazig, Egypt.
  • Atef Amer Department of Chemistry, Faculty of Science, Zagazig University, Zagazig, Egypt.
  • Abdel Nasser Mohammed Department of Chemistry, Faculty of Science, Zagazig University, Zagazig, Egypt.

DOI:

https://doi.org/10.21123/bsj.2024.8185

Keywords:

Adsorption, Agricultural waste, Adsorption isotherm , Cyperus papyrus, Heavy metals, Nano adsorbent..

Abstract

This study sought to examine the removal of some heavy metal ions from an aqueous media utilizing an adsorbent made from waste materials Cyperus papyrus and nano Cyperus papyrus. Because of their abundance of (OH) groups, Cyperus papyrus biomaterials are promising adsorbents for removing heavy metals. Therefore, this study proposed removing Al, Fe, Pb, and Cd from aqueous solutions using dried Cyperus papyrus. The effectiveness of removal was determined to be in this sequence Fe >Pb> Cd>Al. In another method, some of the cyperus papyrus was converted to nanopowder and used to investigate the elimination of Pb and Cd from aqueous solutions, and the results showed that the nano cyperus papyrus is more effective than normal cyperus papyrus. Normal cyperus papyrus was applied into two samples; the first was a sewage water sample, and the other was ground water. The Freundlich isothermal adsorption method worked better for the adsorption of Al, Fe, Pb, and Cd using Cyperus papyrus, and it also demonstrated an ion exchange process that took place in the adsorption surface layer that is uneven. Cyperus papyrus had a high affinity for adsorbing heavy metals Al, Fe, Pb, and Cd without additional chemicals. The results revealed that the used adsorbent had been a promising material for treating some contaminants and was eco-friendly.

References

Mishra S, Bhargava RN, More N, Yadav A, Zainith S, Mani S, et al. Heavy metal contamination: an alarming threat to environment and human health. Environ Biotechnol Sustain Futur. 2019; 103–25. https://doi.org/10.1007/978-981-10-7284-0_5

Sonone SS, Jadhav S, Sankhla MS, Kumar R. Water contamination by heavy metals and their toxic effect on aquaculture and human health through food Chain. Lett Appl NanoBioScience. 2020; 10(2): 2148-66. https://doi.org/10.33263/LIANBS102.21482166.

Abdullah N, Yusof N, Lau WJ, Jaafar J, Ismail AF. Recent trends of heavy metal removal from water/wastewater by membrane technologies. J Ind Eng Chem. 2019; 76: 17–38. https://doi.org/10.1016/j.jiec.2019.03.029.

Qasem NAA, Mohammed RH, Lawal DU. Removal of heavy metal ions from wastewater: A comprehensive and critical review. Npj Clean Water. 2021; 4(1): 1-15?. https://doi.org/10.1038/s41545-021-00127-0.

Sheth Y, Dharaskar S, Chaudhary V, Khalid M, Walvekar R. Prospects of titanium carbide-based MXene in heavy metal ion and radionuclide adsorption for wastewater remediation: A review. Chemosphere. 2022; 133563. https://doi.org/10.1016/j.chemosphere.2022.133563.

Abd Mousa S. The A Comparative Study of the Adsorption of Crystal Violet Dye from Aqueous Solution on Rice Husk and Charcoal. Baghdad Sci J. 2020; 17(1 (Suppl.)): 295. https://doi.org/10.21123/bsj.2020.17.1(Suppl.).0295

James A, Yadav D. Valorization of coconut waste for facile treatment of contaminated water: a comprehensive review (2010–2021). Environ Technol Innov. 2021; 24: 102075. https://doi.org/10.1016/j.eti.2021.102075.

Wang H, Zhang M, Lv Q. Removal efficiency and mechanism of Cr (VI) from aqueous solution by maize straw biochars derived at different pyrolysis temperatures. Water. 2019; 11(4): 78.https://doi.org/10.3390/w11040781.

Sireesha S, Upadhyay U, Sreedhar I. Comparative studies of heavy metal removal from aqueous solution using novel biomass and biochar-based adsorbents: characterization, process optimization, and regeneration. Biomass Convers Biorefinery. 2022; 1–13. https://doi.org/10.1007/s13399-021-02186-2

Taha AA, Hameed NJ, Rashid FH. Preparation and characterization of (hyacinth plant/chitosan) composite as a heavy metal removal. Baghdad Sci J. 2019; 16(4): 865–70. https://doi.org/10.21123/bsj.2019.16.4.0865.

Hassanein HD, Nazif NM, Shahat AA, Hammouda FM, Aboutable E-SA, Saleh MA. Chemical diversity of essential oils from Cyperus articulatus, Cyperus esculentus and Cyperus papyrus. J Essent Oil Bear Plants. 2014; 17(2): 251–64. https://doi.org/10.1080/0972060X.2013.813288.

Taha AS, Salem MZM, Abo Elgat WAA, Ali HM, Hatamleh AA, Abdel-Salam EM. Assessment of the impact of different treatments on the technological and antifungal properties of papyrus (Cyperus papyrus L.) sheets. Materials (Basel). 2019; 12(4): 620.https://doi.org/10.3390/ma12040620.

Hamad MTMH. Comparative study on the performance of Typha latifolia and Cyperus Papyrus on the removal of heavy metals and enteric bacteria from wastewater by surface constructed wetlands. Chemosphere. 2020; 127551. https://doi.org/10.1016/j.chemosphere.2020.127551.

Jiang W, Han G, Zhang Y, Wang M. Fast compositional analysis of ramie using near-infrared spectroscopy. Carbohydr Polym. 2010; 81(4): 937–41.https://doi.org/10.1111/gcbb.12392.

Rosado MJ, Bausch F, Rencoret J, Marques G, Gutiérrez A, Rosenau T, et al. Differences in the content, composition and structure of the lignins from rind and pith of papyrus (Cyperus papyrus L.) culms. Ind Crops Prod. 2021; 174: 114226.https://doi.org/10.1016/j.indcrop.2021.114226.

Muthuri FM, Jones MB, Imbamba SK. Primary productivity of papyrus (Cyperus papyrus) in a tropical swamp; Lake Naivasha, Kenya. Biomass. 1989; 18(1): 1–14.https://doi.org/10.1016/0144-4565(89)90077-2.

Gaudet J. Papyrus and the Pharaoh's Treasure: An Ecological Perspective. Near East Archaeol. 2019; 82(4): 248–55. https://doi.org/10.1086/704258.

Karlen SD, Free HCA, Padmakshan D, Smith BG, Ralph J, Harris PJ. Commelinid monocotyledon lignins are acylated by p-coumarate. Plant Physiol. 2018; 177(2): 513–21.https://doi.org/10.1104/pp.18.00298.

Elnaggar A, Fitzsimons P, Nevin A, Watkins K, Strlič M. Viability of laser cleaning of papyrus: conservation and scientific assessment. Stud Conserv. 2015; 60(sup1): S73–81.https://doi.org/10.1179/0039363015Z.000000000211.

Menei E. Use of East Asian materials and techniques on papyrus: Inspiration and adaptation. In: International Conference of the Icon Book & Paper Group. 2015. p. 10.

Katuscak S, Polovka M, Vrska M, Tino R, Jablonsky M. The effect of paper degradation on uncertainty of determination of initial lignin content. e-Preservation Sci. 2006; 3: 69–72.

Hassan RRA, Mahmoud SMA, Nessem MA, Aty RTA, Ramzy MG, Dessoky ES, et al. Hydroxypropyl cellulose loaded with ZnO nanoparticles for enhancing the mechanical properties of Papyrus (Cyperus papyrus L.) Strips. BioResources. 2021; 16(2): 2607–25. https://doi.org/10.15376/biores.16.2.2607-2625.

Bausch F, Rosado MJ, Rencoret J, Marques G, Gutiérrez A, Graf J, et al. Papyrus production revisited: differences between ancient and modern production modes. Cellulose. 2022; 29(9): 4931–50. https://doi.org/10.1007/s10570-022-04573-y.

Scora PE, Scora RW. Some observations on the nature of Papyrus bonding. J Ethnobiol. 1991; 11(2): 193–202. https://doi.org/10.1080/14786435708243833.

Basile C.A method making papyrus and fixing and preserving it by means of a chemical treatment . Stud Conserv.1972;17(sup1):901–905.https://doi.org/10.1179/sic.1972.17.s1.019i.

Baird R, Rice EW, Eaton AD, Bridgewater L, Federation WE. Standard Methods for the Examination of Water and Wastewater. American Public Health Association; 2017.

Thirunarayanan G. Ultrasonicated synthesis of bio-potent sulphonamides. World Sci News. 2019; 119: 125–38.

Zhao F, Repo E, Song Y, Yin D, Hammouda S Ben, Chen L, et al. Polyethylenimine-cross-linked cellulose nanocrystals for highly efficient recovery of rare earth elements from water and a mechanism study. Green Chem. 2017; 19(20): 4816–28.http://dx.doi.org/10.1039/C7GC01770G.

Ingham B, Toney M F. 1 - X-ray diffraction for characterizing metallic films (K. Barmak & K. B. T.-M. F. for E. Coffey Optical and Magnetic Applications (eds.). 2014; 3–38. Woodhead Publishing. https://doi.org/10.1533/9780857096296.1.3

Ramirez, L. M. F., Rihouey, C., Chaubet, F., Le Cerf, D., & Picton, L. Characterization of dextran particle size: How frit-inlet asymmetrical flow field-flow fractionation (FI-AF4) coupled online with dynamic light scattering (DLS) leads to enhanced size distribution. J Chromatogr A. 2021; 1653: 462404. https://doi.org/10.1016/j.chroma.2021.462404.

Saravanan A, Karishma S, Kumar PS, Varjani S, Yaashikaa PR, Jeevanantham S, et al. Simultaneous removal of Cu(II) and reactive green 6 dye from wastewater using immobilized mixed fungal biomass and its recovery. Chemosphere. 2021; 271: 129519. https://doi.org/10.1016/j.chemosphere.2020.129519.

Darian D, Marholm S, Mortensen M, Miloch WJ. Theory and simulations of spherical and cylindrical Langmuir probes in non-Maxwellian plasmas. Plasma Phys. Control. Fusion. 2019; 61(8): 85025. https://doi.org/10.1088/1361-6587/ab27ff.

Togue Kamga F. Modeling adsorption mechanism of paraquat onto Ayous (Triplochiton scleroxylon) wood sawdust. Appl Water Sci. 2018; 9(1): 1-7 https://doi.org/10.1007/s13201-018-0879-3.

Al-Ghouti MA, Da'ana DA. Guidelines for the use and interpretation of adsorption isotherm models: A review. J Hazard Mater. 2020; 393: 122383.https://doi.org/10.1016/j.jhazmat.2020.122383.

Chen X, Hossain MF, Duan C, Lu J, Tsang YF, Islam MS, et al. Isotherm models for adsorption of heavy metals from water - A review. Chemosphere. 2022; 307: 135545.https://doi.org/10.1016/j.chemosphere.2022.135545.

Chu KH. Revisiting the Temkin Isotherm: Dimensional Inconsistency and Approximate Forms. Ind Eng Chem Res. 2021; 60(35): 13140–7.https://doi.org/10.1021/acs.iecr.1c01788.

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Eco-Friendly Method for Removal of Some Heavy Metals in Water; Physical and Analytical Study. Baghdad Sci.J [Internet]. [cited 2024 Sep. 27];22(3). Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8185