Synthesis, characterization, industrial and biological studies of azo dye ligand and their some metallic ions
DOI:
https://doi.org/10.21123/bsj.2024.8319Keywords:
azo dyes, biological activity, 4-aminoantipyrine, metal complexes, textile industry.Abstract
4-((2-hydroxy-3,5-dinitrophenyl)diazenyl)-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one was produced through the reaction of diazonium salt from 4-amino antipyrine with 2,4-dinitrophenol. This ligand is examined by (UV-Vis, FTIR,1H,13CNMR, and LC-Mass) spectral techniques and micro elemental analysis (C.H.N.O). Co(II), Ni(II), Cu(II), and Zn(II) complexes were also performed and depicted. Metal chelates were distinguished by utilizing flame atomic absorption, infrared analysis, and elemental, visible, as well as ultraviolet spectroscopy, in addition to conductivity and magnetic quantification. Methods of mole ratio and continuous contrast have been studied to determine the nature of the compounds. Beer's law was followed throughout a condensation reach of about 1×10-4 - 3×10-4 M/L. A higher molar absorbance was observed for compound solutions. Analytical data displayed all metal chelates in a 1:2 metal-ligand ratio. In general, the physicochemical data, and the octahedral geometry of the compounds are described. Compounds are tested in biological and dye studies
Received 03/01/2023,
Revised 04/08/2023,
Accepted 06/08/2023,
Published Online First 20/03/2024
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Copyright (c) 2024 Abaas Obaid Hussein , Rana Abdulilah Abbas , Jinan M. M. Al-Zinkee , AmerJ. Jarad
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