Enhancement Optical Characterized of Tin Oxide in Polymer Polyvinyl alcohol Colloid Prepared by Laser Ablation Method

Authors

  • Nadheer Jassim Mohammed Department of Physics, College of Science, Mustansiriyah University, Baghdad, Iraq.
  • Zahraa Sabah Rasheed Department of Physics, College of Science, Mustansiriyah University, Baghdad, Iraq. https://orcid.org/0000-0003-3212-7754

DOI:

https://doi.org/10.21123/bsj.2023.8494

Keywords:

Absorption coefficient, Energy gap, Nanocomposite, Poly(vinyl alcohol), Tin Oxide

Abstract

   Nanocomposites are appropriate materials to meet emerging demands resulting from advances in science and technology. Components with novel structures and better efficiency compared to conventionally processed components are required for technological advances. In this research, polymer-inorganic colloidal nanocomposites can be created by using pulsed laser ablation for tin oxide nanoparticles in polyvinyl alcohol as a host. The optical characteristics and absorption spectra were used to look into the optical characteristics of the nanocomposite. The optical band gap (Eg) was measured; indirect transition values for pure polymer polyvinyl alcohol were determined to be 5 eV and 3.5 eV for PVA-SnO2 nanocomposite. The samples were measured for their extinction coefficient (k), refractive index (n), and dielectric constant. Nanocomposites' dielectric constant decreased while their absorption coefficient, refractive index, and extinction coefficient all increased. The nanocomposites have a high absorbency in the UV region and may be utilized for covering materials to radiation protecting applications. Write a brief abstract about your paper’s subject of study. Write a brief abstract about your paper’s subject of study. Write a brief abstract about your paper’s subject of study. Write a brief abstract about your paper’s subject of study. Write a brief abstract about your paper’s subject of study. Write a brief abstract about your paper’s subject of study.

References

Bhat J S. Concerns of new technology based industries the case of nanotechnology. Technovation. 2005; 25(5): 457- 462. https://doi.org/10.1016/j.technovation.2003.09.001 .

Morget M, Neena P, Muthu M S, Sastikumar D, Balasubramanian K. Optical, phonon properties of ZnO–PVA, ZnO–GO–PVA nanocomposite free standing polymer films for UV sensing. J Mater Sci: Mater Electron. 2018; 29: 365–373. https://doi.org/10.1007/s10854-017-7925-z .

AL-Isla MA, Kader AT, AL-Husam AMA. Synthesis and characterization of some modified polyvinyl alcohol. Baghdad Sci J. 2021;1(2):295-9. https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/562 .

Aijie L, Bac L, Ji S K, Byoung K K , Jin C K. Synthesis and characterization of conducting polyaniline-copper composites. J Nanosci Nanotechnol. 2013; 13(11): 7728-7733. https://doi.org/10.1166/jnn.2013.7831

Hussain T, Jabeen S, Shehzad K, Mujahid A, Ahmad MN, Farooqi Z H, et al. Polyaniline/silver decorated-MWCNT composites with enhanced electrical and thermal properties. Polym Compos. 2018 ; 39(S3): E1346-E1353. https://doi.org/10.1002/pc.24219 .

Begum M H A, Hossain M M, Gafur M A, Kabir A H, Tanvir N I, Molla M R. Preparation and characterization of polyvinyl alcohol–starch composites reinforced with pulp. SN Appl Sci. 2019; 1: 1091. https://doi.org/10.1007/s42452-019-1111-2 .

Wang W, Zhang G. Synthesis and optical properties of high-purity CoO nanowires prepared by an environmentally friendly molten salt route. J Cryst Growth. 2009; 311(17): 4275-4280. https://doi.org/10.1016/j.jcrysgro.2009.07.014 .

Solís-Casados D, Vigueras-Santiago E, Hernández-López S, Camacho-López M A. Characterization and photocatalytic performance of tin oxide. Ind Eng Chem Res. 2009; 48(3): 1249-1252.‏ https://doi.org/10.1021/ie800604u .

Shi L, Lin H. Facile fabrication and optical property of hollow SnO2 spheres and their application in water treatment. Langmuir. 2010; 26(24): 18718-18722.‏ https://doi.org/10.1021/la103769d .

Song F, Su H, Chen J, Moon WJ, Lau WM, Zhang D. 3D hierarchical porous SnO2 derived from self-assembled biological systems for superior gas sensing application. J Mater Chem. 2012; 22(3): 1121-1126.‏ https://doi.org/10.1039/C1JM14468E .

Zahraa SR, Muhanad H A, Sanaa RS. Effect Annealing and Irradiation on Structural - Optical Properties of Tin Oxide Thin Films. J Eng Appl Sci. 2018; 13(23): 9838-9843. https://medwelljournals.com/abstract/?doi=jeasci.2018.9838.9843.‏

Mendes PG, Moreira ML, Tebcherani SM, Orlandi MO, Andres J, Li MS. SnO2 nanocrystals synthesized by microwave-assisted hydrothermal method: towards a relationship between structural and optical properties. J Nanopart Res. 2012; 14(3): 1-13. https://doi.org/10.1007/s11051-012-0750-7 .

Zhiwen J, Liwei L, Hao H, Wenbin H, Wuyi M. Progress in Laser Ablation and Biological Synthesis Processes: “Top-Down” and “Bottom-Up” Approaches for the Green Synthesis of Au/Ag Nanoparticles. Int J Mol Sci. 2022; 23(23): 14658. https://doi.org/10.3390/ijms232314658 .

Naseri F, Dorranian D. Effect of aluminum nanoparticles on the linear and nonlinear optical properties of PVA. Opt Quant Electron. 2017; 49(1): 1-15. https://doi.org/10.1007/s11082-016-0839-9 .‏

Selvi J, Mahalakshmi S, Parthasarathy V. Synthesis, Structural, Optical, Electrical and Thermal Studies of Poly(vinyl alcohol)/CdO Nanocomposite Films. J Inorg Organomet Polym .2017; 27: 1918–1926. https://doi.org/10.1007/s10904-017-0662-1 .

Prepelita P, Garoi F, Craciun V. Structural and optical characteristics determined by the sputtering deposition conditions of oxide thin films. Beilstein J Nanotechnol. 2021; 19(12): 354-365. https://doi.org/10.3762/bjnano.12.29 .

Abd El-Kader K A, Hamied S A, Mansour A B, El-Lawindy A M, El-Tantaway F. Effect of the molecular weights on the optical and mechanical properties of poly (vinyl alcohol) films. Polym Test. 2002; 21(7): 847-850. https://doi.org/10.1016/S0142-9418(02)00020-X .

Duha M A, Sami S C, Muhssen S E, Khalid H A, Nadir F H, Hadi A H. Effects of FeCl3 additives on optical parameters of PVA. J Phys Conf Ser.2018; 1003(1): 012108. https://doi.org/10.1088/1742-6596/1003/1/012108.

Haitham A H, Mohamed M A, Hamed A, Ibrahim SY. The structure analysis and optical performance of PVA films doped with Fe3+-metal for UV- limiter, and optoelectronics. Mater Res Express. 2019 ; 6(8): 6 085334.https://iopscience.iop.org/article/10.1088/2053-1591/ab2668

Kymakis E , Amaratunga GA. Optical properties of polymer-nanotube composites. Synth Met. 2004; 142(1-3): 161-167. https://doi.org/10.1016/j.synthmet.2003.08.011 .

Abdelhamied MM, Atta A, Abdelreheem AM, Farag AT, El Okr MM. Synthesis and optical properties of PVA/PANI/Ag nanocomposite films. J Mater Sci. 2020; 31(24): 22629-22641. https://doi.org/10.1007/s10854-020-04774-w .

Noha H H. The Structure and Optical Properties of Ag doped CdO Thin Film Prepared by Pulse Laser Deposition (PLD). Baghdad Sci J. 2018 ; 15(3): 300-303.‏ https://doi.org/10.21123/bsj. 2018.15.3.0300 .

Downloads

Issue

Section

article

How to Cite

1.
Enhancement Optical Characterized of Tin Oxide in Polymer Polyvinyl alcohol Colloid Prepared by Laser Ablation Method. Baghdad Sci.J [Internet]. [cited 2024 Apr. 30];21(7). Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8494