Preparation and characterization of nanocomposite textile filter for separation of the oil/water mixture using PA-PVA blends reinforced with carbon nanoparticles
DOI:
https://doi.org/10.21123/bsj.2024.9062Keywords:
Carbon nanoparticles, Electrospinning, Filtration, In-situ polymerization, Nano compositesAbstract
The electrospinning technique used to prepare a nano fibre filter under limited conditions involves (20 kV applied voltage, 15 cm gap distance, 1 ml/h: flow rate, and 0.4 mm needle diameter). Several tests for prepared materials were conducted including [scanning electron microscopy (SEM-EDX), Fourier Transform Infrared (FTIR), contact angle, and particle size analysis]. As well as, the characterization of the water/oil mixture was tested before the filtration process and after it. According to the SEM data, smooth and homogeneous nanofibers with an approximate diameter of 350 nm and open porosity morphology were produced using the electrospinning approach. The liquid particles adhere to the filter fibers and work to shrink the holes in the filter, allowing the water to pass through the filter while recovering its characteristics, according to SEM results obtained after the filtration process. According to AFM data, the majority of pores have a diameter of around 100 nm, while the minority has a diameter of more than 100 nm but less than 2500 nm. The results of the catachrestic of water were saved after filtration of a sample by the prepared filter and it closed up the normal water properties by increasing the carbon nanoparticles ratios. The infrared data (FTIR) demonstrate that there is a physical interaction between the polymeric fibers and the added carbon particles since there is a drop in the intensity of infrared radiation after the carbon particles are added to the filter fibers. The hydrophilicity property is found to rise with increasing carbon nanoparticle ratio, and contact angle data demonstrate that this characteristic reduces with increasing carbon nanoparticle ratio, going from 72 o for pure nano filter to 44 o for filter with 0.3 percentage of carbon nanoparticles.
Received 12/05/2023
Revised 06/11/2023
Accepted 08/11/2023
Published Online First 20/04/2024
References
Alesa HJ, Aldabbag BM, Salih RM. Natural pigment -poly vinyl alcohol nano composites thin films for solar cell. Baghdad Sci J. 2020 Sep; 17(3): 832–840. http://dx.doi.org/10.21123/bsj.2020.17.3.0832
Aldabbagh BM, Jawad HK, Mahdi RS. Study of the properties of MgO/ Poly methyl methacrylate Nano-composites. J Phys Conf Ser. 2021 Nov; 2114 (012039): 1-7. http://doi.org/ 10.1088/ 1742-6596/2114/1/012039
Aldabbagh BM, Alshimary HJ. Polyamide nanofibers coating by electrospinning technique for anti-corrosion behavior. J Eng Technol. 2017 Jul ; 35 (10):987–991. http://doi.org/10. 30684/ etj.35.10A.4
Hameed TM, AlDabbagh BM, Jasim RK. Mechanical properties of heat cured acrylic resin reinforced with natural sisal fibers powder. J Phys Conf Ser. 2021 Apr, 2114: (012023): 1-10. http://doi.org/10.1088/1742-6596/2114/1/012023
Talal J H, Mohammed DB, Jawad KH. Fabrication of hydrophobic nanocomposites coating using electrospinning technique for various substrate. J Phys Conf Ser. 2018 Apr; 1032 (012033): 1-13. https://doi.org/10.1088/1742-6596/1032/1/012033
Philos Trans R Soc. Bhushan B. Bioinspired oil–water separation approaches for oil spill clean-up and water purification. Philos Trans R Soc. A ; 2019 June ; 377: 20190120., http://dx.doi.org/10.1098/ rsta.2019.0120
Lyu C , Zhao P, Xie J , Dong S , Liu J , Rao C , et al . Electrospinning of Nanofibrous Membrane and Its Applications in Air Filtration: A Review. Nanomaterials. 2021 June; 11 (6): 1-15. http://doi.org/10.3390/nano 11061501
Aldabbag BM, Kadhim HJ. Nano composites of PAM Reinforced with Al2O3. Baghdad Sci J. 2023 Apr; onlinfirst: 1-7. https://dx.doi.org/10.21123/bsj.2023.7353
Dheyaa BM, Jassim WH, Hameed NA. Evaluation of the Epoxy/Antimony Trioxide Nanocomposites as Flame Retardant. J Phys Conf Ser. 2018 Sep; 1003: (012023): 1-10. http://doi.org/10.1088/1742-6596/1003/1/012078
Hanaa J K, AlDabbagh BM, Rana MS, Ahmed SD. Nano composites films for food packaging applications. AIP Conf . Proce. 2021 Nov; 2372 (100002): 1-6. https://doi.org/10.1063/5.0066204
Zuhair J , Hanaa J , Ola H. Preparation of Blended Nanocomposite Nanofiber Materials for Air Purification. IOP Conf. Ser.: Mater. Sci. Eng. 2018 March ; 433 (012073) : 1-8 , https://doi.org/10.1088/ 1757-899X/433/1/012073
Mohammed R , Jawad H , Al-Zubiedy A. Blended PVA/PVP Electro spun nanofibers for Coating Application. J. Phys.: Conf. Ser. 2021 Dec ; 2114 (012031) : 1-10 , https://doi.org/10.1088/1742-6596/2114/1/012031
Aldabbagh BM, Auda JB, Alesa HJ, Adnan N, Hmaizah O. The Food Security, Biodiversity, and Climate Nexus. 1st edition. Germany: Springer Nature; 2022. 23, Managing the soil erosion through the use of polyacrylamide: an empirical study; 479 – 485. http://doi.org/10.1007/978-3-031-12586-7_24
Jaafar H T , Aldabbagh BM . Investigation of superhydrophobic/hydrophobic materials properties using electrospinning technique. Baghdad Sci J. 2019 Sep; 16 (3): 632–638. https://doi.org/10.21123/bsj. 2019.16.3.0632
Al Dabbagh B M, Kadhim H J, Salih R M. Studying the effect of Polyamide 6 Nanofibers on Physical and Chemical Properties of Unsaturated Polyester Reinforced by Glass Fibers Composites. IOP Conf Ser: Mater Sci Eng. 2020 Nov; 757 (012001): 1-6. http://doi.org/10.1088/1757-899X/757/1/012001
Ahmed D. S. , Kadhim H J , Majeed S. M. Prepared poly amide nanofibers reinforced with ZnO nanoparticles using electrospinning technique . Dig J Nanomater Biostructures, 2019 Seb ; 13(4) : 637-640 , https://www.chalcogen.ro/637_KadhimHJ.pdf
Holmannova D, Borsky P, Svadlakova T, Borska L, Fiala Z. Carbon nanoparticles and their biomedical applications. Appl Sci . 2022 Sep; 12 (7865):1-21. http://doi.org/10.1007/978-981-33-6158-4_11
Saikat S R, Mansi G, Shiao-Shing C , Hau-Ming C, Cao T, Ngoc D, Huy Q . Anti-wetting behaviour of a superhydrophobic octadecyltrimethoxysilane blended PVDF/recycled carbon black composite membrane for enhanced desalination. Environ. Sci.: Water Res Technol. ; 2018 Oct; 4(10) : 1612–1623 , DOI : http://doi.org. 10.1039/c8ew00451j
Yixuan T, Zhengwei C, Sun,Chuanmei C, ,Xinfei Y, ,Mingdi L, Jia X. Electrospun Nanofiber-Based Membranes for Water Treatment. Poly, 2022 May; 14(10) :1-15 . https://doi.org/10.3390/polym14102004
Darwish R M , Mohamed D B , Hanaa J , Abbas Z M . Improving the corrosion resistance of metal surfaces using a polymeric nanocomposite coating armed with prepared carbon nanoparticles . Int. J. Corros. Scale Inhib , 2023 Oct; 12(4) : 1576-1591 , DOI : https://doi.org/10.17675/2305-6894-2023-12-4-10
Hanaa, J., Abd Alradha, R, Alzubaidy, A. Preparation and characterization of Polyvinyl Alcohol/Starch/Bio Oil Extraction Blends Coating for Food Packaging Using Electrospinning Technique. Egypt. J. Chem. 2023 Feb ; 66(2) : 154–161 , https://doi.org/ 10.21608/EJCHEM.2022.13 3004.5876
Darwish MR Jawad K H, Mohammed DB,. Thermal and morphological properties of electrospun polyamide – poly vinyl alcohol/CNPs nanofibers for filtration process. Fuller. Nanotub. Carbon Nanostructures 2023 Jun; 31(11): 1019-1029. https://doi.org/10.1080/1536383X.2023.2236259
Nicolas Ch , Nabil G , Clifford F, Amir F. Polyamide 66 microspheres metallised with in situ synthesised gold nanoparticles for a catalytic application. Nano scal Res Lett. 2012 Jun; 7 (1):182-187. https://doi.org/10.1186/1556-276X-7-182
Choi EY, Kim K, Kim CK. Reinforcement of nylon 6, 6/nylon 6,6 grafted nanodiamond composites by in situ reactive extrusion. Sci Rep. 2016 Feb; 6 (37010): 1-7. https://doi.org/ 10.1038/ srep37010
Jawad K H, Mohammed DB, Alsaffar MR. Performed of filter nano textile for purification of aerosol water by electrospinning technique. J Phys Conf Ser. 2019 Sep; 1298(012023): 1-5. http://doi.org/10.1088/1742-6596/1298/1/012023
Abbass D, Jabbar B, Jawad H. Impacts of Iodine on the Properties of Electrospun Polymeric Nanofibers. Full Nanot Carb Nano struc; 2023 Jan; 31 (4): 388–394. https://doi.org/10.1080/1536383X.2023.2168266
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