An Assessment of Inorganic Contaminants Levels in the Wastewater of Lifting and Treatment Sewage Stations in Karbala, Iraq

Authors

  • Mohammed Nasser Hussain Department of Chemistry, College of Science, University of Kerbala, Karbala, Iraq.
  • Ahmed Fadhil Khudhair Department of Chemistry, College of Science, University of Kerbala, Karbala, Iraq.
  • Hussain Jawad Ahmed Department of Chemistry, College of Science, University of Kerbala, Karbala, Iraq.

DOI:

https://doi.org/10.21123/bsj.2024.9583

Keywords:

Chemical pollutants, ICP-MS, Toxic materials, Wastewater treatment, Water quality.

Abstract

The investigation in this study includes examining the impact of wastewater at ten different stations. Eight lifting stations and two treatment stations in the center and district of Al-Hurr in the Karbala city. The study's goal is to determine the operational effectiveness of the main treatment unit project in Karbala and the Al-Hurr treatment unit and its impact on wastewater quality, disclosing the qualitative features of wastewater in the study area, controlling waste water from treatment plants, and utilizing its service in other fields. More than 70 trace elements were examined in this study by using inductively coupled plasma mass technology, in wastewater samples. Arsenic (As) concentrations were shown to be higher than permitted levels in some sites reaching 11.300 ng/ mL, and lead (Pb) concentrations were found to be higher than permissible limits at several lifting stations, where the concentration value reached 15.500 ng/mL. according to Iraqi standards and the World Health Organization. The findings of the investigation were provided on several indicators and classifications to take advantage of the water departure from the treatment plants in several places, as the indicators revealed that the water is contaminated, salty, and unsuitable for agricultural irrigation. It is suitable for crops that survive high salinity and for animal consumption. The correlation coefficient was also evaluated for the elements measured at the stations under study, and there was a perfect correlation for some elements, with correlation coefficient values ranging between (0.996 -1.000) for each of elements (Ni, Re, W and As, Li).

References

Ibrahem S, Hassan M, Ibraheem Q, Arif K. Genotoxic Effect of Lead and Cadmium on Workers at Wastewater Plant in Iraq. J Environ Public Health. 2020; 9-20.https://doi.org/10.1155/2020/9171027

Azimi A, Azari A, Rezakazemi M, Ansarpour M. Removal of Heavy Metals from Industrial Wastewaters: A Review. Chem Bio Eng Rev. 2017; 4(1): 37–59. https://doi.org/10.1002/cben.201600010

Fu F, Wang Q. Removal of heavy metal ions from wastewaters: A review. J Environ Manage . 2011; 92(3): 407–418. http://dx.doi.org/10.1016/j.jenvman.2010.11.011

Ursino C, Castro-Muñoz R, Drioli E, Gzara L, Albeirutty MH, Figoli A. Progress of nanocomposite membranes for water treatment. Membranes (Basel). 2018; 8(2): 1–40. https://doi.org/10.3390/membranes8020018

Yang X, Liu Y, Hu S, Yu F, He Z, Zeng G, et al. Construction of Fe3O4@MXene composite nanofiltration membrane for heavy metal ions removal from wastewater. Polym Adv Technol. 2021; 32(3): 1000–1010. https://doi.org/10.1002/pat.5148

Castro-Muñoz R, Barragán-Huerta BE, Fíla V, Denis PC, Ruby-Figueroa R. Current Role of Membrane Technology: From the Treatment of Agro-Industrial by-Products up to the Valorization of Valuable Compounds. Waste Biomass Valorization. 2018; 9(4): 513–529. https://doi.org/10.1007/s12649-017-0003-1

Bhuyan MM, Okabe H, Hidaka Y, Hara K. Pectin-[(3-acrylamidopropyl) trimethylammonium chloride-co-acrylic acid] hydrogel prepared by gamma radiation and selectively silver (Ag) metal adsorption. J Appl Polym Sci. 2018; 135(8): 2-9. https://doi.org/10.1002/app.45906

Bhuyan MM, Adala OB, Okabe H, Hidaka Y, Hara K. Selective adsorption of trivalent metal ions from multielement solution by using gamma radiation-induced pectin-acrylamide-(2-Acrylamido-2-methyl-1-propanesulfonic acid) hydrogel. J Environ Chem Eng. 2019; 7(1): 5–6. https://doi.org/10.1016/j.jece.2018.102844

Journal BS, Ali RJ, Sadee BA. Determination of essential and trace elements in various vegetables using ICP-MS. Baghdad Sci J. 2022; 20: 715–725. https://doi.org/10.21123/bsj.2022.7253

Youni A M, Darwesh D A. An Evaluation of Waste and Well Water Quality for Agriculture Production Around Erbil City, Iraq. Baghdad Sci J 2023; 20 : 1242-page?. https://doi.org/10.21123/bsj.2023.7576

Castro-Muñoz R, Gontarek E, Figoli A. Membranes for toxic- and heavy-metal removal. Current Trends and Future Developments on (Bio-) Membranes. 2019; 125–149. https://doi.org/10.1016/B978-0-12-816778-6.00007-2

Heydari Moghaddam M, Nabizadeh R, Dehghani MH, Akbarpour B, Azari A, Yousefi M. Performance investigation of Zeolitic Imidazolate Framework – 8 (ZIF-8) in the removal of trichloroethylene from aqueous solutions. Microchem J . 2019; 150: 104-185. https://doi.org/10.1016/j.microc.2019.104185

Yousefi M, Nabizadeh R, Alimohammadi Mohammadi AA, Mahvi AH. Removal of phosphate from aqueous solutions using granular ferric hydroxide process optimization by response surface methodology. Desalin Water Treat. 2019; 158: 290–300. https://doi.org/10.5004/dwt.2019.24281

Werkneh AA, Gebru SB. Development of ecological sanitation approaches for integrated recovery of biogas, nutrients and clean water from domestic wastewater. Resour Environ Sustain . 2023; 11: 1-15. https://doi.org/10.1016/j.resenv.2022.100095

Janjhi FA, Ihsanullah I, Bilal M, Castro-Muñoz R, Boczkaj G, Gallucci F. MXene-based materials for removal of antibiotics and heavy metals from wastewater- a review. Water Resour Ind. 2023; 29: 1–20. https://doi.org/10.1016/j.wri.2023.100202

Dehghani MH, Kamalian S, Shayeghi M, Yousefi M, Heidarinejad Z, Agarwal S, et al. High-performance removal of diazinon pesticide from water using multi-walled carbon nanotubes. Microchem J. 2019; 145: 486–491. https://doi.org/10.1016/j.microc.2018.10.053

Khan NA, Khan SU, Islam DT, Ahmed S, Farooqi IH, Isa MH, et al. Performance evaluation of column-SBR in paper and pulp wastewater treatment: Optimization and bio-kinetics. Desalin Water Treat. 2019; 156: 204–219. https://doi.org/10.5004/dwt.2019.23775

Shamsollahi HR, Alimohammadi M, Momeni S, Naddafi K, Nabizadeh R, Khorasgani FC, et al. Assessment of the Health Risk Induced by Accumulated Heavy Metals from Anaerobic Digestion of Biological Sludge of the Lettuce. Biol Trace Elem Res. 2019; 188(2): 514–520 https://doi.org/10.1007/s12011-018-1422-y

Czikkely M, Neubauer E, Fekete I, Ymeri P, Fogarassy C. Review of heavy metal adsorption processes by several organic matters from wastewaters. Water (Switzerland). 2018; 10(10): 1–15. https://doi.org/10.3390/w10101377

Ihsanullah Abbas A, Al-Amer AM, Laoui T, Al-Marri MJ, Nasser MS, et al. Heavy metal removal from aqueous solution by advanced carbon nanotubes: Critical review of adsorption applications. Sep Purif Technol. 2016; 157: 141–161. http://dx.doi.org/10.1016/j.seppur.2015.11.039

De Santiago-Martín A, Meffe R, Teijón G, Martínez Hernández V, López-Heras I, Alonso Alonso C, et al. Pharmaceuticals and trace metals in the surface water used for crop irrigation: Risk to health or natural attenuation? Sci Total Environ. 2020; 705: 1–15. https://doi.org/10.1016/j.scitotenv.2019.135825

Pillai HPS, Tharayil M. Treatment of heavy metals from water by electro-phytoremediation technique. J Ecol Eng. 2017; 18(5): 17–26. https://doi.org/10.12911/22998993/76208

Pinter J, Jones BS, Vriens B. Loads and elimination of trace elements in wastewater in the Great Lakes basin. Water Res. 2022; 209: 1-11. https://doi.org/10.1016/j.watres.2021.117949

Tong S, Li H, Tudi M, Yuan X, Yang L. Comparison of characteristics, water quality and health risk assessment of trace elements in surface water and groundwater in China. Ecotoxicol Environ Saf. 2021; 219: 112283. https://doi.org/10.1016/j.ecoenv.2021.112283

Long J, Luo K. Elements in surface and well water from the central North China Plain: Enrichment patterns, origins, and health risk assessment. Environ Pollut. 2020; 258: 113725. https://doi.org/10.1016/j.envpol.2019.113725

Fazaa N A, Dunn J C, Whittingham M J. Pollution Threatens Water Quality in the Central Marshes of Southern Iraq. Baghdad Sci J . 2021; 18: 1501-page?. https://doi.org/10.21123/bsj.2021.18.4(Suppl.).1501

Hammadi A H, Ramadan A A, Ali A Y, Atia A F, Hassan R K, Mahdy Z M. Effect of Waste Water Bacteria and Some Chemical Properties on Drinking Water in AL-Mada,in Treatment Plan Station. Baghdad Sci J. 2011; 8: 35-38. https://doi.org/10.21123/bsj.2011.8.1.35-38

Boudias M, Gourgiotis A, Montavon G, Cazala C, Pichon V, Delaunay N. 226Ra and 137Cs determination by inductively coupled plasma mass spectrometry: state of the art and perspectives including sample pretreatment and separation steps. J Environ Radioact. 2022; 244: 106812 https://doi.org/10.1016/j.jenvrad.2022.106812

Hong YS, Choi JY, Nho EY, Hwang IM, Khan N, Jamila N, et al. Determination of macro, micro and trace elements in citrus fruits by inductively coupled plasma–optical emission spectrometry (ICP- OES), ICP–mass spectrometry and direct mercury analyzer. J Sci Food Agric. 2019; 99(4): 1–9. https://doi.org/10.1002/jsfa.9382

AL-Nuaimi S A. Study the Effects of the Polluted Waste Water on the Environment. Baghdad Sci J 2021; 3(1): 94-100. https://doi.org/10.21123/bsj.2006.681

Mohammed Nawi A, Chin SF, Jamal R. Simultaneous analysis of 25 trace elements in micro volume of human serum by inductively coupled plasma mass spectrometry (ICP-MS). Pract Lab Med 2020; 18: 2–9. https://doi.org/10.1016/j.plabm.2019.e00142

Michalke B. Review about Powerful Combinations of Advanced and Hyphenated Sample Introduction Techniques with Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) for Elucidating Trace Element Species in Pathologic Conditions on a Molecular Level. Int J Mol Sci. 2022; 23(11): 2–22. https://doi.org/10.3390/ijms23116109

Aziz A M, Aws A. Waste water production treatment and use in Iraq country report. In Second Regional Workshop of the Project ‘Safe Use of Wastewater in Agriculture, 2012, p. 16-18.

Noor T, Alanisi EMA. Critical Assessment of Treated Wastewater and Their Reuse for Irrigation in Iraq. South Asian Res J Biol Appl Biosci. 2022; 12; 4(2): 50–62. http://dx.doi.org/10.36346/sarjbab.2022.v04i02.003

Herschy RW. Water Quality for Drinking: WHO Guidelines. In: Encyclopedia of Earth Sciences Series. 2012: 876–883. https://doi.org/10.1007/978-1-4020-4410-6_184.

Downloads

Issue

Section

article

How to Cite

1.
An Assessment of Inorganic Contaminants Levels in the Wastewater of Lifting and Treatment Sewage Stations in Karbala, Iraq. Baghdad Sci.J [Internet]. [cited 2024 Dec. 23];22(6). Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/9583