Effects of Ultrasonic Treatment and Hydrogen Donor Addition on the Viscosity of Iraqi Heavy Crude Oil

Authors

  • Athraa W. Azeez Department of Chemical Engineering, College of Engineering, University of Baghdad, Baghdad, Iraq.
  • Hussein Q. Hussein Department of Chemical Engineering, College of Engineering, University of Baghdad, Baghdad, Iraq.

DOI:

https://doi.org/10.21123/bsj.2024.9823

Keywords:

Decalin, Heavy crude oil, Hydrogen donor, Ultrasonic waves, Viscosity.

Abstract

         The current investigation examines the combined impacts of ultrasonic radiation and hydrogen donors on the viscosity of heavy crude oil. The impact of exposure time, power, duty cycle, and temperature on the viscosity of Iraqi heavy crude oil with 20.32 API was studied. Also, the viscosity of the oil samples, which were mixed with a hydrogen donor (decalin) and subjected to ultrasonic treatment under optimal conditions, was examined to evaluate the combined impact of ultrasonic radiation and hydrogen donor on the viscosity of crude oil.  The viscosity experienced a decrease of 52.34% at 2 min of irradiation, 360 W ultrasonic power, 0.8 duty cycle, 35 ⁰C, and 8vol% decalin. To validate the outcomes of the experiments, asphaltene content, sulfur content, API gravity, and distillation tests were conducted on both the original and final samples (under optimal conditions). The concentrations of asphaltene and sulfur exhibited a drop of 37.51% and 35.04%, respectively. The results show that cavitation, a heat phenomenon, and the mechanical impact of ultrasound may help break up long carbon chains and reduce the size of asphaltene aggregates, which causes the crude oil's viscosity to drop. Moreover, the findings demonstrated that the simultaneous application of ultrasound and hydrogen donor yielded the most significant decrease in oil viscosity compared with untreated crude oil or treated just with ultrasonic waves.

References

Lafta Alzurfi SK, Alasedi K kadhim, Abdulraheem NI. Effect different concentrations of crude oil on the pigment content and protein content of Hydrilla verticillata plant. Iraqi J Sci. 2019; 60(10): 2141-2148. https://doi.org/10.24996/ijs.2019.60.10.6

Abid Al-Hisnawi AA, Yasser YK, Kadhum NH, Mustafa JM. Hydrocarbon degradation test among the microbial community in oil-contaminated soil of power generators in Kerbala city, Iraq. Iraqi J Sci. 2022; 63(7): 2900-2913. https://doi.org/10.24996/ijs.2022.63.7.14

Naser HA, Mahmood AI, Fandi SK. Measurements of linear and nonlinear optical properties for Iraqi heavy crude oil samples. Iraqi J Sci. 2021; 62(3): 845-851. https://doi.org/10.24996/ijs.2021.62.3.15

Speight JG. Enhanced Recovery Methods for Heavy Oil and Tar Sands. Houston (Texas) : Gulf Publishing Company; 1st Ed. 2009. 354 p. https://doi.org/10.1016/C2013-0-15525-0

Shakir F, Hussein HQ, Abdulwahhab ZT. Influence of Nanosilica on Solvent Deasphalting for Upgrading Iraqi Heavy Crude Oil. Baghdad Sci J. 2022; 20: 144-156. https://doi.org/10.21123/bsj.2022.6895

Mordi JC, Achuba FI, Ichipi-Ifukor PC, Emete G, Hughs Mokogwu AT, Nmanedu AC, et al. Protective influence of Costus afer Aqueous Extract in Rats Fed with Crude Oil Contaminated Diet as Measured by Employing Biochemical Indices. Iraqi J Sci. 2021; 62(12): 4639-4648.https://doi.org/10.24996/ijs.2021.62.12.5

Hussein HQ, Abdul-wahhab Mohammad S. Viscosity Reduction of Sharqi Baghdad Heavy Crude Oil Using Different Polar Hydrocarbons, Oxygenated Solvents. Iraqi J Chem Pet Eng. 2014; 15(2): 39-48. https://doi.org/10.31699/IJCPE.2014.2.5

Majeed EM, Naife TM. Viscosity reduction of Iraqi crude oil by different additives. AIP Conf Proc. 2020; 2213. https://doi.org/10.1063/5.0000229

Hussein HQ, Khedheer ZA. Investigation the synergistic effect of Nano Catalyst and Hydrogen Donors for Improving Heavy Oil using microwave radiation. 7th Sci Eng 1st Int Conf. 2017; 457-488.

Subkh TM, Hussein HQ. The Effect of Potato Starch and CTAB Surfactant on Viscosity and Drag Reduction for Iraqi Crude Oil. Solid State Technol. 2020; 63(3): 5235-5244.

11. Saeed AQ, Al-Zaidi BY, Hamadi AS, Majdi HS, AbdulRazak AA. Upgrade of heavy crude oil via aquathermolysis over several types of catalysts. Mater Express. 2022; 12(2): 278-287. https://doi.org/10.1166/mex.2022.2139

12. Mohammed SA, Maan SD. The Effect of Asphaltene on the Stability of Iraqi Water in Crude Oil Emulsions. Iraqi J Chem Pet Eng. 2016; 17(2): 37-45.https://doi.org/10.31699/IJCPE.2016.2.5

13. Hasan RM, Al-haleem A A. Modifying an Equation to Predict the Asphaltene Deposition in the Buzurgan Oil Field. Iraqi J Chem Pet Eng. 2020; 21(4): 49-55.https://doi.org/10.31699/IJCPE.2020.4.6

Moud AA. Asphaltene induced changes in rheological properties: A review. Fuel. 2022; 316: 123372.https://doi.org/10.1016/j.fuel.2022.123372

Mohammed I, Mahmoud M, Al Shehri D, El-Husseiny A, Alade O. Asphaltene precipitation and deposition: A critical review. J Pet Sci Eng. 2020; 197: 107956.https://doi.org/10.1016/j.petrol.2020.107956

Shnain ZY, Mageed AK, Majdi HS, Mohammadi M, AbdulRazak AA, Abid MF. Investigating the effect of TiO2-based nanofluids in the stability of crude oil flow: parametric analysis and Gaussian process regression modeling. J Pet Explor Prod Technol. 2022; 12(9): 2429-2439. https://doi.org/10.1007/s13202-022-01473-6

Ke H, Yuan M, Xia S. A review of nanomaterials as viscosity reducer for heavy oil. J Dispers Sci Technol. 2022; 43(9): 1271-1282. https://doi.org/10.1080/01932691.2020.1851246

Ali SA, Al-Haideri HH, Al Hashimi AM. Evaluating the Activity of Ultrasound on Biofilm Formation by Acinetobacter baumannii isolated from clinical Specimens. Baghdad Sci J. 2022; 19(6): 1522-1535. https://doi.org/10.21123/bsj.2022.7739

Mohsin M, Meribout M. An extended model for ultrasonic-based enhanced oil recovery with experimental validation. Ultrason Sonochem. 2015; 23: 413-423. https://doi.org/10.1016/j.ultsonch.2014.08.007

Li X, Zhang F, Liu G. Review on new heavy oil viscosity reduction technologies. IOP Conf Ser Earth Environ Sci. 2022; 983. https://doi.org/10.1088/1755-1315/983/1/012059

Palaev AG, Shammazov IA, Dzhemilev ER. Research of the impact of ultrasonic and thermal effects on oil to reduce its viscosity. J Phys Conf Ser. 2020; 1679. https://doi.org/10.1088/1742-6596/1679/5/052073

Razavifar M, Qajar J. Synergistic effects of ultrasonic irradiation and α-Fe2O3 nanoparticles on the viscosity and thermal properties of an asphaltenic crude oil and their application to in-situ combustion EOR. Ultrason. 2022; 120: 106655. https://doi.org/10.1016/j.ultras.2021.106655

Yusof SM, Hussin N, Isa M. Viscosity Reduction of Palm Oil via Ultrasonic Radiation. Appl Mech Mater. 2015; 785: 315-319. https://doi.org/10.4028/www.scientific.net/amm.785.315

Razavifar M, Qajar J. Experimental investigation of the ultrasonic wave effects on the viscosity and thermal behaviour of an asphaltenic crude oil. Chem Eng Process - Process Intensif. 2020; 153: 107964.https://doi.org/10.1016/j.cep.2020.107964

Dengaev AV, Kayumov AA, Getalov AA, Aliev FA, Baimukhametov GF, Sargin BV, et al. Chemical Viscosity Reduction of Heavy Oil by Multi-Frequency Ultrasonic Waves with the Main Harmonics of 20–60 kHz. Fluids. 2023; 8: 136. https://doi.org/10.3390/fluids8040136

Hart A, Adam M, Robinson JP, Rigby SP, Wood J. Tetralin and decalin H-donor effect on catalytic upgrading of heavy oil inductively heated with steel balls. Catalysts. 2020; 10(4): 393. https://doi.org/10.3390/catal10040393

Qiao J, Zuo K, Sun Y, Song W, Zhang X, Dai L, et al. Experimental studies on the effect of ultrasonic treatment and hydrogen donors on residual oil characteristics. Ultrason Sonochem. 2020; 69: 105266.https://doi.org/10.1016/j.ultsonch.2020.105266

Gao J, Li C, Xu D, Wu P, Lin W, Wang X. The mechanism of ultrasonic irradiation effect on viscosity variations of heavy crude oil. Ultrason Sonochem. 2021; 81: 105842. https://doi.org/10.1016/j.ultsonch.2021.105842

Razavifar M, Qajar J, Riazi M. Experimental study on pore-scale mechanisms of ultrasonic-assisted heavy oil recovery with solvent effects. J Pet Sci Eng. 2022; 214(5): 110553. https://doi.org/10.1016/j.petrol.2022.110553

Qajar J, Razavifar M, Riazi M. A mechanistic study of the synergistic and counter effects of ultrasonic and solvent treatment on the rheology and asphaltene structure of heavy crude oil. Chem Eng Process Intensif. 2023; 195: 109619. https://doi.org/10.1016/j.cep.2023.109619

Al-Muntaser AA, Varfolomeev MA, Suwaid MA, Saleh MM, Djimasbe R, Yuan C, et al. Effect of decalin as hydrogen-donor for in-situ upgrading of heavy crude oil in presence of nickel-based catalyst. Fuel. 2022; 313: 122652. https://doi.org/10.1016/j.fuel.2021.122652

Lu HJ, Yuan DH, Gao C, Li BC, Huang ZB, Yang JY, et al. Roles of decalin as hydrogen donor in visbreaking of heavy oil. J Anal Appl Pyrolysis. 2023; 175: 106169. https://doi.org/10.1016/j.jaap.2023.106169

Kang S, Kim N, Jung J. Effect of Hydrogen Donor Addition on Thermal Decomposition of Bio-jet Fuel. Ind Eng Chem Res. 2021; 60(30): 11432-11438. https://doi.org/10.1021/acs.iecr.1c01574

Najafi I, Amani M. Asphaltene Flocculation Inhibition with Ultrasonic Wave Radiation: A Detailed Experimental Study of the Governing Mechanisms. Adv Pet Explor Dev. 2011; 2(2): 32-36. http://dx.doi.org/10.3968/j.aped.1925543820110202.108

Mansouri H, Mohammadidoust A, Mohammadi F. Chemical Engineering and Processing - Process Intensification An optimization study on quality promotion of heavy crude oil exposed ultrasonic waves and magnetic nanoparticles addition. Chem Eng Process - Process Intensif. 2021; 167: 108542. https://doi.org/10.1016/j.cep.2021.108542

Abbas FH, Naife TM, Barghash H. The Effect of Variable Parameters on Carbon Residue of Iraqi Vacuum Gas Oil using Ultrasound Techniques. Iraqi J Chem Pet Eng. 2023; 24(2): 107-112.https://doi.org/10.31699/IJCPE.2023.2.12

Setyaningsih W, Karmila Fathimah RN, Cahyanto MN. Process optimization for ultrasound-assisted starch production from cassava (manihot esculenta crantz) using response surface methodology. Agronomy. 2021; 11(1):117. https://doi.org/10.3390/agronomy11010117

Shedid SA. An ultrasonic irradiation technique for treatment of asphaltene deposition. J Pet Sci Eng. 2004; 42(1): 57-70. https://doi.org/10.1016/j.petrol.2003.11.001

Liu J, Yang F, Xia J, Wu F, Pu C. Mechanism of Ultrasonic Physical-Chemical Viscosity Reduction for Different Heavy Oils. ACS Omega. 2021; 6(3): 2276-2283. https://doi.org/10.1021/acsomega.0c05585

Alemán-Vázquez LO, Cano-Domínguez JL, García-Gutiérrez JL. Effect of tetralin, decalin and naphthalene as hydrogen donors in the upgrading of heavy oils. Procedia Eng. 2012; 42: 532-539. https://doi.org/10.1016/j.proeng.2012.07.445

Wan C, Wang R, Zhou W, Li L. Experimental study on viscosity reduction of heavy oil by hydrogen donors using a cavitating jet. RSC Adv. 2019; 9(5): 2509-2515. https://doi.org/10.1039/c8ra08087a

Lababidi HMS, Sabti HM, AlHumaidan FS. Changes in asphaltenes during thermal cracking of residual oils. Fuel. 2014; 117: 59-67.https://doi.org/10.1016/j.fuel.2013.09.048

Fan Z xia, Zhao F lin, Wang J xiang, Gong Y gang. Upgrading and viscosity reduction of super heavy oil by aqua-thermolysis with hydrogen donor. J Fuel Chem Technol. 2006; 34(3): 315.

Askarian M, Vatani A, Edalat M. Heavy Oil Upgrading in a Hydrodynamic Cavitation System: CFD Modelling, Effect of the Presence of Hydrogen Donor and Metal Nanoparticles. Can J Chem Eng. 2017; 95(4): 670-679. https://doi.org/10.1002/cjce.22709

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Effects of Ultrasonic Treatment and Hydrogen Donor Addition on the Viscosity of Iraqi Heavy Crude Oil. Baghdad Sci.J [Internet]. [cited 2024 Oct. 9];22(4). Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/9823