Studying of The Process of Obtaining Monocalcium Phosphate based on Extraction Phosphoric Acid from Phosphorites of Central Kyzylkum

Authors

  • Mokhichekhra Shaymardanova Department of Chemical Technology, Termez Institute of Engineering and Technology, Termez 190100, Uzbekistan.
  • Kholtura Mirzakulov Department of Chemical Technology, Faculty of Chemical Technology, Tashkent Institute of Chemical Technology, Tashkent, 100011, Uzbekistan.
  • Gavkhar Melikulova Department of Chemical Technology, Faculty of Chemical Technology, Tashkent Institute of Chemical Technology, Tashkent, 100011, Uzbekistan.
  • Sakhomiddin. Khodjamkulov Department of Chemical Technology, Termez Institute of Engineering and Technology, Termez 190100, Uzbekistan.
  • Abror Nomozov Department of Chemical Technology, Termez Institute of Engineering and Technology, Termez 190100, Uzbekistan. https://orcid.org/0000-0003-0409-8247
  • Oybek Toshmamatov Department of Chemical Technology, Termez Institute of Engineering and Technology, Termez 190100, Uzbekistan.

DOI:

https://doi.org/10.21123/bsj.2024.9836

Keywords:

Phosphorites of Central Kyzylkum, extraction phosphoric acid, monocalcium phosphate,, X-ray, IR spectrum, scanning electron microscopic

Abstract

In this paper, a study of monocalcium phosphate production based on extractable phosphoric acid obtained from Central Kyzyl-Kum phosphorites was conducted. Effects of various parameters (density, temperature, and viscosity of starting materials) on the process of defluoridation and desulfation of extraction phosphoric acid and production of monocalcium phosphate based on calcium carbonate were studied. The experiments were mainly conducted on two samples, and the composition of the substances before and after the process was studied. According to the results, the contents of other components also increase proportionally (sample 1). Thus, the content of calcium oxide increases from 1.58% to 5.54% with a content of 60% P2O5, magnesium from 0.49% to 1.15%, iron oxide from 0.25% to 0.85%, aluminum oxide from 0.38% to 1.24%, sulfate ions from 0.23% to 0.76%, the content of calcium oxide increases from 2.09% to 7.40% with a content of 60% P2O5, magnesium from 0.80% to 2.83%, iron oxide from 0.25% to 0.90%, aluminum oxide from 0.38% to 1.34%, sulfate ions from 0.23% to 0.82%. The fluorine content decreases from 0.32% to 0.17% depending on the EPA concentration (sample 2). Some factors, such as the rate and concentration of phosphoric acid and high-speed separation of phosphoric acid, were also studied in the process of obtaining monocalcium phosphate and its chemical composition and properties. The results obtained based on both samples were studied and analyzed using X-ray, IR spectrum, scanning electron microscopic, and elemental analysis.

References

Leonid Lazarevich Ubugunov, Enkhtuyaa B, Maria Merkusheva. The content of available mineral phosphorus compounds in chestnut soils of Northern Mongolia upon application of different forms of phosphorite. Eurasian Soil Sc. 2015; 48: 634–642 https://doi.org/10.1134/S1064229315060113.

Shahida Waheed, Sabiha-Javied Skhurram, Naila Siddique, Ribha Shakoor, Muhammad Tufail. Rare earths elements in phosphorite and granulated single super-phosphate fertilizers of Pakistan, a study using instrumental neutron activation analysis. J Radioanal Nucl Chem. 2011; 289: 521–528. https://doi.org/10.1007/s10967-011-1112-0.

Zaynitdinova LI, Juraeva RN, Tashpulatov JJ, Kukanova SI, Lazutin NA, Mavjudova AM. Influence of Silver and Copper Nanoparticles on the Enzymatic Activity of Soil-Borne Microorganisms. Baghdad Sci J. 2022; 19(6): 1487. https://doi.org/10.21123/bsj.2022.6532.

Baturin G N. Chlorine in phosphorites and bone phosphate from Oceanic and marine deposits. Lith Min Resour 2005; 40: 56–67. https://doi.org/10.1007/s10987-005-0006-z

Shamim A Dar, K F Khan, Saif A Khan, Samsuddin Khan, M Masroor Alam. Petro-mineralogical Studies of the Paleoproterozoic Phosphorites in the Sonrai basin, Lalitpur District, Uttar Pradesh, India. Nat Resour Res. 2015; 24: 339–348. https://doi.org/10.1007/s11053-014-9260-x

Kurbaniyazov R K, Reimov A M, Dadakhodzhaev A T, Namazov Sh S, Beglov B M. Nitrogen-phosphoric fertilizers produced by introduction of Central Kyzylkum phosphate raw material into ammonium nitrate melt. Russ J Appl Chem 2007; 80: 1984–1988. https://doi.org/10.1134/S1070427207110456

Melikulova G E, Mirzakulov Kh Ch, Usmanov I I, Isakov A F. Study of the process of obtaining feed dicalcium phosphate from phosphorites of the Central Kyzylkum. Universum. 2018; 6(51).

Valentina K, Krut’ko, Lyubov Maslova, Olga N Musskaya, Safronova T V, Anatoly Kulak. Calcium Phosphate Ceramic Foam Obtained by Firing a Hydroxyapatite – Monocalcium Phosphate Monohydrate Powder Mixture. Glas Ceram. 2022; 11(12): 476-480. https://doi.org/10.1007/s10717-022-00435-y

Krut’ko V K, Maslova L Y, Musskaya O N, Safronova T V, Kulak A I. Calcium Phosphate Ceramic Foam Obtained by Firing a Hydroxyapatite – Monocalcium Phosphate Monohydrate Powder Mixture. Glas Ceram. 2022; 78: 476–480. https://doi.org/10.1007/s10717-022-00435-y.

Safronova T V, Sadilov I S, Chaikun K V, Shatalova T B, Filippov Ya Yu. Ceramics Based on a Powder Mixture of Calcium Hydroxyapatite, Monocalcium Phosphate Monohydrate, and Sodium Hydrogen Phosphate Homogenized under Mechanical Activation Conditions. Inorg Mater Appl Res. 2020; 11: 879–885. https://doi.org/10.1134/S2075113320040346.

Shaymardanova M A, Mirzakulov Kh Ch, Melikulova G, Khodjamkulov S Z, Nomozov A K, Shaymardanova Kh.S. Study of process of obtaining monopotassium phosphate based on monosodium phosphate and potassium chloride. Chemical Problems. 2023; 3 (21): 279-293. https://doi.org/10.32737/2221-8688-2023-3-279-293

Saheed SA, aweez SJ, Ahmed SM. Effect of different levels and sizes of walnut seed residues on phosphorus availability and alkaline phosphatase activity in calcareous soil. Baghdad Sci J. 2022; 19(2): 240-245. https://doi.org/10.21123/bsj.2022.19.2.0240.

Safranova T V, Sadilov I S, Chaikun K V, Shatalova T B, Filippov Ya Yu. Synthesis of Monetite from Calcium Hydroxyapatite and Monocalcium Phosphate Monohydrate under Mechanical Activation Conditions. Russ J Inorg Chem. 2019; 64(9): 916-922. https://doi.org/10.1134/S0036023619090171

Safronova T V, Korneichuk S A, Shatalova T B, LukinaYu S, Sivkov S P, Filippov, Y A, , et al. Ca2P2O7–Ca(PO3)2 Ceramic Obtained by Firing β-Tricalcium Phosphate and Monocalcium Phosphate Monohydrate Based Cement Stone. Glass Ceram 2020; 77: 165–172. https://doi.org/10.1007/s10717-020-00263-y.

Daniel Lemos, Rafael Coelho, Sjo Zwart, Albert Tacon, Albert Tacon.. Performance and digestibility of inorganic phosphates in diets for juvenile shrimp (Litopenaeus vannamei): dicalcium phosphate, monocalcium phosphate, and monoammonium phosphate. AqUac Int. 2021; 29: 681–695. https://doi.org/10.1007/s10499-021-00651-3.

Musskaya O N, Krut’ko V K, Kulak A I, Safronova T V, Shatalova T B. Thermal Transformations in Hardening Compositions Based on Hydroxyapatite, Monocalcium Phosphate Monohydrate, and Polymeric Binders. Glass Ceram 2020; 77: 256–262. https://doi.org/10.1007/s10717-020-00283-8.

Safronova T V, Shatalova T B, Filippov Y Y, Musskaya Olga, Safronov A S, Toshev O. Ceramics in the Ca2P2O7–Ca(PO3)2 System Obtained by Annealing of the Samples Made from Hardening Mixtures Based on Calcium Citrate Tetrahydrate and Monocalcium Phosphate Monohydrate. Inorg Mater Appl. 2020; 11: 777–786. https://doi.org/10.1134/S2075113320040334.

Al-Shahwany A, Greabb B M, Abdul Alohab N K. Effect of saline water and potash fertilizer on proline content and water potental in pisum sativum. Baghdad Sci J. 2021; 4(3): 351-7. https://doi.org/10.21123/bsj.2007.4.3.351-357.

AL-SHAHWANY A, OWN A. Effect of Saline water and Potash Fertilizer on some chemical constituents in Pisum sativum L.(Var.Senador Cambados) plant. Baghdad Sci J. 2009; 6(2): 257-64. https://doi.org/10.21123/bsj.2009.6.2.257-264.

Fouad H K. Determination of hexavalent and tetravalent uranium in phosphate ores through hydrºChloric acid selective leaching. J Radioanal Nucl Chem 2010; 285: 193–197. https://doi.org/10.1007/s10967-010-0540-6.

Pohreliuk I M, Proskurniak R V, Tkachuk O V, Goral A. Effect of parameters of plasma electrolytic oxidation on formation of calcium-phosphate coatings on titanium. Mater Sci. 2018; 54(6): 36–41. http://jnas.nbuv.gov.ua/article/UJRN-0000958918.

Tae-Hyun Yoon, Seunggun Won, Dong-Hoon Lee, Jung-Woo Choi, Changsix Ra, Jeong-Dae Kim. Effect of a new phosphorus source, magnesium hydrogen phosphate (MHP) on growth, utilization of phosphorus, and physiological responses in carp Cyprinus carpio. Fish Aquatic Sci. 2016; 19: 39. https://doi.org/10.1186/s41240-016-0038-4.

Abinash Das, Sampad Ghosh, Togam Ringu, Nabakumar Pramanik. A Focus on Biomaterials Based on Calcium Phosphate Nanoparticles: an Indispensable Tool for Emerging Biomedical Applications. Bio Nano Sci. 2023; 13: 795–818. https://doi.org/10.1007/s12668-023-01081-6.

Turaeva D Yu, Pochitalkinaa I A. Theoretical and Practical Foundations of the Selective Separation of Phosphate Ions from Phosphate Ores with a High Content of Iron Impurities with the Recirculation Method. Theor Found Chem E. 2022; 56: 252–264. https://doi.org/10.1134/S0040579522020142.

Nomozov A K, Beknazarov Kh S, Khodjamkulov S Z, Misirov Z Kh. Salsola Oppositifolia acid extract as a green corrosion inhibitor for carbon steel. Indian J Chem Technol. 2023; 30(6): 872-877.

https://doi.org/10.56042/ijct.v30i6.6553

Muratov B A, Turaev Kh Kh, Umbarov I A, Kasimov Sh A, Nomozov A K. Studying of Complexes of Zn(II) and Co(II) with Acyclovir (2-amino-9-((2-hydroxyethoxy)methyl)-1,9- dihydro-6H-purine-6-OH), Int J Eng Trends Technol. 2024; 72(1); 202-208.

https://doi.org/10.14445/22315381/IJETT-V72I1P120.

Sara Chahine, Giovanni Garau, Paola Castaldi, Maria Vittoria Pinna, Sara Melito, Giovanna Seddaiu et al. Stabilising fluoride in contaminated soils with monocalcium phosphate and municipal solid waste compost: microbial, biochemical and plant growth impact. Environ Sci Pollut Res. 2022; 29: 41820–41833. https://doi.org/10.1007/s11356-021-17835-2.

Otaboev Kh A, Sherkuziev D S, Badalova O A, Radjabov R, Namazov Sh S, Seytnazarov A R. Mineralogical Composition of Kyzylkum Washed Dry Concentrate and Its Processing into Simple Superphosphate. Russ J Gen Chem. 2022; 92: 505–517. https://doi.org/10.1134/S1070363222030203.

Turaev Kh, Shavkatova D, Amanova N, Shadhar MH, Berdimurodov E, Bektenov N, et al. Application of Sulfur-2,4-dinitrophenylhydrazine as Modifier for Producing an Advantageous Concrete. Baghdad Sci J. 2023; 20(6(Suppl)): 2414. https://doi.org/10.21123/bsj.2023.9038.

Downloads

Issue

Section

article

How to Cite

1.
Studying of The Process of Obtaining Monocalcium Phosphate based on Extraction Phosphoric Acid from Phosphorites of Central Kyzylkum. Baghdad Sci.J [Internet]. [cited 2024 Jul. 22];22(1). Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/9836