تشخيص الكربون المنشط بكلوريد البوتاسيوم المشتق من قشور الجوز في جزيرة تيدور، إندونيسيا
DOI:
https://doi.org/10.21123/bsj.2024.10684الكلمات المفتاحية:
الكربون، FTIR، منشط كلوريد البوتاسيوم، EDX-SEM، قشور الجوز، .XRDالملخص
يعتبر الكربون المنشط ذو قيمة عالية لتعدد استخداماته واستخدامه الصناعي الواسع النطاق. ينتج الجوز (Canarium vulgare Leech)، وهو نبات إندونيسي أصلي يوجد بشكل أساسي في المناطق الشرقية مثل جزر مالوكو وتيدور، قشورًا يمكن تحويلها إلى كربون نشط. تضمنت هذه الدراسة الحصول على الكربون من قشور الجوز من خلال التحلل الحراري عند 360 درجة مئوية لمدة 6 ساعات، يليه التنشيط في محلول 3M KCl لمدة 24 ساعة. تم تحليل الكربون المنشط باستخدام مطيافية تحويل فورييه بالأشعة تحت الحمراء (FTIR)، ومجهر مسح إلكتروني - أشعة سينية مشتتة للطاقة (SEM-EDX)، وحيود الأشعة السينية (XRD). كشف تحليل FTIR عن مجموعات وظيفية بما في ذلك N-H وAr-H (عطري) وC≡N وكربونيل CO وإستر CO. أظهرت صور المجهر الإلكتروني الماسح بنية غير متجانسة في الكربون المنشط بالتحلل الحراري وKCl. بعد التنشيط، زاد توزيع قطر المسام بشكل ملحوظ من 496.2 نانومتر إلى 1226 ميكرومتر. أشار تحليل EDX إلى ارتفاع في محتوى الكربون من 85.40٪ بعد التحلل الحراري إلى 86.50٪ بعد تنشيط كلوريد البوتاسيوم. اقترحت حيود الأشعة السينية هياكل غير متبلورة في كلا الشكلين من الكربون، كما هو موضح من خلال القمم السائبة وأنماط الحيود العريضة. يقدم هذا البحث الاستخدام الجديد لكلوريد البوتاسيوم كمنشط لتعزيز مسامية الكربون المنشط المشتق من قشور الجوز. أظهر الكربون المنشط بكلوريد البوتاسيوم القدرة على إزالة 0.122 مجم / لتر من Fe (III) ، محققًا امتصاص 16.78٪ من Fe (III) في 150 دقيقة. تشير هذه النتائج إلى أن كربون قشور الجوز المنشط بكلوريد البوتاسيوم يمكن أن يكون بديلاً فعالاً للامتصاص لمعالجة المياه النظيفة في المستقبل.
Received 15/01/2024
Revised 27/09/2024
Accepted 29/09/2024
Published Online First 20/12/2024
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