تحضير,تشخيص ودراسة حرارية لمعقدات Cd(II), Zn(II), Cu(II),VO(II) و Au (III) معليكاند صبغة الازو وتقييمها كمضادات أكسدة

المؤلفون

  • اريج ملك فاضل وزارة التربية, مديرية تربية بغداد الرصافة الثانية.
  • عباس علي صالح الحمداني قسم الكيمياء, كلية العلوم للبنات, جامعة بغداد, بغداد, العراق.
  • وائل الزغبي مجموعة الكيمياء الكهربائية للمواد، كلية علوم وهندسة المواد، جامعة يونجنام، جيونجسان، جمهورية كوريا.

DOI:

https://doi.org/10.21123/bsj.2024.10985

الكلمات المفتاحية:

معقدات الازو، أصباغ الازو ، تاثير مضادات الاكسدة ، التحليل الحراري الوزني ، 2,4,6-هيدروكسي اسيتوفينون.

الملخص

حضرت معقدات كل من الفنادايل, الخارصين, النحاس والكادميوم بتكافؤهم الثنائي والذهب بتكافؤه الثلاثي بأستخدام صبغة ازوجديدة (6،4،2-ثلاثي هيدروكسي-3-((3-هيدروكسي فنيل) ثنائي زينيل ) فنيل ) ايثان-1-اون المحضرة من ملح الديازونيوم مع ٦,٤,٢- ثلاثي هيدروكسي اسيتوفينون بعد عزل (E)-1-(2,4,6-trihydroxy-3-((3-hydroxyphenyl)diazenyl)phenyl)ethan-1-one تم تشخيصها بواسطة الطرق الطيفية المتاحة  والتقنيات التشخيصية لكل من التحليل الدقيق للعناصرواطياف كل من الكتلة ,الرنين النووي البروتوني والكاربوني ,الاشعة فوق البنفسجية ,الاشعة تحت الحمراءومنحنى التحلل الحراري الوزني والمسعر التفاضلي والمعقدات شملت التقنيات هذه فضلا عن تحديد نسبة الفلز وتحديد محتوى الكلور والحساسية المغناطيسية والتوصيلية المولارية. أعطت النتائج أن الليكاند ايوني (سالب) رباعي السن مرة عند تناسقه مع النحاس والخارصين والكادميوم عن طريق ذرة الاوكسجين الفينولية و ذرة الاوكسجين الكاربونيلية وذرة نتروجين الازو , بينما كان ثلاثي السن عند التناسق مع الذهب الثلاثي من خلال ذرة الاوكسجين الفينولية وذرة نتروجين الازو حيث اعطى الذهب شكل مربع مستوي متعادل بينما الخارصين والكادميوم ثماني السطوح متعادل حاوي على جزيئتين ماء متناسقة واعطى النحاس شكل رباعي السطوح متعادل اما الفنادايل فاعطى شكلا ثنائي الهرم المثلثي متعادل. ثم تم تحديد قابلية هذه المركبات المحضرة كمضادات اكسدة من خلال كبحها للجذور الحرة باستعمال مادة DPPH كجذر حر وفيتامين C كمرجع لتحديد قيمة IC50التي اعطت النتائج(Au-complex >H4L>Ascorbic acid > Zn-complex> Cu-complex> Cd-complex>V-complex)

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كيفية الاقتباس

1.
تحضير,تشخيص ودراسة حرارية لمعقدات Cd(II), Zn(II), Cu(II),VO(II) و Au (III) معليكاند صبغة الازو وتقييمها كمضادات أكسدة. Baghdad Sci.J [انترنت]. [وثق 27 يوليو، 2024];22(2). موجود في: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/10985