دراسة مقارنة للتحضير الكيميائي والخضراء للسيليكا ذات المسام المتوسطة

المؤلفون

  • ساره قحطان داود قسم الكيمياء، كلية العلوم للبنات، جامعة بغداد، بغداد، العراق
  • سمير حكيم كريم قسم الكيمياء، كلية العلوم للبنات، جامعة بغداد، بغداد، العراق

DOI:

https://doi.org/10.21123/bsj.2024.11137

الكلمات المفتاحية:

أملوديبين، خافض للتوتر السطحي الكاتيوني، سيليكا مسامية، قالب ناعم، اوراق نبات السدر.

الملخص

يتضمن البحث الحالي دراسة مقارنة لتحضير السيليكا مسامية باستخدام طريقتين مختلفتين: الطريقة الكيميائية والطريقة الخضراء. تم استخدام طريقة sol-gel باستخدام سيليكات الصوديوم (الماء الزجاجي) كمصدر رخيص للسيليكا والمواد الخافضة للتوتر السطحي الكاتيونية في الطريقة الكيميائية، ومستخلص أوراق شجرة السدر بالطريقة الخضراء كقالب ناعم، وتمت مقارنة السيليكا المتوسطة المسام المحضرة باستخدام الطريقتين من خلال توصيفها باستخدام طرق مختلفة: قياس مساحة السطح بطريقة BET والمسامية بواسطة BJH، XRD، SAXRD، AFM، SEM و EDX أظهرت النتائج أن السيليكا المحضرة بالطريقة الخضراء حصلت على أفضل مساحة سطحية مسجلة 800 م2جرام-1 ومتوسط   قطر مسام يساوي 2.5 نانومتر، بينما أظهرت قياسات حيود الأشعة السينية أن كلا الطريقتين أنتجتا سيليكا غير بلورية (غيرمتبلورة)، بينما أظهرت طريقة  SAXRD  أن الطريقة الخضراء أنتجت سيليكا أكثر انتظاما، وأظهرت دراسة الامتزاز أن السيليكا المحضرة كيميائيا لديها قدرة أعلى على امتزاز الأملوديبين وفقا لمعايير فروندليتش التي تم الحصول عليها عن طريق التركيب الخطي.

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كيفية الاقتباس

1.
دراسة مقارنة للتحضير الكيميائي والخضراء للسيليكا ذات المسام المتوسطة. Baghdad Sci.J [انترنت]. [وثق 7 نوفمبر، 2024];22(5). موجود في: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/11137