دراسة مقارنة للتحضير الكيميائي والخضراء للسيليكا ذات المسام المتوسطة

المؤلفون

  • ساره قحطان داود قسم الكيمياء، كلية العلوم للبنات، جامعة بغداد، بغداد، العراق
  • سمير حكيم كريم قسم الكيمياء، كلية العلوم للبنات، جامعة بغداد، بغداد، العراق

DOI:

https://doi.org/10.21123/bsj.2024.11137

الكلمات المفتاحية:

أملوديبين، خافض للتوتر السطحي الكاتيوني، سيليكا مسامية، قالب ناعم، اوراق نبات السدر.

الملخص

يتضمن البحث الحالي دراسة مقارنة لتحضير السيليكا مسامية باستخدام طريقتين مختلفتين: الطريقة الكيميائية والطريقة الخضراء. تم استخدام طريقة sol-gel باستخدام سيليكات الصوديوم (الماء الزجاجي) كمصدر رخيص للسيليكا والمواد الخافضة للتوتر السطحي الكاتيونية في الطريقة الكيميائية، ومستخلص أوراق شجرة السدر بالطريقة الخضراء كقالب ناعم، وتمت مقارنة السيليكا المتوسطة المسام المحضرة باستخدام الطريقتين من خلال توصيفها باستخدام طرق مختلفة: قياس مساحة السطح بطريقة BET والمسامية بواسطة BJH، XRD، SAXRD، AFM، SEM و EDX أظهرت النتائج أن السيليكا المحضرة بالطريقة الخضراء حصلت على أفضل مساحة سطحية مسجلة 800 م2جرام-1 ومتوسط   قطر مسام يساوي 2.5 نانومتر، بينما أظهرت قياسات حيود الأشعة السينية أن كلا الطريقتين أنتجتا سيليكا غير بلورية (غيرمتبلورة)، بينما أظهرت طريقة  SAXRD  أن الطريقة الخضراء أنتجت سيليكا أكثر انتظاما، وأظهرت دراسة الامتزاز أن السيليكا المحضرة كيميائيا لديها قدرة أعلى على امتزاز الأملوديبين وفقا لمعايير فروندليتش التي تم الحصول عليها عن طريق التركيب الخطي.

المراجع

- Rahimzadeh CY, Barzinjy AA, Mohammed AS, Hamad SM. Green synthesis of SiO2 nanoparticles from Rhus coriaria L. extract: Comparison with chemically synthesized SiO2 nanoparticles. PloS One. 2022 Aug 5; 17(8): e0268184. https://doi.org/10.1371/journal.pone.0268184

- Ganesan K, Vanathi P, Sasthri G, Ganeshan A, Periakaruppan R. Green synthesis and characterization of Halymenia floresia-mediated silica nanoparticles with antibacterial potential for removal of heavy metals from water. Biomass Conv Bioref. 2023 Dec 27: 1-7. https://doi.org/10.1007/s13399-023-05239-w

- Periakaruppan R, Samadh SPA, Abed SA, Al-Dayan N, Dhanasekaran S, Aldhayan SHA. Allium cepa-assisted biogenic silica dioxide nanoparticles: their production, structural characterization, and antioxidant activity. Biomass Conv. Bioref. 2023 Jul 28: 1-9. https://doi.org/10.1007/s13399-023-04636-5

- Brezoiu AM, Prundeanu M, Berger D, Deaconu M, Matei C, Oprea O, et al. Properties of Salvia officinalis L. and Thymus serpyllum L. Extracts Free and Embedded into Mesopores of Silica and Titania. Nanomater. 2020 Apr 25; 10(5): 820. https://doi.org/10.3390/nano10050820

- Petrisor G, Ficai D, Motelica L, Trusca RD, Bîrcă AC, Vasile BS, et al. Mesoporous Silica Materials Loaded with Gallic Acid with Antimicrobial Potential. Nanomater. 2022 May 12; 12(10): 1648. https://doi.org/10.3390/nano12101648

- Alazzawi HF, Salih IK, Albayati TM. Drug delivery of amoxicillin molecule as a suggested treatment for covid-19 implementing functionalized mesoporous SBA-15 with aminopropyl groups. Drug Deliv. 2021; 28(1): 856-864.‏‏https://doi.org/10.1080/10717544.2021.1914778

- Pagar NS, Karandikar PR, Chandwadkar AJ, Deshpande RM. Synthesis, characterization and catalytic study of mesoporous carbon materials prepared via mesoporous silica using non-surfactant templating agents. J Porous Mater. 2020 Nov 9; 28(2): 423–33. https://doi.org/10.1007/s10934-020-01003-x

- Telalović S, Ramanathan A, Mul G, Hanefeld U. TUD-1: synthesis and application of a versatile catalyst, carrier, material. J Mater Chem. 2010 Jan 1; 20(4): 642–58. https://doi.org/10.1039/b904193a

- Abduljabbar AT, Dhahir SA, Abood WM. Furfural Removal from Simulated Wastewater Using Zno Nanoparticles / H2O2 in Solar Photocatalysis Reactor. Int J Mod Phys Conf Ser. 2021 Mar 1; 1818(1): 012048. https://doi.org/10.1088/1742-6596/1818/1/012048

- Abdulsada ZS, Hassan SS, Awad SH. Removal of Some Heavy Metals from Polluted Water Using New Schiff Base for Polyacrylamide with Zeolite Nanocomposites. Baghdad Sci J.. https://doi.org/10.21123/bsj.2024.8591

- Ghaedi H, Zhao M. Review on template removal techniques for synthesis of mesoporous silica Materials. Energy Fuel. 2022 Feb 19; 36(5): 2424–46. https://doi.org/10.1021/acs.energyfuels.1c04435

- Ravetti-Duran R, Blin JL, Stébé MJ, Castel C, Pasc A. Tuning the morphology and the structure of hierarchical meso–macroporous silica by dual templating with micelles and solid lipid nanoparticles (SLN). Front Chem Biol. 2012 Jan 1; 22(40): 21540. https://doi.org/10.1039/c2jm35004a

- Ulfa M, Aristia KS, Prasetyoko D. Synthesis of mesoporous silica materials via dual templating method from starch of waste rice and their application for drug delivery system. AIP Conf Proc 2012; 2049(1). AIP Publishing. https://doi.org/10.1063/1.5082407

- Dolete G, Purcăreanu B, Mihaiescu DE, Ficai D, Oprea OC, Bîrcă AC, et al. A Comparative Loading and Release Study of Vancomycin from a Green Mesoporous Silica. Molecules. 2022 Aug 30; 27(17): 5589. https://doi.org/10.3390/molecules27175589

- Maroušek J, Maroušková A, Periakaruppan R, Gokul GM, Anbukumaran A, Bohatá A, et al. Silica Nanoparticles from Coir Pith Synthesized by Acidic Sol-Gel Method Improve Germination Economics. Polymers. 2022 Jan 10; 14(2): 266. https://doi.org/10.3390/polym14020266

- Ahmadi MA, Shadizadeh SR. Spotlight on the new natural surfactant flooding in carbonate rock samples in low salinity condition. Sci Rep 2018 Jul 20; 8(1).10985 https://doi.org/10.1038/s41598-018-29321-w

- Yagoub AEA, Alshammari GM, Subash-Babu P, Mohammed MAA, Yahya MA, Alhosain AI. Synthesis of Ziziphus spina-christi (Jujube) Root Methanol Extract Loaded Functionalized Silver Nanoparticle (ZS-Ag-NPs); Physiochemical Characterization and Effect of ZS-Ag-NPs on Adipocyte Maturation, Adipokine and Vascular Smooth Muscle Cell Interaction. Nanomater. 2021 Sep 29; 11(10): 2563. https://doi.org/10.3390/nano11102563

- Tokumura T, Watarai Y, Morita Y. Adsorption of amlodipine besylate to corn starch and microcrystalline cellulose suspended in aqueous solution. Future J Pharm Sci. 2021 Jan 1; 81(2): 200–4.

- Londono C, Barrera K, Rojas J. Synthesis of Urea and Magnetite -Based Chitin as Adsorbents for the Removal of Amlodipine Besylate. Int J Pharm Pharm Sci. 2023 Sep 1; 24–31. https://doi.org/10.22159/ijpps.2023v15i9.48685

- Dleam EA, Kareem SH. Mesoporous silica nanoparticles as a system for ciprofloxacin drug delivery; kinetic of adsorption and releasing. Baghdad Sci J. 2021 Jun 1; 18(2): 0357. https://doi.org/10.21123/bsj.2021.18.2.0357

- Abou Abou Rida M, Harb F. Synthesis and characterization of amorphous silica nanoparitcles from aqueous silicates uisng cationic surfactants. Npj Mater Degrad. 2014 Jun 30: 24(1):37-42

- Jin X, Ge J, Zhang L, Wu Z, Zhu L, Xiong M. Synthesis of hierarchically ordered porous silica materials for CO2 capture: The role of pore structure and functionalized amine. Inorganics. 2022 Jun 21; 10(7): 87- 100. https://doi.org/10.3390/inorganics10070087

- Sharma P, Kherb J, Prakash J, Kaushal R. A novel and facile green synthesis of SiO2 nanoparticles for removal of toxic water pollutants. Appl Nanosci. 2021 Jun 5; 13(1): 735–47. https://doi.org/10.1007/s13204-021-01898-1

- Bajpai N, Tiwari A, Khan SA, Kher RS, Bramhe N, Dhoble SJ. Effects of rare earth ions (Tb, Ce, Eu, Dy) on the thermoluminescence characteristics of sol–gel derived and γ‐irradiated SiO2 nanoparticles. Lumin. 2013 Nov 13; 29(6): 669–73. https://doi.org/10.1002/bio.2604

- Albayati TM, Jassam AAA. Experimental Study of Drug Delivery system for Prednisolone Loaded and Released by Mesoporous Silica MCM-41. AL-Khawarizmi Eng. J. 2019 Mar 1; 15(1): 117–24. https://doi.org/10.22153/kej.2019.06.004

- Maqbool Q, Chanchal A, Srivastava A. Tween 20‐Assisted Synthesis of Uniform Mesoporous Silica Nanospheres with Wormhole Porosity for Efficient Intracellular Curcumin Delivery. Chemistry Selec. 2018 Mar 22; 3(11): 3324–9.https://doi.org/10.1002/slct.201800386

- Dolete G, Purcăreanu B, Mihaiescu DE, Ficai D, Oprea OC, Bîrcă AC, et al. A Comparative Loading and Release Study of Vancomycin from a Green Mesoporous Silica. Molecules. 2022 Aug 30; 27(17): 5589.https://doi.org/10.3390/molecules27175589

- Hussein EA, Kareem SH. Magnetic mesoporous silica material (Fe3O4@mSiO2) as adsorbent and delivery system for ciprofloxacin drug. IOP Conf Ser Mater Sci Eng. 2020 Jun 1; 871(1): 012020. https://doi.org/10.1088/1757-899x/871/1/012020

- Saed SA, Aidan D. Influence of acid activation of a mixture of illite, koalinite, and chlorite clays on the adsorption of methyl violet 6B dye. Iraqi J Sci. 2021 Jul 1; 1761-1778. https://doi.org/10.24996/ijs.2021.62.6.2

- Thommes M, Kaneko K, Neimark AV, Olivier JP, Rodriguez-Reinoso F, Rouquerol J, et al. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl Chem. 2015 Jul 2; 87(9–10): 1051–69. https://doi.org/10.1515/pac-2014-1117

- Naseem T, Baig MM, Warsi MF, Hussain R, Agboola PO, Waseem M. Mesoporous silica prepared via a green route: a comparative study for the removal of crystal violet from wastewater. Mate Res Express. 2020 Dec 30; 8(1): 015005. https://doi.org/10.1088/2053-1591/abd45d.

- Parashar D, Gandhimathi R. Zinc Ions adsorption from aqueous solution using raw and acid-modified orange peels: Kinetics, Isotherm, Thermodynamics, and Adsorption mechanism. Water Air Soil Pollut 2022 Sep 22; 233(10). https://doi.org/10.1007/s11270-022-05857-6.

- Ali IH. Removal of congo red dye from aqueous solution using Eco-Friendly adsorbent of nanosilica. Baghdad Sci J. 2021 Jun 1; 18(2): 0366.‏‏https://doi.org/10.21123/bsj.2021.18.2.0366.

- Hussain Z, Fadhil Z, Kareem S, Mohammed S, Yousif E. Removal of Organic Contaminants from Textile Wastewater by Adsorption on Natural Biosorbent. Mater Sci Forum 2020; 1002: 489–97. https://doi.org/10.4028/www.scientific.net/MSF.1002.489.

التنزيلات

إصدار

القسم

article

كيفية الاقتباس

1.
دراسة مقارنة للتحضير الكيميائي والخضراء للسيليكا ذات المسام المتوسطة. Baghdad Sci.J [انترنت]. [وثق 21 نوفمبر، 2024];22(5). موجود في: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/11137