II- تحضير ودراسة معقدات بعض العناصر الانتقالية لبعض مشتقات قواعد شف
محتوى المقالة الرئيسي
الملخص
يتضمن البحث تحضير معقدات لبعض مشتقات قواعد شف( كليكندات) ذات التراكيب التالية :
( -2هيدروكسي- بنزيليدين ) - ثايويوريا=(L1)
( -2هيدروكسي- بنزيليدين ) - يوريا =(L2)
تم تحضير معقدات لهذه الليكندات مع بعض املاح العناصر الانتقالية التي تشمل (Zn+2,Cd+2,Hg+2) وقد تم تشخيص ودراسة تراكيب الليكندات والمعقدات المحضرة باستخدام تقنية التحليل الدقيق للعناصر (C.H.N) ومطيافية الاشعة تحت الحمراء والاشعة فوق البنفسجية وتقنية الامتصاص الذري اضافة الى قياس الموصلية الكهربائية المولارية ودرجات الانصهار للمعقدات المحضرة وعلى ضوء النتائج تم تعيين التركيب الهندسي لهذه المعقدات.
تفاصيل المقالة
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كيفية الاقتباس
المراجع
-Sigal, H. (1979)."Metal ion in Biological Systems". Dekker, New York.
-Dugas.H, L. Penney, (1981), "Bioorganic Chemistry". Speringer-Verlag.
-Williams.D.R. (1971)." The Metal of Life". Van Nostrand, London.
-Mostava, M.M., Shallaby A.M., El.Asmy, A.A.,(1981).,Transition Metal complexes of 4- phenyl thiosimecarbazide., J.Inorg.Nucl. Chem, 43: 2992.
-Hughes, M.N., (1988)"The inorganic chemistry of biological processes," 2nd ed.,John wiley and sons.
-Catssch, A., Harmuth and D.P. Meller, (1979) "The Chelation of Heavy Metals". Pergamon press,oxford,New york.
-Moheshwari, G.L., Maheshand R.P., Singh P., (1976). "Synthesis of some heterocyclic derived from Lionyl-4-substituted thiosemicarbazide Curr.Sci, 1975, 44,594; Chem.Abs. 83,193185j.
-Cotton, F.A., Wilkinson,G.,(1980),"Advanced inorganic chemistry ", 4th ed., Interscince ,New york , 690.
-Chatterjee, A., Adityaa chauduru B.Das,N., Kirtaniyaniya S.D., (1980)."Kinetics of benziliden-induced Decomposition of Dibenzoyl peroxide in viscous media. Indian. J.Chem. 19:163.
-Chiyomaru, I., Yoshinago, E., Kawata, H., Ito, H. (1973)." Bactericidal thiadiazole Compositions for Agricultural use", Japan, 7343, 615; Chem,Abs., (1974).31:59323b.
-Bhagwan, S, G, Vinod K., and Malladi J.R. (1966).Synthesis and spectral studies of zinc (II) and Palladium (II) complexes of amide ligands derived from 2-amino pyridine .Indian.j. Chem., 35A:598-600.
-Catsch, A., Harmuth.Hoene, A.E., Meller, D.P., (1979).”The Chelation of Heavy Metals “, PergamonPress ,Oxford,Newyork.
-Mohan, M., Gupta.N.S., Lakhan,Chandra and Sha, N.K., ., (1987)." Synthesis, characterization and Antitumor preparations of some Metal complexes of 3-and5-substituted salicyaldehyde 2-pyridinyl hydra zone". J.Inorg. Biochem., 31(1):70.
-Orgel, L.E., (1981) "An introduction to Transition Metals Chemistry," John Willy and sons. inc., New york.
-Nakamishi, N., (1962)."Practical infrared absorption spectroscopy:., Nankedo company, ltd. Tokyo.
-Hassan, A.H., (1998)., Synthesis and study of the complexes of the thiourea derivatives with a nuber Of transition Metals.,Ph.d thesis, al- mustansyria Uni.
-Al-Hitie, W.F.,Al-Hadethy, M.A., (2005) . Synthesis, characterization and Kinetic Studies of Oxazepine and Oxazepine from reaction of 1,3-Bis(2-hydroxy-benzylidene)-urea and 1,3-(bis-(Dimethyl amine benzylidene)-urea with malic,Succinic and phthalic anhydride Al- Nhrain UN. SC. J., (2) , pp 27-34.
- Al-Obaidi O.H., (1997). Preparation and study of some (transition metal-flavylium salt-chalcon or flavon., M.Sc. al- mustansyria Uni.
-Yamaguchi, A., Miyazawa T., Shimanouchi T., and Mizushimo S., (1957) Normasl vibration of urea And urea-d4., Spectro.Chimi. Acta , 10:170
-Freema, H.C.(1973).," Metal complexes of amino acids and peptides from inorganic biochemistry"., ed.,Gunther L.E., Cholorn . Elesevir 1:121.
-Murrel.J.N., (1963)"the theory of the electronic spectra of organic molecules"1st .ed. Methuen co. ltd. London pp.158
-Tamura, J., et.al., (1983)."Structures of a succinyl anthocynine and a malonyl flavone , two Constituents of the complexes blue pigment of corn flower cantaurea cyanus.,Tetrahedron Lett, 24: 5749.
-Silverstein, R.M., Bassler, G.C., (1981)."Spectrometric Identification of Organic Compound," 4thEd. John Wiely and Sons Ltd .New York.
-AlMukhtar, S.E., Mostafa I.A.,(1988). "Inorganic and Coordination chemistry (Arabic Version) Pp.611-613
-Gillam.A.E., (1957)." AnIntroduction to Electronic Absorption Spectroscopy" 2nd .ed.Edward Arnold Ltd., London.
-Rao C.N.R.(1967)." Ultraviolet and visible spectroscopy chemical application ,"2nd., ed. Butter Worths Ltd. London .pp 77-78
-Gillam, A.E., Strm, E.S., (1957). "An Introduction to the Electronic Absorption Spectroscopy", 2nd Ed.Edward Arnold Ltd,London, P.115,150.
-Silverstein, R.M., Bassler, G.C., (1969) "Spectrometric Identification of Organic Compound," 2ndEd. John Wiely and Sons Ltd .New York.