تحضير ودراسة الخواص التركيبية والبصرية لمادة Pb1-xCdxS النانوية للتطبقات الشمسية
الشريط الجانبي للمقالة
محتوى المقالة الرئيسي
الملخص
تم تحضير الجسيمات النانوية لـ Pb1-xCdxS ضمن تركيبة x≤1≤0 من تفاعل المحلول المائي لأسيتات الكادميوم ، أسيتات الرصاص ، ثيوريا ، و NaOH بواسطة الترسيب الكيميائي المشترك. تميزت العينات التي تم تحضيرها بواسطة التحليل الطيفي للأشعة فوق البنفسجية (في نطاق 300-1100 نانومتر) لدراسة الخواص الضوئية و AFM و SEM للتحقق من و Pb0.75 Cd0.25 و Pb0.5Cd0.5S و Pb0.25Cd0 75S ، و CdS على التوالي ، ونقاء المرحلة. تشير النتائج إلى أن البنية البلورية لجميع العينات المحضرة هي مكعبة باستثناء CdS التي تظهر بنية سداسية شكل السطح (متوسط الخشونة والشكل) وحجم الجسيمات. تم استخدام تقنية XRD لتحديد البنية البلورية ، ومتوسط الحجم البلوري للجسيمات النانوية والتي هي 20.7 و 15.48 و 11.9 و 11.8 و 13.65 نانومتر لـ PbS ومكعبة ، وكان حجم الجسيمات (النطاق بين 64.81 إلى 91.14 نانومتر) في المدى النانوي ، ولها درجة نقاء عالية.
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كيفية الاقتباس
المراجع
Barot M A,Yadav A A, Masumdar E U. Effect of deposition parameters on growth and characterization of chemical deposited Cd1-x Pbx S thin film. Chalcogenide Lett. 2001; 8(2):129-138.
Wang Y, Huang Y, Li H, Zhou Y, Wan L, Niu H, et al. In Situ Growth of PbS Nanocubes as Highly Catalytic Counter Electrodes for Quantum Dot Sensitized Solar Cells. IEEE J Photovolt. 2018; 8(6): 1670-1676.
Agidew S A. Effect of Cation Precursor Concentration on the Structural, Morphological and Optical Properties of Lead Sulphide (PbS) Thin Films Synthesized by Chemical Bath Deposition Method. MSc Thesis, Hawassa University, Hawassa, Ethiopia, June, 2017.
Ampong FK, Nkrumah I, Nkum RK, Boakye F. Investigating the structure, morphology and optical band gab of cadmium sulphide thin film grown by chemical bath deposition. IJTRA. 2014; 2(6): 91-93.
Göde F, ünlü S. Structural, Morphological and Optical Properties of Chemically Deposited Nanocrystalline Cadmium Sulfide Thin Films. J. Nanoelectron. Optoelectron. 2019; 14(7): 939-944.
Wang Y, Liu Z, Huo N, Huo N, Li F, Gu M, et al . Room-temperature direct synthesis of semi-conductive PbS nanocrystal inks for optoelectronic applications. Nat Commun. 2019; 10: 5136.
Hone F G, Ampong FK, Abza T, Nkrumah I, Nkum R K, Boakye F. Investigating the effect of deposition time on morphology, structure and optical gap of PbS thin films synthesized by CBD technique. Elixir Thin Film Tech. 2014; 76: 28432-28436.
Deshmukh L P, More B M. Preparation and properties of (CdS)x-(PbS)1-x thin-film composites. Bull. Mater Sci. 1994; 17(5): 455-463.
Himadri D, Pranayee D, Kandarpa S K. Synthesis of PbS nanoparticles and its potential as a biosensor based on memristic properties. J Nanosci Tech. 2018; 4(5): 500-502.
Hepi P, Devamani M, Archana K, Maheshwari D. Syntheses and Characterization of LeadII Sulphide Nanoparticles. IJESI. 2018; 7(1): 58-65.
Muthuraj V, Umadevi M, Sankarasubramanian K, Kajamuhideen MS. Synthesis of CdS nanoparticles for photocatalytic application of methylene blue degradation. AIP Conf Proc, 2014; 1591: 514-515.
Shaik R, Bokka D, Santoshi G R, Boddeti G, Nowduri A. Syntheses and Characterization of CdS Nanoparticles using reishi mushroom. IJAST. 2016; 4(06).
Khan MJ, Kanwal Z, Usmani MN, Zeeshan M, Yousaf M. An insight into optical properties of Pb:CdS system (a theoretical study). Mater Res Express. 2019; 6(6): 065904.
Thangavel S, Ganesan S, Chandramohan S, Sudhagar P, Soo Y, Chang-Hee H. Band gap engineering in PbS Nanostructured thin films from near-infrared down to visible range by in situ Cd- doping. J Alloys Compd. 2010; 495: 234-237.
Modaffer A, Mousa AM, Ponpon JP. Optical and optoelectronic properties of PbCdS ternary thin films deposited by CBD . J Semicond Technol Sci. 2009; 9(2): 1-6.
Deshmukh LP, More BM, Rotti CB. Shahani GS. Polycrystalline n-PbxCd1-xS mixed electrodes for photoelectrochemical(PEC)solar cell. Mat Chem Phys. 1996: 45: 145-149.
Rohom AB, Londhe PU, Jadhav PR, Bhand GR, Chaure NB.Studies on chemically synthesized PbS thin films for IR detector. J Mater Sci-Mater El. 2017; 28:17107–17113.
Dhawankar SH, Suryavanshi BM.. Characterization of cadmium sulphide (CdS) thin film deposited by spray pyrolysis technique. Int J Phys Sci . 2016 4; (2) 58-61.
Qutub N, Pirzada B M, Umar K , Sabir S. Synthesis of CdS nanoparticles using different sulfide ion precursors: Formation mechanism and photocatalytic degradation of Acid Blue-29. J Environ Chem Eng. 2016;4(1), 808–817.
Sathiyaraj E, Thirumaran S. Effect of precursor on morphology of lead sulfide nanoparticles . J Chin Chem Soc. 2015; 3(2), 137–147...
Cullity B D, Stock S R. Elements of x-ray diffraction. 3rd ed., Prentice Hall, New york, 2001.
Rajashree C, Balu AR, Nagarethinam VS. Properties of Cd doped PbS thin films: doping concentration effect. Suf Eng . 2015; 31: 319–321.
Rajathi S, Kirubavathi K, Selvaraju K.Preparation of nanocrystalline Cd-doped PbS thin films and their structural and optical properties. J Taibah Univ Sci. 2017; 11: 1296–1305.
Dawood YZ, Kadhim SM, Mohammed AZ. Structure and Optical Properties of Nano PbS Thin Film Deposited by Pulse Laser Deposition. Eng Tech Journal. 2015; 33(9): Part (B) Scientific Pages 1723-1730.
Abbas NK, Al-Fawade EM, Alatya SJ.Structure and Optical Investigations of (PbSxSe1-x) Alloy and Films .Mater Sci Eng. A. 2013 Feb 1;3(2A):82.
AADIM K, IBRAHIM A, MARIE J. Structural and optical properties of PbS thin films deposited by pulsed laser deposited (PLD) technique at different annealing temperature. Int. J. Phys. 2017;5(1):1-8.
Nada KA. A study of the effect of thin film thickness on the A.C electrical properties of CuS thin films . Baghdad Sci J. 2006; 3: 4.