تحضير، تشخيص وتحليل حراري لبعض معقدات العناصر مع ليكاند آزو حامضية جديدة

محتوى المقالة الرئيسي

Rasha Khider Hussain Al-Daffay
Abbas Ali Salih Al-Hamdani

الملخص

حضرت معقدات جديدة للكروم الثلاثي والنحاس الثنائي والكوبلت الثنائي والمنغنيز الثنائي والخارصين الثنائي والروثينيوم الثنائي والروديوم الثلاثي باستخدام  ليكاندالآزو الجديد  4 -((2-امينو-4-فنيل ازو)-مثيل)-سايكلوهكسان حامض كاربوكسيلي تم تشخيص المركبات المحضرة باطياف (الاشعة تحت الحمراء الاشعة فوق البنفسجية – المرئية والكتلة والرنين النووي المغناطيسي البروتوني) اضافة الى التحليل الدقيق  للعناصر ومنحنى التحلل الحراري الوزني مع قياس التوصيلية المولارية وتحديد نسبة الفلز ، اعطت نتائج التحليل ان الليكاند يسلك ثنائي السن مع الكوبلت والنحاس والمنغنيز بينما ثلاثي السن مع بقية العناصر المذكورة سابقا وقد اعطى  الكوبلت والمنغنيز معقد رباعي السطوح بينما معقد النحاس مربع مستوي ومعقدات الكروم والروثينيوم والروديوم والخارصين  ثماني السطوح وبينت دراسة التحلل الحراري استقرارية المركبات حراريا ووجود جزيئات ماء داخل مجال التناسق. يسلك الليكاند سلوك ثلاثية السن متعادل الشحنة في تناسقه مع ايونات الكروم الثلاثي والخارصين الثنائي والروثيميوم الثلاثي والروديوم الثلاثي من خلال ذرة النيتروجين لمجموعتي الامينية والازو وكذلك الاوكسجين لمجموعة الفينولية .بينما تناسق الليكاند مع النحاس الثنائي والكوبلت الثنائي والمنغنيز الثنائي يكون عن طريق النيتروجين لمجموعتي الامين والازو وبالتالي يسلك الليكاند ثنائية السن متعادل الشحنة.

تفاصيل المقالة

كيفية الاقتباس
1.
تحضير، تشخيص وتحليل حراري لبعض معقدات العناصر مع ليكاند آزو حامضية جديدة. Baghdad Sci.J [انترنت]. 1 فبراير، 2023 [وثق 22 فبراير، 2025];20(1):0121. موجود في: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6709
القسم
article

كيفية الاقتباس

1.
تحضير، تشخيص وتحليل حراري لبعض معقدات العناصر مع ليكاند آزو حامضية جديدة. Baghdad Sci.J [انترنت]. 1 فبراير، 2023 [وثق 22 فبراير، 2025];20(1):0121. موجود في: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6709

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