معالجة المياه من الملوثات العضويةو اللاعضوية باستخدام دقائق الزنك النانوية مع مستخلص نبات المشمش
محتوى المقالة الرئيسي
الملخص
نبات المشمش تم غسلهُ، طحنه بعد حصاده للحصول على مسحوق جيد ليستخدم في معالجة المياه. تم استخدام نبات المشمش مع الايثانول للحصول على المستخلص الكحولي وتم تشخيصهُ بالتقنيات الطيفية كروموتوغرافيا الغاز، تقنية الاشعة تحت الحمراء، تقنية الاشعة فوق البنفسجية – المرئية، الطيفيةلتحديد المركبات الفعالة للمستخلص. مركب الزنك النانوي تم تحضيره باستخدام المستخلص الكحولي وتشخيصهُ بالتقنيات الطيفية (الاشعة تحت الحمراء، الاشعة فوق البنفسجية المرئية، فحص المجهر الالكتروني الماسح، مطيافية تشتت الاشعة السينية، المجهر الالكتروني النافذ)-)لتشخيص المركب الزنك النانوي. تم استخدام طريقة التدفق المستمر، مركب الزنك النانوي مع مستخلص المشمش الكحولي ومسحوق نبات الجت لمعالجة المياه الملوثة. أولا استخدمت 2 غرام من مركب الزنك النانوي مع 20 مل من المياه الملوثة وكانت النتيجة ( Tetra 44%، Levo 32%)، بعد ذلك استخدمت 4 غرام وكانت النتائج (Tetra 100%، Levo 100%). ثانياً، استخدم مسحوق نبات المشمش لمعالجة المياه وكانت النتيجة (Tetra 100%، Levo 100%). عند المقارنة بين مسحوق المشمش ومركب الزنك النانوي مع مستخلص المشمش وجد ان المعالجة باستخدام مركب الزنك النانوي افضل. ثالثاًاستخدم 2 غرام من مسحوق الزنك النانوي واظهرت نتائج المعالجة (Fe 99.50%، Cr 99.10%، Pb 100%، Sb 95%، Cd 95%، Cu 100%) وثم تم استخدام 4 غرام من مسحوق النانو (Fe 98.75%، Cr 83.40%، Pb 100%، Sb 77.50%، Cd 95.80%، Cu 100%).
Received 14/10/2022,
Revised 29/1/2023,
Accepted 30/1/2023,
Published Online First 20/5/2023
تفاصيل المقالة
هذا العمل مرخص بموجب Creative Commons Attribution 4.0 International License.
كيفية الاقتباس
المراجع
Ajmi RN, Sultan M, Hanno SH. Bioabsorbent of Chromium, Cadmium, and Lead from Industrial Waste Water by the Waste Plant. J Pharm Sci Res. 2018; 10(3): 672-674. http://dx.doi.org/10.1016/j.colsurfb.2017.02.020
Al-Hadithy AH, Motlag KH, Sharaf ME, Hashim LQ. Using of Rustumiya sewage water for irrigation: its effect on some soil properties and corn growth. Baghdad Sci J. 2011; 8(1): 179-187.http://dx.doi.org/10.21123/bsj.2016.13.3.0511
Al-Bahadili ZR, Al-Hamdani AAS, Rashid FA, Al-Zubaidi LA, Ibrahim SM. An Evaluation of the Activity of Prepared Zinc Nanoparticles with Extract of Alfalfa Plant in the Treatment of heavy metals. Baghdad Sci J. 2022 November; 19(6): 1399-1409. https://dx.doi.org/10.21123/bsj.2022.
Ahmadi R A, Amani S. Synthesis, Spectroscopy, Thermal Analysis, Magnetic Properties and Biological A. ctivity Studies of Cu(II) and Co(II) Complexes with Schiff Base Dye Ligands. Molecules. 2012; 17(6): 6434-6448. https://doi.org/10.3390/molecules17066434
Xia J, Duan QY, Luo Y, Xie ZH, Liu ZY, Mo XG. Climate change and water resources: Case study of Eastern Monsoon Region of China. AdvClim Change Res. 2017 Jun 1; 8(2): 63-67. https://doi.org/10.1016/j.saa.2015.02.011
Barrahi, M, Elhartiti H, El Mostaphi A, Chahboun N, Saadouni M et al. Corrosion inhibition of mild steel by Fennel seeds (Foeniculumvulgare Mill) essential oil in 1 M hydrochloric acid solution.Int J Corros. 2019; 8(4): 937–953. https://doi.org/10.17675/2305-6894-2019-8-4-9
Sadiq H, Sher F, Sehar S, Lima EC, Zhang S, Iqbal HM, et al. Green synthesis of ZnO nanoparticles from SyzygiumCumini leaves extract with robust photocatalysis applications. J Mol Liq. 2021Aug 1; 335: 116567. https://doi.org/10.1016/j.saa.2015.02.011 .
Jayanthi P, Lalitha P. Reducing power of the solvent extracts of Eichhorniacrassipes (Mart.) Sold. Int. J Phar Phar Sci. 2011; 3(3): 126-8. https://doi.org/10.22034/AJGC.2021.261206.1287 .
Matinise N, Fuku XG, Kaviyarasu K, Mayedwa N, Maaza MJ. ZnO nanoparticles via MoringaOleifera green synthesis: Physical properties & mechanism of formation. App Sur Sci. 2017 Jun 1; 406: 339-347. https://doi.org/10.1016/j.apsusc.2017.01.219
Christian P, Kammer FV, Baalousha M, Hofmann H. Nanoparticles: Structure, Properties, Preparation and Behaviors in Environmental Media. Ecotoxicology.2008; 17(5): 326-343. https://doi.org/10.1007/s10646-008-0213-1
Al-Khazraji AMA, Al Hassani RAM. Synthesis, Characterization and Spectroscopic Study of New Metal Complexes form Heterocyclic Compounds for Photostability Study. Syst Rev Pharm. 2020; 11(5): 535-555. https://doi.org/10.31838/srp.2020.5.71
Samy ME, Moamen SR, Fawziah AA, Reham ZH. Situ Neutral System Synthesis, Spectroscopic, and Biological Interpretations of Magnesium(II), Calcium(II), Chromium(III),Zinc(II), Copper(II) and Selenium(IV) Sitagliptin Complexes. Int J Environ Res Public Health. 2021; 18(8030): 1-19. https://doi.org/10.3390/ijerph18158030
Abdallah, M, Altas HM, Al-Gorair AS, Jabir H, Al-Fahemi BAAL et al. Natural nutmeg oil as a green corrosion inhibitor for carbon steel in 1.0 M HCl solution: Chemical. Electrochemical, and computational methods. J MolLiq 2021; 323: 115036. https://doi.org/10.1016/j.molliq.2020.115036.
Al-Zoubi W, Kim MJ, Yoon DK, Al-Hamdani AA, Kim YG, Young GK. Effect of organic compounds and rough inorganic layer formed by plasma electrolytic oxidation on photocatalytic performance. J Alloys Compd. 2020 May 15; 823: 153787. https://doi.org/10.3390/membranes12050516 .
Al- Hamdani AAS, Al- Zoubi W. synthesis and antioxidant activities of Schiff bases and their complexes. ApplOrganomet Chem. 2016; 32(3): 11864-11876. https://doi.org/10.5606/tftrd.2020.6889.
Reda SM, Al-Hamdani AAS. Mn(II), Fe(III), Co(II) and Rh(III) complexes with azo ligand: Synthesis, characterization, thermal analysis and bioactivity. Baghdad Sci J. 2022. November; 20(6): 1399-1409. https://doi.org/10.21123/bsj.2022.7289 .
Al- Zoubi W, Kim MJ, Al-Hamdani AAS, Kim YG, Ko YG. Phosphorus-based and their complexes as nontoxic antioxidants: structure- activity relationship and mechanism of action. Appl. Organomet. Chem. 2019; 33(11): e5210. https://doi.org/10.1016/j.matpr.2020.07.368
Tyner KM, Wokovich AM, Doub WH, Watson N. Sadrieh Comparing methods for detecting and characterizing metal oxide nanoparticles in unmodified commercial sunscreens. Nanomedicine. 2009; 4(12): 145-159. https://doi.org/10.2217/17435889.4.2.145
González-Ballesteros N S, Prado-López J, Rodríguez-González B, Lastra M, Rodríguez-Argüelles MC. Green synthesis of gold nanoparticles using brown algae, Cystoseirabaccata: Its activity in colon cancer cells. Colloids Surf. B. 2017; 15(3): 190-198. https://doi.org/10.1016/j.colsurfb.2017.02.020
Obaid S M H, Sultan J S, Synthesis, Characterization and Biological Efficaciesfrom Some New Dinuclear Metal Complexes for Base 3-(3, 4-Dihydroxy-phenyl)-2-[(2-hydroxy-3-methylperoxy-benzylidene)-amino]-2-methyl Propionic Acid. Indones. J. Chem. 2020; 20(6), 1311-1322. https://dx.doi.org/10.21123/bsj.2022.6709
Rahman A, De Clippeleir H, Thomas W, Jimenez JA, Wett B, Al-Omari A, Murthy. A-stage and high-rate contact-stabilization performance comparison for carbon and nutrient redirection from high-strength municipal wastewater. ChemEng J. 2019; 3(57): 737-749 https://doi.org/10.1016/j.cej.2018.09.206
Kirill VY, Aleksandr SS, Werner K, Sergey AG. Synthesis, Crystal Chemistry of Octahedral Rhodium (III) Chloroamines. Molecules Sci J. 2020; 25(768): 1-17. https://doi.org/10.3390/molecules25040768
Lingmei L, Yang W, Li Q, Gao S, Shang JK. Synthesis of Cu2O nanospheres decorated withTiO2nanoislands, their enhanced photoactivity stability under visible light illumination, and theirpost-illumination catalytic memory. ACS Appl Mater Interfaces. 2014; 6: 5629–5639. https://doi.org/10.1016/j.colsurfb.2017.02.020
Moamen SR, AltalhiT.,Safyah BB, Ghaferah HA and Kehkashan A. New Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Zn(II), Cd(II), and Hg(II) GibberellateComplexes: Synthesis, Structure and Inhibitory Activity Against COVID-19 Protease. Russ J Gen Chem. 2021; 91(5): 890–896. https://doi.org/10.21123/bsj.2022.7289. .
Rahman A, De Clippeleir H, Thomas W, Jimenez JA, Wett B, Al-Omari A, et al. A-stage and high-rate contact-stabilization performance comparison for carbon and nutrient redirection from high-strength municipal wastewater. ChemEng J. 2018; 10(7): 878-896. https://doi.org/10.1016/j.scitotenv.2013.07.022
Maurice K, Mariam AC, Katia NN, Awawou GP, Sally-Judith EN,Peter TN. Synthesis, Characterization and Antimicrobial Studies of Co(II), Ni(II), Cu(II) and Zn(II) Complexes of (E)-2-(4-Dimethylbenzydimino)-Glycylglycine,(Glygly-DAB) a Schiff Base Derived from 4-Dimethylaminobenzaldehyde and Glycylglycine. Int J Org Chem. 2018; 8: 298-308. https://doi.org/10.4236/ijoc.2022.124015
Al Zoubi W, Saad G M, Agastya PM, Young GK. Acyclic and cyclic imines and their metal complexes: recent progress in biomaterials and corrosion applications. RSC Adv., 2018; 8: 23294–23318. DOI https://doi.org/10.1039/C8RA01890A
Suleman VT, Al-Hamdani AAS, Ahmed SD, Jirjees VY, Khan ME, Adnan Dib. Phosphorus Schiff base ligand and its complexes: Experimental and theoretical investigations. ApplOrganomet Chem. 2020; 34(4): 1-16. https://doi.org/10.1002/aoc.5546