النشاط التحفيزي المعزز للمركبات النانوية Cu2O / ZnO / GO على تحلل الميثيلين الأزرق
محتوى المقالة الرئيسي
الملخص
في هذا البحث، مادة التحفيز الضوئي للمركبات النانوية مركبة من مخلوط الجسميات النانوية Cu2O، والجسميات النانوية ZnO و أكسيد الغرافين (GO) من خلال منهجي الترسيب المتشارك والهيدروحراري. يهدف هذا البحث إلى معرفة التكوينات المثلى من المركبات النانوية Cu2O/ZnO/GO لانحلال الميثيلين الأزرق. ويقام تركيب المركبات النانوية بخطوتين: (1) تركيب المركبات النانوية Cu2O و ZnO بمنهج الترسيب المتشارك وتحضير GO من خلال منهاج هامر المعدل؛ (2) تحضير مخلوط الجسميات النانوية لمركبات النانوية مع GO من خلال المنهج الهيدروحراري لشكل المركبات النانوية Cu2O/ZnO/GO. ويقام عملية امتزاز التحفيز الضوئي على الميثيلين الأزرق بمساعدة الأشعة فوق البنفسجية من مصياح الهالوجين. تدل نتائج الخصائص على أن التكوينات المثلى هي المركبات النانوية Cu2O/ZnO مع نسبة 1:2.و10% من GO وله مساحة محددة 35.874 م2 ج-1، ونصف قطر مسامي 19.073 نانومتر، وحجم المسام 0.092 سم3 ج-1، وحجم البلورة 31.19 نانومتر. كانت كفاءة تحلل الميثيلين الأزرق تحت ضوء الأشعة فوق البنفسجية لمدة 120 دقيقة 82.0٪ ، 86.0٪ ، 91.4٪ ، و 79.3٪ باستخدام المركبات النانوية Cu2O/ZnO مع GO بنسبة 1٪ ، 3٪ ، 5٪ ، و 10٪ على التوالي. وأيضا، هذه النتائج تدل على أن المركبات النانوية Cu2O/ZnO/GO تعطي الكفاية المرضية في انحلال الميثيلين الأزرق من نفايات صبغ النسيج.
Received 10/11/2022
Revised 28/4/2022
Accepted 30/4/2022
Published Online First 20/5/2023
تفاصيل المقالة
هذا العمل مرخص بموجب Creative Commons Attribution 4.0 International License.
كيفية الاقتباس
المراجع
Haseeb M, Haouas I, Nasih M, et al. Asymmetric impact of textile and clothing manufacturing on carbon-dioxide emissions: Evidence from top Asian economies. Energy. 2020; 196: 117094. https://doi.org/10.1016/j.energy.2020.117094
Ismail M, Akhtar K, Khan MI, Kamal Tahseen , Khan A Murad Asiri M Abdullah, et al. Pollution, Toxicity and Carcinogenicity of Organic Dyes and their Catalytic Bio-Remediation. Curr Pharm. 2019; 25: 3645–3663. https://doi.org/10.2174/1381612825666191021142026
Shindhal T, Rakholiya P, Varjani S, Pandey Ashok, Guo Wenshan Hao Ngo Huu, et al. A critical review on advances in the practices and perspectives for the treatment of dye industry wastewater. Bioengineered. 2021; 12: 70–87. https://doi.org/10.1080/21655979.2020.1863034
Nandhini NT, Rajeshkumar S, Mythili S. The possible mechanism of eco-friendly synthesized nanoparticles on hazardous dyes degradation. Biocatal Agric Biotechnol. 2019; 19: 101138. https://doi.org/10.1016/j.bcab.2019.101138
Salgot M, Folch M. Wastewater treatment and water reuse. Curr Opin Environ Sci Health. 2018; 2: 64–74. https://doi.org/10.1016/j.coesh.2018.03.005
Ali SS, Sun J, Koutra E, El-Zawawy Nessma , Elsamahy Tamer El-Shetehy Mohamed. Construction of a novel cold-adapted oleaginous yeast consortium valued for textile azo dye wastewater processing and biorefinery. Fuel. 2021; 285: 119050. https://doi.org/10.1016/j.fuel.2020.119050
Sarayu K, Sandhya S. Current Technologies for Biological Treatment of Textile Wastewater–A Review. Appl Biochem Biotechnol. 2012; 167: 645–661. https://doi.org/10.1007/s12010-012-9716-6
Miklos DB, Remy C, Jekel M, Linden Karl G, Drewes Jörg E, Hübner Uwe, et al. Evaluation of advanced oxidation processes for water and wastewater treatment – A critical review. Water Res. 2018; 139: 118–131. https://doi.org/10.1016/j.watres.2018.03.042
Laghrib F, Bakasse M, Lahrich S, El Mhammedi Moulay Abderrahim . Advanced oxidation processes: photo-electro-Fenton remediation process for wastewater contaminated by organic azo dyes. Int J Environ Anal Chem. 2021; 101: 2947–2962. https://doi.org/10.1080/03067319.2020.1711892
Singla S, Sharma S, Basu S, Shetti P Nagaraj, Aminabhavi Tejraj M. Photocatalytic water splitting hydrogen production via environmental benign carbon based nanomaterials. Int J Hydrogen Energy. 2021; 46: 33696–33717. https://doi.org/10.1016/j.ijhydene.2021.07.187
Li P, Li D, Liu L, Li Anli, Luo Cuixian, Xiao Yue, et al. Concave structure of Cu2O truncated microcubes: PVP assisted {100} facet etching and improved facet-dependent photocatalytic properties. CrystEngComm. 2018; 20: 6580–6588. https://doi.org/10.1039/C8CE01332B
Kerour A, Boudjadar S, Bourzami R, Allouche B. Eco-friendly synthesis of cuprous oxide (Cu2O) nanoparticles and improvement of their solar photocatalytic activities. J Solid State Chem. 2018; 263: 79–83. https://doi.org/10.1016/j.jssc.2018.04.010
Singh J, Juneja S, Soni RK, Bhattacharya Jaydeep . Sunlight mediated enhanced photocatalytic activity of TiO2 nanoparticles functionalized CuO-Cu2O nanorods for removal of methylene blue and oxytetracycline hydrochloride. J Colloid Interface Sci. 2021; 590: 60–71. https://doi.org/10.1016/j.jcis.2021.01.022
Nie J, Li C, Jin Z, Hu Wen-ting, Wang Jia-hao, , Huang Ting, et al. Fabrication of MCC/Cu2O/GO composite foam with high photocatalytic degradation ability toward methylene blue. Carbohydr Polym. 2019; 223: 115101. https://doi.org/10.1016/j.carbpol.2019.115101
Huo Y, Wang Z, Zhang J, Liang Changhao Dai Kai . Ag SPR-promoted 2D porous g-C3N4/Ag2MoO4 composites for enhanced photocatalytic performance towards methylene blue degradation. Appl Surf Sci. 2018; 459: 271–280. https://doi.org/10.1016/j.apsusc.2018.08.005
Wang P, Qi C, Hao L, Wen Pengchao , Xu Xin . Sepiolite/Cu2O/Cu photocatalyst: Preparation and high performance for degradation of organic dye. J Mater Sci Technol. 2019; 35: 285–291. https://doi.org/10.1016/j.jmst.2018.03.023
Zhang D, Yang J, Wang J, Yang Jianfeng, Qiao Guanjun . Construction of Cu2O-reduced graphene oxide composites with enhanced photoelectric and photocatalytic properties. Opt Mater (Amst). 2020; 100: 109612. https://doi.org/10.1016/j.optmat.2019.109612
Muscetta M, Jitan S al, Palmisano G, Andreozzi Roberto, Marotta Raffaele, Cimino Stefano et al. Visible light – driven photocatalytic hydrogen production using Cu2O/TiO2 composites prepared by facile mechanochemical synthesis. J Environ Chem Eng. 2022; 10: 107735. https://doi.org/10.1016/j.jece.2022.107735
Gao S, Zhang H, Wang X, Deng Ruiping, Sun Dehui, Zheng Guoli. ZnO-Based Hollow Microspheres: Biopolymer-Assisted Assemblies from ZnO Nanorods. J Phys Chem B. 2006; 110: 15847–15852. https://doi.org/10.1021/jp062850s
Fatima R, Kim J-O. Inhibiting photocatalytic electron-hole recombination by coupling MIL-125(Ti) with chemically reduced, nitrogen-containing graphene oxide. Appl Surf Sci. 2021; 541: 148503. https://doi.org/10.1016/j.apsusc.2020.148503
Zhang Y-H, Cai X-L, Guo D-Y, Zhang Hui-Jing Zhou Ning, Fang Shao-Ming, et al. Oxygen vacancies in concave cubes Cu2O-reduced graphene oxide heterojunction with enhanced photocatalytic H2 production. J Mater Sci: Mater Electron. 2019; 30: 7182–7193. https://doi.org/10.1007/s10854-019-01036-2
Zou W, Zhang L, Liu L, Wang Xiaobo, Sun Jingfang, Wu Shiguo et al. Engineering the Cu2O–reduced graphene oxide interface to enhance photocatalytic degradation of organic pollutants under visible light. Appl Catal B. 2016; 181: 495–503. https://doi.org/10.1016/j.apcatb.2015.08.017
Ma J, Wang K, Li L, Zhang Tianli, Kong Yong, Komarneni Sridhar, et al. Visible-light photocatalytic decolorization of Orange II on Cu2O/ZnO nanocomposites. Ceram Int. 2015; 41: 2050–2056. https://doi.org/10.1016/j.ceramint.2014.09.137
Huang H, Zhang J, Jiang L, Zang Zhigang . Preparation of cubic Cu2O nanoparticles wrapped by reduced graphene oxide for the efficient removal of rhodamine B. J Alloys Compd 2017; 718: 112–115. https://doi.org/10.1016/j.jallcom.2017.05.132
Purba FJ, Tarigan K, Sitorus Z, Nurdin Iregar, Ema Frida, Nurdin Bukit, et al. Cu2O/ZnO Nanocomposite and Graphene Oxide with Photocatalysis for Textile Dyes/Dye Reduction. Tianjin Daxue Xuebao. 2022; 55: 388–398. https://doi.org/10.17605/OSF.IO/3JD56
Regmi A, Bhandari J, Bhattarai S, Gautam K Surendra. Synthesis, Characterizations and Antimicrobial Activity of Cuprous Oxide (Cu2O) Nanoparticles. J Nepal Chem Soc. 2019; 40: 5–10. https://doi.org/10.3126/jncs.v40i0.27271
Hjiri M, Mir L, Leonardi S. Synthesis, Characterization and Sensing Properties of AZO and IZO Nanomaterials. Chemosensors. 2014; 2: 121–130. https://doi.org/10.3390/chemosensors2020121
Yoo MJ, Park HB. Effect of hydrogen peroxide on properties of graphene oxide in Hummers method. Carbon. 2019; 141: 515–522. https://doi.org/10.1016/j.carbon.2018.10.009
Scherrer P. Bestimmung der Grösse und der inneren Struktur von Kolloidteilchen mittels Röntgenstrahlen. Nachrichten von der Gesellschaft der Wissenschaften zu Göttingen, mathematisch-physikalische Klasse 1918; 98–100.
Zhang W, Xu H, Xie F, Ma Xiaohua, Niu Bo, Mingqi Chen et al. General synthesis of ultrafine metal oxide/reduced graphene oxide nanocomposites for ultrahigh-flux nanofiltration membrane. Nat Commun. 2022; 13: 471. https://doi.org/10.1038/s41467-022-28180-4
Islam MR, Rahman M, Farhad SFU, Podder J. Structural, optical and photocatalysis properties of sol–gel deposited Al-doped ZnO thin films. Surf Interfaces. 2019; 16: 120–126. https://doi.org/10.1016/j.surfin.2019.05.007
Rosas-Laverde NM, Pruna A, Busquets-Mataix D, Marí B, Cembrero J, Vicente F Salas, et al. Improving the properties of Cu2O/ZnO heterojunction for photovoltaic application by graphene oxide. Ceram Int. 2018; 44: 23045–23051. https://doi.org/10.1016/j.ceramint.2018.09.107
Tantubay K, Das P, Baskey Sen M. Ternary reduced graphene oxide–CuO/ZnO nanocomposite as a recyclable catalyst with enhanced reducing capability. J Environ Chem Eng. 2020; 8: 103818. https://doi.org/10.1016/j.jece.2020.103818
Phoohinkong W, Foophow T, Pecharapa W. Synthesis and characterization of copper zinc oxide nanoparticles obtained via metathesis process. Advances in Natural Sciences: Nanoscience and Nanotechnology. 2017; 8: 035003. https://doi.org/10.1088/2043-6254/aa7223
Al-Senani GM, Al-Saeedi SI, Al-Kadhi NS, Abd-Elkader Omar H Deraz Nasrallah M. Green Synthesis and Pinning Behavior of Fe-Doped CuO/Cu2O/Cu4O3 Nanocomposites. Processes. 2022; 10: 729. https://doi.org/10.3390/pr10040729
Ma Z, Hu L, Li X, Deng Lingjuan, Fan Guang He Yangqing. A novel nano-sized MoS2 decorated Bi2O3 heterojunction with enhanced photocatalytic performance for methylene blue and tetracycline degradation. Ceram Int. 2019; 45: 15824–15833. https://doi.org/10.1016/j.ceramint.2019.05.085