تحضير ، تشخيص دراسة التحلل الحراري فعالية مضادات الاكسدة لمعقدات العناصر الانتقالية مع ليكاند صبغة الازو
محتوى المقالة الرئيسي
الملخص
تم إجراء تفاعل ديازوتيزيشن بين 1- (6,4,2-ثلاثي هيدروكسي-فينيل) -إيثانون وأملاح ديازونيوم مما أدى إلى تكوين ليكاند 4- (3-أسيتيل -2،4،6-ثلاثي هيدروكسي-فينيل ازو) -N- (5-ميثيل-إيزوكسازول-3-يل) -بنزين سلفوناميد ، وهذا بدوره يتفاعل مع أيونات المعادن التالية (+V4، +Cr3، +Mn2 و +Cu2) مكونة معقدات مستقرة ثمانية السطوح لكل من الكروم والمنغنيز والنحاس و هرمي مربع القاعدة لـلفناديوم الرباعي .تم اكتشاف إنشاء مثل هذه المعقدات من خلال استخدام الوسائل الطيفية التي تنطوي على الأشعة فوق البنفسجية التي أثبتت الأشكال الهندسية التي تم الحصول عليها ، وأثبت IR تكوين مجموعة الآزو والتنسيق مع أيون المعدن من خلالها. أثبتت دراسات الانحلال الحراري (TGA & DSC) تنسيق بقايا الماء مع أيونات المعادن داخل مجال التناسق وكذلك ذرات الكلور. علاوة على ذلك ، التحليل الجزئي للعنصر و AAS الذي أعطى النتيجة المقابلة مع نتيجة العد النظري. (H &13C-NMR1) والكميات المغناطيسية يمكن أن تشير أيضًا إلى تكوين ليكاند H3L وحدوث التنسيق. تم حساب الثوابت الديناميكية الحرارية (H∆, S∆, G∆). سيتم استخدام طريقة الكسح الجذري DPPH لتقييم الأنشطة المضادة للأكسدة للمركبات التي أظهرت قدرتها المضادة للأكسدة على اخماد الجذور الحرة.
Received 14/01/2023
Revised 31/03/2023
Accepted 02/04/2023
Published Online First 20/10/2023
تفاصيل المقالة
هذا العمل مرخص بموجب Creative Commons Attribution 4.0 International License.
كيفية الاقتباس
المراجع
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