إزالة صبغة الفوكسين القاعدية عن طريق الامتزاز على متراكب نانوي CuCo2O4 كسطح ماص نشط
DOI:
https://doi.org/10.21123/bsj.2023.8782الكلمات المفتاحية:
تلوث المياه ، معالجة المياه ، الامتزاز ، CuCo2O4 ، متراكب نانوي من نوع الإسبنيل ، صبغة الفوكسين القاعديةالملخص
تتضمن هذه الدراسة تصنيع مركب نانوي من نوع CuCo2O4. تم تصنيع هذه المادة باستخدام طريقة الترسيب المشترك. تم تشخيص المواد المحضرة بأستخدام الطيفي للأشعة تحت الحمراء (FTIR) ، حيود الأشعة السينية (XRD) ، المجهر الإلكتروني لمسح الانبعاث الميداني (FESEM) ، والفحص المجهري للقوة الذرية (AFM). تم فحص نشاط المواد المحضرة باتباع إزالة صبغة الفوشسين الأساسية (BF) من محلولها المائي عن طريق الامتزاز. تم دراسة الظروف الفضل للأمتزاز المختلفة مثل وزن السطح الممتز ووقت الامتزاز ودرجة الحموضة الوسط فضلاً عن درجة الحرارة. حيث كانت كفاءة الإزالة المثلى حوالي 97٪ في وقت التلامس 5 دقائق ، 0.005 غم من السطح الممتز مع أفضل درجة حموضة = 8 و تركيز صبغة 50 ملغم.لتر-1. تم حساب المعلمات الديناميكية الحرارية لأمتزاز هذه الصبغة على المواد المحضرة أيضًا مثل الطاقة الحرة (∆G) سالبة بينما المحتوى الحراري (∆H) موجباً مما يشير إلى أن الامتزاز كان تلقائيًا وممتصًا للحرارة ، كما كان الانتروبيا (∆S) موجبًا.
Received 22/03/2023
Revised 22/05/2023
Accepted 24/05/2023
Published Online First 25/12/2023
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