تحضير وتشخيص صبغتين مشتقتين من بارا- أمينو فينول ودراسة فعاليتهما كمثبطات للتآكل: التحليل التجريبي والنظري

المؤلفون

  • اسيل فرحان عبد الله قسم الكيمياء ، كلية العلوم ، جامعة واسط ، الكوت ، العراق.
  • سرى حامد كاظم قسم الكيمياء ، كلية العلوم ، جامعة واسط ، الكوت ، العراق.
  • عذراء كطامي صكر قسم الكيمياء ، كلية العلوم ، جامعة واسط ، الكوت ، العراق. https://orcid.org/0000-0002-7792-5365
  • جواد كاظم عبيس قسم الكيمياء ، كلية العلوم ، جامعة واسط ، الكوت ، العراق.

DOI:

https://doi.org/10.21123/bsj.2024.9948

الكلمات المفتاحية:

آزو، مثبط التآكل، نظرية الكثافة الوظيفية، الكيمياء الكهربائية، شحنات موليكين.

الملخص

تم في هذا البحث تحضير صبغتين من بار-امينو فينول من خلال تفاعل ملح الديزونيوم من بارا-امينو فينول مع مركبين اروماتي (1-نفثول وبارا-امينو فينول). تم تشخيص الصبغتين الجديدتين (a و b ) بتقنية FTIR وHNMR1 مع قياس بعض الخواص الفيزيائية. تم دراسة النشاط التثبيطي تجريبياً بواسطة القياسات الكهروكيميائية لمركبات الآزو المحضرة ضد تآكل الفولاذ الكربوني نوع C45 في وسط (HCl 0.1 M,).  تم استخدام طريقة ميكانيكة الكم  لحساب البنية الهندسية والخواص الفيزيائية بواسطة برنامج Gaussian 09 W ونظرية الكثافة الوظيفية (DFT)  لدالة   B3LYP بمستوى 6-311 +G  (2d, 2p) . تم استخدام نظرية الكثافة الوظيفية  في حساب معاملات  كفاءة التثبيط للصبغتين في  وسط  مفرغ من الهواء,  وأظهرت النتائج ان  المركب a الافضل بالتثبيط.

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كيفية الاقتباس

1.
تحضير وتشخيص صبغتين مشتقتين من بارا- أمينو فينول ودراسة فعاليتهما كمثبطات للتآكل: التحليل التجريبي والنظري. Baghdad Sci.J [انترنت]. [وثق 21 نوفمبر، 2024];22(6). موجود في: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/9948