Nano composites of PAM Reinforced with Al2O3

Main Article Content

Balqees M. Al-dabbag
https://orcid.org/0000-0001-9726-7542
Hanaa Jawad Kadhim
https://orcid.org/0000-0001-7385-4574

Abstract

         The aim of this investigation is to determine how different weight percentages of alumina nanoparticles, including 0.02, 0.04, and 0.06 percent wt, affect the physical characteristics of Poly Acrylamide (PAAM). Using a hot plate magnetic stirrer, 10 g of poly acrylamide powder was dissolved in 90 g of di-ionized distillate water for 4 hours to produce PAAM with a concentration of 0.11 g/ml. Four sections of the resulting solution, each with a volume of 20 ml, were created. Each solution was added independently with alumina nanoparticles in different ratios 0.0, 0.02, 0.04, and 0.06 to create four nano fluid solutions with different alumina nanoparticle contents based on each weight percent. The hand casting process for nanocomposites samples, which entailed pouring the prepared solution into an appropriate plastic mold, allowing it to cure for 24 hours, and then cutting the resulting thin film according to each test, was used to create the nano composited membranes. The tensile test was used to study tensile strength, Young's modulus, elongation, and toughness. Additionally, a test using Fourier transition infrared radiation (FTIR) was conducted to examine the chemical and physical connections between polyacrylamide and alumina nanoparticles. The morphology of the materials was examined using scan electron microscopy. The contact angles of samples were tested to limit the hydrophilicity behavior of these samples. To control the hydrophilicity behavior of these samples, the contact angles of the samples were evaluated. The results showed that including alumina nanoparticles into the PAAM matrix improves the mechanical characteristics of the resulting nanocomposites. Tensile strength increases from 1 GPa to 2.5 GPa with an increase in alumina nanoparticle content from 0 to 0.06 percent wt. For the same prior ratios, Young's modulus likewise increased, rising from 1.3 to 2 GPa. For the higher weight ratio of alumina nanoparticles (0.04 percent wt), toughness rises to 240 J/cm2. On the other hand, the addition of alumina nanoparticles increased the PAAM surface's contact angle from 55 degrees to 67 degrees, and it exhibited hydrophilic behavior

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Nano composites of PAM Reinforced with Al2O3. Baghdad Sci.J [Internet]. 2023 Dec. 1 [cited 2024 Nov. 23];20(6). Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/7353
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How to Cite

1.
Nano composites of PAM Reinforced with Al2O3. Baghdad Sci.J [Internet]. 2023 Dec. 1 [cited 2024 Nov. 23];20(6). Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/7353

References

Hanaa J K, Al-Dabbagh B M, Rana MS, Ahmed S D. Nano composites films for food packaging applications. AIP Conf. Proce. 2021 Nov; 2372 (100002): 1-6.

Aldabbagh B M, Jawad H K, Mahdi R S. Study of the properties of MgO/ Poly methyl methacrylate Nano-composites. J Phys: Conf Ser. 2021 Nov; 2114 (012039): 1-7

Hameed T M, Al-Dabbagh B M, Jasim R K. Mechanical Properties of Heat Cured Acrylic Resin Reinforced with Natural Sisal Fibers Powder. J Phys: Conf Ser. 2021 Apr, 2114 (012023) : 1-10

Al-Zubaydi A S, Salih R M, Al-Dabbagh B M. Effect of nano TiO2 particles on the properties of carbon fiber-epoxy composites. Prog Rubber Plast Recycl Technol, 2021 Aug; 37(3) : 216–232

Al Dabbagh B M, Kadhim H J, Salih R M. Studying the effect of Polyamide 6 Nanofibers on Physical and Chemical Properties of Unsaturated Polyester Reinforced by Glass Fibers Composites. IOP Conf Ser: Mater Sci Eng. 2020 Nov; 757 (012001) : 1-6

Charles C O. Nanocomposites – An Overview. Int. J. Eng. Res. Dev., 2013 Jan; 8 (11) :17-23

Jaafar H T, Aldabbagh B M. Investigation of superhydrophobic/hydrophobic materials properties using electrospinning technique. Baghdad Sci J, 2019 Sep; 16 (3): 632–638

Talal J H, Mohammed D B, Jawad K H. Fabrication of Hydrophobic Nanocomposites Coating Using Electrospinning Technique for Various Substrate. J Phys: Conf. Ser. 2018 Apr; 1032 (012033): 1-13

Alesa H J, Aldabbag B M, Salih R M. Natural pigment -poly vinyl alcohol nano composites thin films for solar cell. Baghdad. Sci J, 2020 Sep; 17(3): 832–840

Jawad K H, Mohammed D B, Alsaffar M R. Performed of Filter Nano Textile for Purification of Aerosol Water by Electrospinning Technique. J Phys: Conf Ser. 2019 Sep; 1298(012023): 1-5

Cammarata R. Introduction to Nano Scale Science and Technology. 1 st Ed. Chap.8. USA. Springer. 2006. P. 199 - 212. https://link.springer.com/content/pdf/bfm:978-1-4020-7757-9/1

Charles C O. The Benefit and Applications of Nanocomposites. Int J Adv Engg Tech. 2014 Aug; 5(6): 12-18

Rehim M H, Alhamidi J. Tio2 /Polymer Nanocomposites for Antibacterial Packaging Applications. J Adv Food Technol. 2018 Jan; 1(1) : 1-8

Ricardo J B, Sara D, Patrizia S, Carlos P N, Tito T. Antibacterial Activity of Nanocomposites of Copper and Cellulose. Bio Med Res Int. 2013 Feb; 2013 (280512): 1-6

Shokry H, Hassan M F, Hafez, E S. Novel Antibacterial Zinc Oxide Polymeric Nanocomposite Membrane as Wound Dress. J Nano Sci Nano technol Asia 2017 Jan; 7 (1): 62-72

Barbooti M M, Al-Dabbagh, B D, Hilal R H. Preparation, characterization and utilization of polyacrylic acid–kaolin composite in the removal of heavy metals from water. Int J Environ Sci Technol , 2019 Feb; 16 (8) : 4571–4582

Murugan R. FTIR and Polarised Raman Spectra of Acrylamide and Polyacrylamide. J Korean Phys Soc. 1998 Jan; 32(4): 505-512.

Olabode O O, William Z X, Paul A C. Adhesive RAFT agents for controlled polymerization of acrylamide effect of catecholend R groups. Rsc Adv. 2015 (5): 76919-76926

Neelam V, Gagandeep K. Colorimetric determination of Cu 2+ ions in water and milk by apo-tyrosinase disc. Sens Act B Chem. 2018 Jan ; 263(7): 524-532

Alfred C. Polymer Nanocomposites: The “Nano” Effect on Mechanical Properties. Poly Rev. 2007 Jan ; 47(2) : 217-229