Catalytic Innovation for Renewable Energy: TiO2-Supported Precipitated Calcium Carbonate Catalyst for Eco-Friendly Biodiesel Synthesis

Authors

  • Vivi Sisca Research Center for Chemistry, National Research and Innovation Agency, B.J. Habibie Science and Techno Park, Serpong, South Tangerang, Banten, 15314, Indonesia
  • Syukri Department of Chemistry, University of Andalas, Limau Manis, Padang, West Sumatra, Indonesia.
  • Zilfa Department of Chemistry, University of Andalas, Limau Manis, Padang, West Sumatra, Indonesia.
  • Novesar Jamarun Department of Chemistry, University of Andalas, Limau Manis, Padang, West Sumatra, Indonesia.
  • Denny Akbar Tanjung Department of Agrotechnology, University of Medan Area, Medan, Indonesia. https://orcid.org/0000-0003-3556-4351
  • Ahmad Hafizullah Ritonga Institut Kesehatan Medistra Lubuk Pakam, Deli Serdang-20512, Indonesia. https://orcid.org/0000-0002-8415-5549
  • Dicky Annas Research Center for Chemistry, National Research and Innovation Agency, B.J. Habibie Science and Techno Park, Serpong, South Tangerang, Banten, 15314, Indonesia.
  • Khoiriah Khoiriah Research Center for Chemistry, National Research and Innovation Agency, B.J. Habibie Science and Techno Park, Serpong, South Tangerang, Banten, 15314, Indonesia. https://orcid.org/0000-0003-1116-6367
  • Poedji Loekitowati Hariani Department of Chemistry, Sriwijaya University, Ogan Ilir 30662, Indonesia.

DOI:

https://doi.org/10.21123/bsj.2024.11692

Keywords:

Biodiesel, Heterogeneous catalyst, Precipitated Calcium Carbonate/TiO2, Transesterification, Waste Vegetable Oil.

Abstract

Biodiesel produced through transesterification reactions with homogeneous and heterogeneous base catalysts is a promising alternative energy source. This study uses Precipitated Calcium Carbonate (PCC) enriched with TiO2 to produce biodiesel from waste vegetable oil. The synthesized catalyst was comprehensively identified through XRD, XRF, SEM, BET, and FT-IR analyses and then applied in the transesterification reaction. The results showed that PCC enriched with TiO2 is an effective catalyst, producing biodiesel with an efficiency of 95.09% under optimal conditions: 5 wt% catalyst, a methanol to oil ratio of 6:1, a reaction temperature of 65°C, and a reaction time of 4 hours. Enhancing catalytic properties, increased surface area, and strengthening of basic sites significantly improved biodiesel yield.

Received 31/05/2024

Revised 08/09/2024

Accepted 10/09/2024

Published Online First 20/10/2024

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Copyright (c) 2024 Vivi Sisca, Syukri, Zilfa, Novesar Jamarun, Denny Akbar Tanjung, Ahmad Hazizullah Ritonga, Dicky Annas, Khoiriah Khoiriah, Poedji Loekitowati Hariani

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Catalytic Innovation for Renewable Energy: TiO2-Supported Precipitated Calcium Carbonate Catalyst for Eco-Friendly Biodiesel Synthesis. Baghdad Sci.J [Internet]. [cited 2024 Dec. 23];22(5). Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/11692
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