الابتكار التحفيزي للطاقة المتجددة: محفز كربونات الكالسيوم المترسب المدعوم بـ TiO2 لتخليق وقود الديزل الحيوي الصديق للبيئة
DOI:
https://doi.org/10.21123/bsj.2024.11692الكلمات المفتاحية:
وقود الديزل الحيوي، محفز غير متجانس، كربونات الكالسيوم المترسبة/ثاني أكسيد التيتانيوم، إعادة الاسترة، زيت نباتي مستهلك.الملخص
إن الوقود الحيوي المنتج من خلال تفاعلات الاسترة مع محفزات قاعدية متجانسة وغير متجانسة هو مصدر طاقة بديل واعد. تستخدم هذه الدراسة كربونات الكالسيوم المترسبة (PCC) المخصبة بثاني أكسيد التيتانيوم لإنتاج الوقود الحيوي من زيت نباتي مستعمل. تم التعرف على المحفز المصنّع بشكل شامل من خلال تحليلات XRD وXRF وSEM وBET وFT-IR ثم تم تطبيقه في تفاعل الاسترة. أظهرت النتائج أن PCC المخصب بثاني أكسيد التيتانيوم هو محفز فعال، ينتج الوقود الحيوي بكفاءة 95.09٪ في ظل الظروف المثلى: محفز 5٪ بالوزن، ونسبة الميثانول إلى الزيت 6: 1، ودرجة حرارة التفاعل 65 درجة مئوية، ووقت التفاعل 4 ساعات. أدى تحسين الخصائص الحفزية، وزيادة مساحة السطح، وتعزيز المواقع الأساسية إلى تحسين إنتاج الوقود الحيوي بشكل كبير.
Received 31/05/2024
Revised 08/09/2024
Accepted 10/09/2024
Published Online First 20/10/2024
المراجع
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