Describing Polymers Synthesized from Reducing Sugars and Ammonia Employing FTIR Spectroscopy

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Ghassan Faisal Mohsin
Wasan J. Al-Kaabi
Azalldeen Kazal Alzubaidi

Abstract

          Melanoidins can be diagnosed using the Fourier transform infrared (FTIR) technique. UV/Vis is an effective tool for both qualitative and quantitative analysis of chemical components in melanoidin polymers. The structural and vibrational features of melanoidin synthesized from D-glucose and D-fructose are identical, according to FTIR spectra, with the only difference being the intensity of bands.  Using FTIR spectra, the skeleton of melanoidin is divided into seven major regions. The existence of the C=C, C=N, and C=O groups in all melanoidins formed from fructose and glucose with ammonia is confirmed by the areas ranging from 1600 to 1690 cm-1, and the band is largely evident as a broad shoulder. Both melanoidins have a carboxyl or carbonyl extending around 1700 cm-1. In all melanoidins, the NH+ group has vanished in the 3080 cm-1 range. However, the color intensity depends on the type of sugar employed in melanoidin synthesis. Furthermore, in comparison to Glc-ammonia, which has a higher proportion of sp3 hybridized carbon, Fru-ammonia has a higher proportion of sp2 hybridized carbon based on UV/Vis, FTIR and second-derivative spectra. Moreover, the data were simulated using principal component analysis. Principal component analysis (PCA) was used to interpret the data.

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Mohsin GF, Al-Kaabi WJ, Alzubaidi AK. Describing Polymers Synthesized from Reducing Sugars and Ammonia Employing FTIR Spectroscopy. Baghdad Sci.J [Internet]. [cited 2022Jun.26];:1297. Available from: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/6527
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References

. Mohsin GF, Schmitt FJ, Kanzler C, Dirk Epping J, Flemig S, Hornemann A. Structural characterization of melanoidin formed from D-glucose and L-alanine at different temperatures applying FTIR, NMR, EPR, and MALDI-ToF-MS. Food Chem. 2017 Dec. 8; 245:761-767. doi:10.1016/j.foodchem.2017.11.115

Chandra R, Kumar V, Tripathi S. Evaluation of molasses-melanoidin decolourisation by potential bacterial consortium discharged in distillery effluent. 3 Biotech. 2018 Mar. 16; 8(4):187. doi:10.1007/s13205-018-1205-3

Chandra R, Bharagava RN, Rai V. Melanoidins as major colourant in sugarcane molasses based distillery effluent and its degradation. Bioresour Technol. 2007 Nov.7; 99(11): 4648-4660. doi:10.1016/j.biortech.2007.09.057

Mohsin GF, Schmitt FJ, Kanzler C, Hoehl A, Hornemann A. PCA-based identification and d ifferentiation of FTIR data from model melanoidins with specific molecular compositions. Food Chem. 2018 Dec. 19; 281:106-113. doi:10.1016/j.foodchem.2018.12.054

Mohsin GF, Schmitt FJ, Kanzler C, Epping JD, Buhrke D, Hornemann A. Melanoidin formed from fructosylalanine contains more alanine than melanoidin formed from d-glucose with L-alanine. Food Chem. 2019 Sep. 6; 305:125459. doi:10.1016/j.foodchem.2019.125459

Echavarría AP, Pagán J, Ibarz A. Kinetics of color development of melanoidins formed from fructose/amino acid model systems. Food Sci Technol Int. 2013 Jun. 6; 20(2):119-126. doi:10.1177/1082013213476071

Rodríguez A, Lema P, Bessio MI, Moyna G, Panizzolo LA, Ferreira F. Isolation and Characterization of Melanoidins from Dulce de Leche, A Confectionary Dairy Product. Molecules. 2019 Nov. 17; 24(22): 4163. doi:10.3390/molecules24224163

Ramírez-Hernández A, Aguilar-Flores C, Aparicio-Saguilán A. Fingerprint analysis of FTIR spectra of polymers containing vinyl acetate. DYNA. 2019 Apr.-June; 86 (209): 198-205. doi: 10.15446/dyna.v86n209.77513

El-Kholy WM, Soliman TN, Darwish AMG. Evaluation of date palm pollen (Phoenix dactylifera L.) encapsulation, impact on the nutritional and functional properties of fortified yoghurt. PLoS One. 2019 Oct. 15; 14(10):e0222789. doi:10.1371/journal.pone.0222789

Kim J-S, Lee Y-S. FT-IR and X-Ray Diffraction Characterization of Melanoidins Formed from Glucose and Fructose with Amino Acid Enantiomers in the Maillard Reaction. Food Sci. Biotechnol. 2009 Apr. 30; 18(2): 546–551.

Guillén-Casla V, Rosales-Conrado N, León-González ME, Pérez-Arribas LV, Polo-Díez LM. Principal component analysis (PCA) and multiple linear regression (MLR) statistical tools to evaluate the effect of E-beam irradiation on ready-to-eat food. J. Food Compos. Anal. 2011 May. 01; 24(3): 456-464. doi:10.1016/j.jfca.2010.11.010

Formosa JP, Lia F, Mifsud D, Farrugia C. Application of ATR-FT-MIR for Tracing the Geographical Origin of Honey Produced in the Maltese Islands. Foods. 2020 Jun. 01; 9(6):710. doi:10.3390/foods9060710

Sahlan M, Karwita S, Gozan M, Hermansyah H, Yohda M, Yoo YJ, et al. Identification and classification of honey's authenticity by attenuated total reflectance Fourier-transform infrared spectroscopy and chemometric method. Vet World. 2019 Aug. 23; 12(8):1304-1310. doi:10.14202/vetworld.2019.1304-1310

Horvatinec J, Svečnjak L. Infrared (FTIR) spectral features of honey bee (Apis mellifera L.) hemolymph. J. Cent. Eur. Agric. 2021 Sep. 12; 21(1): 37-41. doi: 10.5513/JCEA01/21.1.2741

Genkawa T, Ahamed T, Noguchi R, Takigawa T, Ozaki Y. Simple and rapid determination of free fatty acids in brown rice by FTIR spectroscopy in conjunction with a second-derivative treatment. Food Chem. 2015 Feb. 10; 191:7-11. doi:10.1016/j.foodchem.2015.02.014

Yousif E, Asaad N, Ahmed DS, Mohammed SA, Jawad AH. A Spectral, Optical, Microscopic Study, Synthesis and Characterization of PVC Films Containing Schiff Base Complexes. Baghdad Sci J. 2021Sep.12, 16(1): 0056. DOI: http://dx.doi.org/10.21123/bsj.2019.16.1.0056

Taha AA, Hameed NJ, Rashid FH. Decolorization of Phenol Red Dye by Immobilized Laccase in Chitosan Beads Using Laccase - Mediator - System Model. Baghdad Sci J. 2021Sep.12; 17(3):0720. DOI: http://dx.doi.org/10.21123/bsj.2020.17.3.0720

Alwash A. The Green Synthesize of Zinc Oxide Catalyst Using Pomegranate Peels Extract for the Photocatalytic Degradation of Methylene Blue Dye. Baghdad Sci J. 2021Sep.12; 17(3):787-794. DOI: http://dx.doi.org/10.21123/bsj.2020.17.3.0787

Alesa HJ, Aldabbag BM, Salih RM. Natural Pigment –Poly Vinyl Alcohol Nano composites Thin Films for Solar Cell. Baghdad Sci J. 2021Sep.12; 17(3):832-840. DOI: http://dx.doi.org/10.21123/bsj.2020.17.3.0832

Cozzolino, D., Power, A., and Chapman, J. Interpreting and Reporting Principal Component Analysis in Food Science Analysis and Beyond. Food Anal. Methods. 2019 Jul. 24; 12: 2469–2473. https://doi.org/10.1007/s12161-019-01605-5