تحضير ودراسة الخصائص الهيكلية، الشكلية والبصرية لجسيمات نانوية من اوكسيد القصديرالنقي ومخدرCu
محتوى المقالة الرئيسي
الملخص
في هذه الدراسة، تم تصنيع جزيئاتSnO2 النانويه النقيه والمشوبة بالنحاس بواسطة طريقه الترسيب الكيميائي . تم استخدام SnCl2.2H2O , CuCl2.2H2O كمواد خام . تم تلدين المواد عند°C 550 لمدة 3ساعات من اجل تحسين التبلور. اظهرت نتائج حيود الاشعه السينية ان العينات تبلورت في طورمن نوع رباعي الروتيل , SnO2 نظرا ان متوسط الحجم البلوري لSnO2 النقي 9 نانومتر ويختلف مع تغير منشطات النحاس (0.5%, 1%, 1.5%, 2%, 2.5%, 3%) , ، ( 8.35 ,8.36 ,8.67 , 9,7 ,8.86) نانومتر على التوالي والتركيب البلوريSnO2 لا يتغير مع ادخال النحاس , أكدت نتائج SEM للنقاوة والمخدر أن حجم الجسيمات يقع في نطاق (25-56) نانومتر داخل الحجم النانوي .كانت دراسات UV-ViS حيث كشف التحليل الطيفي للانعكاس ان طاقه فجوة النطاق تزداد مع زيادة نسب المنشطات (4.18,4.33 ,4.21 , 4.21 4.35,4.23 ) الكترون فولت للنقي والمشوب بالنحاس ( (0.5%, 1%, 1.5%, 2%, 2.5%, 3%) على توالي . واظهرت نتائج AFM معدل الخشونة، SPMوحجم الحبوب للعينات النقيه والمشوبة وان معدل الخشونة نانومتر و (3.04, 25,27,16,41.8,23.6,25.2) ومعدل القطر (98.9, 72.56,92.91, 88.38, 76.79, 70.94, 71.21) نانومتر للنقي والمشوب على التوالي.
تفاصيل المقالة
![Creative Commons License](http://i.creativecommons.org/l/by/4.0/88x31.png)
هذا العمل مرخص بموجب Creative Commons Attribution 4.0 International License.
كيفية الاقتباس
المراجع
Hornyak GL, Moore JJ, Tibbals HF, Dutta J. Fundamentals of nanotechnology. 1St ed. Boca Raton: Taylor&Francis Group ; 2009. Ch.1, P .786-4.
Poole Jr CP, Owens FJ. Introduction to nanotechnology.1St ed.Hoboken,New Jersey,in Canada : John Wiley & Sons,Inc;2003. Ch.1, P.388-4.
Pascariu P, Airinei A, Grigoras M, Fifere N, Sacarescu L, Lupu N, et al. Structural, optical and magnetic properties of Ni doped SnO2 nanoparticles. J. Alloys Compd. 2016; 668:65–72.
Dey A. Semiconductor metal oxide gas sensors: A review. Mat Sci Eng B-Adv. 2018; 229:206– 17.
Mubeenabanu A, Veemaraj T. Effect of Ag Doping on Structural and Optical Properties of ZnO Nanoparticles. Adv Appl Sci Res. 2017;1(9).
Gautam S, Agrawal H, Thakur M, Akbari A, Sharda H, Kaur R, et al. Metal oxides and metal organic frameworks for the photocatalytic degradation: A review. J. Environ. Chem. Eng.. 2020;8(3):103726.
Danish MSS, Estrella LL, Alemaida IMA, Lisin A, Moiseev N, Ahmadi M, et al. Photocatalytic Applications of Metal Oxides for Sustainable Environmental Remediation. Metals 2021, 11, 80. MDPI; 2021.
Umar A, Ammar HY, Kumar R, Almas T, Ibrahim AA, AlAssiri MS, et al. Efficient H2 gas sensor based on 2D SnO2 disks: experimental and theoretical studies. Int. J Hydrog Energ. 2020;45(50):26388–401.
Pascariu P, Airinei A, Olaru N, Petrila I, Nica V, Sacarescu L, et al. Microstructure, electrical and humidity sensor properties of electrospun NiO–SnO2 nanofibers. Sens. Actuators B Chem. 2016; 222:1024–31.
Sharma N, Jha R, Jindal N. Hydrothermally Synthesized Stannic Oxide Nano-hexagons. Mater Today Proc. 2018;5(5):13807–15.
Periyasamy M, Kar A. Modulating the properties of SnO2 nanocrystals: morphological effects on structural, photoluminescence, photocatalytic, electrochemical and gas sensing properties. J. Mater Chem C. 2020;8(14):4604–35.
Mehra S, Bishnoi S, Jaiswal A, Jagadeeswararao M, Srivastava AK, Sharma SN, et al. A review on spectral converting nanomaterials as a photoanode layer in dye‐sensitized solar cells with implementation in energy storage devices. Energy Storage Mater. 2020;2(2):e120.
Xu R, Zhang L-X, Li M-W, Yin Y-Y, Yin J, Zhu M-Y, et al. Ultrathin SnO2 nanosheets with dominant high-energy {001} facets for low temperature formaldehyde gas sensor. Sens. Actuators B Chem. 2019; 289:186–94.
Kadhim IH, Hassan HA, Ibrahim FT. Hydrogen gas sensing based on nanocrystalline SnO2 thin films operating at low temperatures. Int J Hydrogen Energ. 2020;45(46):25599–607.
Kadhim IH, Hassan HA. Hydrogen gas sensing based on SnO 2 nanostructure prepared by sol–gel spin coating method. J Electron Mater. 2017;46(3):1419–26.
Chithra MJ, Sathya M, Pushpanathan K. Effect of pH on crystal size and photoluminescence property of ZnO nanoparticles prepared by chemical precipitation method. Acta Metal Sin Eng llett. 2015;28(3):394–404. 2015;28(3):394–404.
Amendola V, Amans ID, Ishikawa Y, Koshizaki N, Scirè S, Compagnini G, et al. Room‐Temperature Laser Synthesis in Liquid of Oxide, Metal‐Oxide Core‐Shells, and Doped Oxide Nanoparticles. Chemistry. 2020;26(42):9206.
Khan D, Rehman A, Rafiq MZ, Khan AM, Ali M. Improving the Optical properties of SnO2 nanoparticles through Ni doping by sol-gel Technique. CRGSC. 2021;100079.
Nada A, Khalid R, Zainb J. New Method of Preparation ZnS Nano size at low pH. Int. J. Electrochem. Sci., 2013;(8): 3049 - 3056
Vojvodić K, Nikolić-Bujanović L, Mrazovac-Kurilić S, Staletović N. Application of ecofrendly oxidant ferrate (vi) in the metallurgical processes of copper extraction. J. Min. Metall., Sect. B Metall. 2018;(3–4):97–108.
Nada A, Mohammed T, Lamia A,” Fabricated of Cu Doped ZnO Nanoparticles for Solar Cell Application” Baghdad Sci. J. 2018;15(2).
Mohammed A, Bachtiar D, Siregar JP, Rejab MRM. Effect of sodium hydroxide on the tensile properties of sugar palm fibre reinforced thermoplastic polyurethane composites. J Mech Eng. Sci. 2016;10(1):1765–77.
Muliyadi L, Doyan A, Susilawati S, Hakim S. Synthesis of SnO2 Thin Layer with a Doping Fluorine by Sol-Gel Spin Coating Method. J JPPIPA. 2019;5(2):175–8.
Sagadevan S, Johan M, Bin R, Aziz FA, Hsu H-L, Selvin R, et al. Influence of Mn Doping on the Properties of Tin Oxide Nanoparticles Prepared by Co-Precipitation Method. J Nanoelectron. Optoelectron. 2019;14(4):583–92.
Yakout SM. Robust ferromagnetic and fast sunlight photocatalytic properties of nanocrystalline SnO2: Co/Cu codoping. Ceram. Int. 2021;47(7):10104–12.
Ehsani M, Hamidon MN, Toudeshki A, Abadi MHS, Rezaeian S. CO2 gas sensing properties of screen-printed La 2 O 3/SnO2 thick film. IEEE Sens J. 2016;16(18):6839–45.
Mason RP, Tulenko TN, Jacob RF. Direct evidence for cholesterol crystalline domains in biological membranes: role in human pathobiology. Biochim Biophys Acta, Biomembr. 2003;1610(2):198–207.
Sarmah S, Kumar A. Electrical and optical studies in polyaniline nanofibre–SnO2 nanocomposites. Bull Mater Sci. 2013;36(1):31–6.
Gosens I, Post JA, de la Fonteyne LJJ, Jansen EHJM, Geus JW, Cassee FR, et al. Impact of agglomeration state of nano-and submicron sized gold particles on pulmonary inflammation. Part Fibre Toxicol. 2010;7(1):1–11.
Dahman Y. Nanotechnology and functional materials for engineers. 1St ed . Elsevier; 2017. Ch.1, An Introduction to Nanotechnology; P .282-14.
Iwashita N. X-ray powder diffraction. In: Materials science and engineering of carbon.1St ed. Elsevier; 2016.; p. 7–25.
Andrade AB, Ferreira NS, Valerio MEG. Particle size effects on structural and optical properties of BaF 2 nanoparticles. RSC Adv. 2017;7(43):26839–48.
Shamaila S, Bano T, Sajjad AKL. Efficient visible light magnetic modified iron oxide photocatalysts. Ceram Int. 2017;43(17):14672–7.
Saikia K, Deb P, Kalita E. Sensitive fluorescence response of ZnSe (S) quantum dots: an efficient fluorescence probe. Phys Scr. 2013;87(6):65802.
Sharma RK, Agrawal M, Marshall F. Heavy metal contamination in vegetables grown in wastewater irrigated areas of Varanasi, India. Bull Environ Contam Toxicol. 2006;77(2):312–8.
Vayssieres L, Sathe C, Butorin SM, Shuh DK, Nordgren J, Guo J. One‐dimensional quantum‐confinement effect in α‐Fe2O3 ultrafine nanorod arrays. Adv. Mater. 2005;17(19):2320–3.
Ziabari AA, Ghodsi FE. Influence of Cu doping and post-heat treatment on the microstructure, optical properties and photoluminescence features of sol–gel derived nanostructured CdS thin films. J Lumin. 2013; 141:121–9.
Brindley GW. XLV. The effect of grain or particle Size on X-ray reflections from mixed powders and alloys, considered in relation to the quantitative determination of crystalline substances by X-ray methods. Mater Sic. 1945;36(256):347–69.