دراسة مقارنة للتثبيت الضوئي للبولي فينيل كلوريد باوكسيد النيكل النانوي والميكروي

المؤلفون

  • B. E. Jasim قسم الصناعات الكيمياوية،معهد التكنولوجيا/ بغداد، الجامعة التقنية الوسطى، بغداد، العراق. https://orcid.org/0000-0001-7114-2418
  • Ahmed A. Ahmed وحدة ابحاث البوليمر، الجامعة المستنصرية، بغداد، العراق.
  • N. A.A. Aboud قسم الصناعات الكيمياوية،معهد التكنولوجيا/ بغداد، الجامعة التقنية الوسطى، بغداد، العراق. https://orcid.org/0000-0003-4469-6524

DOI:

https://doi.org/10.21123/bsj.2023.7516

الكلمات المفتاحية:

Photocatalysis, nano nickel oxide , PVC photodegradation, Polymer–NiO.

الملخص

        تم  تصنيع الجسيمات النانوية NiO بالطريقة الكيميائية وشخصت باستعمال  بـ XRD  واتضح ان المادة النانوية بحجم بلوري (11.72 نانومتر) وحجم حبيبي (13 نانومتر) من  خلال صورة FESEM وايضااستخدم NiO micro ،استعمل كلا الاوكسيدين لتقييم إمكانية البوليمرات على  التحلل الضوئي ، تم فحص التطبيق العملي للتحلل التحفيزي للطور الصلب للبولي فينيل كلوريد (أفلام مركب PVC- NiO).  حيث يؤثر PVC سلبًا على البيئة لأن البوليمر الخاص به يتحلل ببطء ولكن له استخدام صناعي واسع والكمية المستهلكة لا تظهر أي علامات على التباطؤ في الاستخدام ، وبالتالي ، تمت دراسة توليف PVC- NiO micro and nano المعدل مع 0 ، 50 ، 100 و 150 و 200 و 250 و 300 (ساعة) كوقت تشعيع وعدد من التحليلات الطيفية. المتضمنه FTIR ,UV-VIS وتم فحص تأثيرات إضافة الاوكسيد النانويي والمايكروي إلى سلاسل PVC على اختبار الثبات البصري من خلال المؤشرات (ICO و IPO و IOH) وقياسات فقدان الوزن والأشعة فوق البنفسجية واللزوجة ، وكلها أظهرت أن مادة PVC المطورة تؤدي إلى ثبات البوليمرلفترة طويلة.

 

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التنزيلات

منشور

2023-10-28

كيفية الاقتباس

1.
دراسة مقارنة للتثبيت الضوئي للبولي فينيل كلوريد باوكسيد النيكل النانوي والميكروي. Baghdad Sci.J [انترنت]. 28 أكتوبر، 2023 [وثق 12 مايو، 2024];20(5(Suppl.). موجود في: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/7516

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