تشييد بعض الهيدرازايد-هيدرازون والمركبات الحلقية غير المتجانسة الجديدة مشتقات الثايوفين ، ايمين ، كومارين و البيرازول
DOI:
https://doi.org/10.21123/bsj.2024.9395الكلمات المفتاحية:
كومارين ، مركبات حلقية غير متجانسة ، هيدرازيد –هيدرازون ، ايمين ، بيرازول ، ثايوفين.الملخص
تم تشييد سلسلة من المشتقات الجديدة الثايوفين ، الايمين ، الكومارين و البيرازول X4-X16 باستخدام N – (1- (4- (بنزيل سلفونيل) فينيل) ايثيليدين)-2- سيانو اسيتو هيدرازيد X3 بوصفه مادة اساسية أولية عن طريق مفاعلتها مع كواشف مختلفة مثل (التترالون ، سايكلو بنتانون ، سايكلو هبتانون ، 2-هيدروكسي بنزالديهايد ، 2-هيدروكسي-1- نفثالديهايد ، كبريتيد ثنائي كاربون و فنيل ايزوثايو سيانيد). تم تحضير المركب X3 من تصعيد 4-(بنزايل سلفونيل) اسيتوفينون مع 2- سيانو اسيتوهيدرازايد في الايثانول. تم تشخيص تراكيب المركبات المحضرة الجديدة من خلال القياسات الفيزيائية و الطيفية (الأشعة تحت الحمراء والتحليل الطيفي البروتون والكاربون 13 النووي المغناطيسي).
Received 11/09/2023
Revised 22/12/2023
Accepted 24/12/2023
Published Online First 20/08/2024
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الحقوق الفكرية (c) 2024 Istabrick M. Al-Mola, Ammar H. Al-Sabawi
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