تحضير وتشخيص ودراسة تحلل حراري لمعقدات بعض ايونات المعادن وتقييم فعاليتها كمضادات اكسدة

المؤلفون

  • رشا خضر حسين الدفاعي قسم الكيمياء, كلية العلوم, جامعة بغداد, بغداد, العراق https://orcid.org/0000-0002-7708-3436
  • عباس علي صالح الحمداني قسم الكيمياء, كلية العلوم للبنات, جامعة بغداد, بغداد, العراق .
  • عمران عبد الجبار عمران اللهيبي وزارة التربية, مديرية تربية بغداد الرصافة الاولى.

DOI:

https://doi.org/10.21123/bsj.2024.9644

الكلمات المفتاحية:

مضادات اكسدة ،معقدات الازو ،4-امينو مثيل-سايكلوهكسان كاربوكسيلك، اطياف الكتلة ، التحاليل الحرارية

الملخص

وفقأ للدراسات السابقة تم تحضير ليكاند آزو جديد (ن-(3-اسيتايل-2-هيدروكسي-5-مثيل-فنيل)ن-(4-كاربوكسي-سايكلوهكسيل مثيل)-ملح الدايازونيوم) وبعد التحقق من الصيغة المقترحة وفق نتائج التحاليل وبعد استخدام الليكاند لتحضير سلسلة ن المعقدات باستخدام نسب مولية متساوية (1:1) من الليكاند وتفاعلها مع كل من املاح المنغنيز والكوبلت والنيكل والنحاس والخارصين وبعد التحقق وفق تقنيات التحاليل الطيفية والتشخيصية(الاشعة فوق البنفسية والاشعة تحت الحمراء)  التي اعطت اشكال رباعية السطوح لكل المعقدات بصيغة متعادلة والليكاند ثلاثي السن من نوع (نيتروجين- اوكسجين- اوكسجين) ثم دراسة التحلل الحراري لبعض المركبات المحضرة بتقنية التحليل الوزني الحراري و المسعر التفاضلي مطيافية الكتلة . استخدم الصبغة المعقدات المحضرة منها لتحدد قابليتها على كبح الجذور الحرة من خلال قياس قابليتها كمضادات اكسدة باستخدام مادة  DPPHكجذر حر وحامض الاسكوربك كمادة قياسية وتحديد قيمة  IC50 حيث وجد ان الليكاند يمتلك قابلية عالية على كبح الجذور الحرة والمعقدات تفاوتت قابليتها على الكبح حسب قيمة  IC50وكانت النتائج كما يلي

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كيفية الاقتباس

1.
تحضير وتشخيص ودراسة تحلل حراري لمعقدات بعض ايونات المعادن وتقييم فعاليتها كمضادات اكسدة. Baghdad Sci.J [انترنت]. [وثق 7 نوفمبر، 2024];22(5). موجود في: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/9644