Adsorption and Photocatalytic of Biosynthesis Zinc Ferrite Nanoparticles for Removing Acid Black 210 Dye from Aqueous Medium
DOI:
https://doi.org/10.21123/bsj.2024.9359Keywords:
Adsorption process, Green method, Kinetic and thermodynamic studies, Photocatalyst, Zinc ferrite nanoparticlesAbstract
This study treated Acid black 210 dye contaminated textile wastewater by adsorption and photocatalytic techniques using zinc ferrite nanoparticles. Zinc ferrite nanoparticles were formed by the green synthesis technique using eucalyptus leaves as reducing and capping agents. SEM, EDAX, XRD, BET, Zeta potential, and FTIR techniques identified the resulting zinc ferrite nanoparticles. The images from the SEM indicated the crystallinity and spherical shape of the zinc ferrite nanoparticles with a particle size of 32 nm. In addition, this study involved using a photoreactor to accomplish the photo-degradation process. Effect of the main factors on the adsorption and photocatalytic degradation of dye was examined. Based on adsorption results, the removal efficacy of dye after 180 min was 74 % at optimum conditions of 5 mg/L, 0.75 g/L, 5, and 45 °C for AB210 concentration, Zinc ferrite nanoparticles dosage, pH, and temperature, respectively. In contrast, the photodegradation results show that five mg/L of dye was entirely removed within 30 min at optimal pH of 7, UV-intensity 24 W/m2, and a temperature of 45 ℃. The adsorption isotherms were studied using Freundlich, Langmuir, Temkin, and Dubinin models.
Received 10/09/2023
Revised 07/01/2024
Accepted 09/01/2024
Published Online First 20/09/2024
References
Noormohamad HR, Mohammed AH, Ahmad M Bin. Kinetic Study of Polymerization Isopropylacrylamide in Aqueous Solution. Baghdad Sci J. 2023; 20(5): 1926-1932. https://doi.org/10.21123/bsj.2023.7523
Ali N, Zada A, Zahid M, Ismail A, Rafiq M, Riaz A, et al. Enhanced photodegradation of methylene blue with alkaline and transition-metal ferrite nanophotocatalysts under direct sun light irradiation. J Chin Chem Soc. 2018; 66(4) :1-7.https://doi.org/10.1002/jccs.201800213
Al-Qahtani KM, Cadmium removal from aqueous solution by green synthesis zero valent silver nanoparticles with Benjamina leaves extract, Egypt J Aquat Res. 2017; 43(6): 269–274. https://doi.org/10.1016/j.ejar.2017.10.003
Luaibi I M, Atiya MA, Hassan AK, Mahmoud ZA. Heterogeneous catalytic degradation of dye by Fenton-like oxidation over a continuous system based on Box–Behnken design and traditional batch experiments. Karbala Int J Mod Sci. 2022; 8(2): 9–28.https://doi.org/10.33640/2405-609x.3217
AlShaheeb ZA, Thabit ZA, Oraibi AG. Effect of Green-biosynthesis Aluminum Nanoparticles (Al NPs) on Salmonella enterica Isolated from Baghdad City. Baghdad Sci J. 2023; 20(5): 1840-1857. https://doi.org/10.21123/bsj.2023.7526
Vasantharaj S, Sathiyavimal S, Senthilkumar P, Kalpana VN, Rajalakshmi G, Alsehli M, et al. Enhanced photocatalytic degradation of water pollutants using bio-green synthesis of zinc oxide nanoparticles (ZnO NPs). J Environ Chem Eng. 2021; 9(4): 105772. https://doi.org/10.1016/j.jece.2021.105772
Abdi J, Vossoughi M, Mahmoodi NM, Alemzadeh I. Synthesis of metal-organic framework hybrid nanocomposites based on GO and CNT with high adsorption capacity for dye removal. Chem Eng J. 2017; 326(6): 1145-1158.https://doi.org/10.1016/j.cej.2017.06.054
Liu Y, Zhang Q, Xu M, Yuan H, Chen Y, Zhanog J, et al. Novel and efficient synthesis of Ag-ZnO nanoparticles for the sunlight-induced photocatalytic degradation. Appl Surf Sci. 2019; 476(9): 632-640. https://doi.org/10.1016/j.apsusc.2019.01.137
Yadav N, Kola AK, Naz I, Saroj D. A review on advanced physico-chemical and biological textile dye wastewater treatment techniques. Rev Environ Sci Bio Technol. 2020; 19: 543–560.https://doi.org/10.1007/s11157-020-09543-z
Alkasir M, Samadi N, Sabouri Z, Mardani Z, Khatami M, Darroudi M. Evaluation cytotoxicity effects of biosynthesized zinc oxide nanoparticles using aqueous Linum Usitatissimum extract and investigation of their photocatalytic activityackn. Inorg Chem Commun. 2020; 119: 108066. https://doi.org/10.1016/j.inoche.2020.108066
Dheeb BI, Al-Dujayli S, Ibrahim IM, Abbas QA, Ali AH, Ramizy A, et al. Study the Antifungal Activity of ZnS:Mn Nanoparticles Against Some Isolated Pathogenic Fungi. J Phys Conf Ser. 2019; 7(1): 1178. https://doi.org/10.1088/1742-6596/1178/1/012008
Barzinjy AA, Azeez HH. Green synthesis and characterization of zinc oxide nanoparticles using Eucalyptus globulus Labill . leaf extract and zinc nitrate hexahydrate salt. SN Appl Sci. 2020; 2(5): 1-14. https://doi.org/10.1007/s42452-020-2813-1
Patel H. Fixed ‑ bed column adsorption study : a comprehensive review. Appl Water Sci. 2020; 9(45): 349. https://doi.org/10.1007/s13201-019-0927-7
Nakate UT, Patil P, Nakate YT, Na S In, Yu YT, Hahn Y bong. Ultrathin ternary metal oxide Bi2MoO6 nanosheets for high performance asymmetric supercapacitor and gas sensor applications. Appl Surf Sci. 2021; 551(1): 149422. https://doi.org/10.1016/j.apsusc.2021.149422
Raizada P, Sudhaik A, Patial S, Hasija V, Khan AP, Singh P, et al. Engineering nanostructures of CuO-based photocatalysts for water treatment : Current progress and future challenges. Arab J Chem. 2020; 13(11): 8424-8457.https://doi.org/10.1016/j.arabjc.2020.06.031
Altıntıg E, Yenigun M, Sarı A, Altundag H, Tuzen M, Saleh TA. Facile synthesis of zinc oxide nanoparticles loaded activated carbon as an eco-friendly adsorbent for ultra-removal of malachite green from water. Environ Technol Innov. 2021; 21: 101305. https://doi.org/10.1016/j.eti.2020.101305
Atiya MA, Hassan AK, Luaibi IM. Green Synthesis Of Bimetallic Iron/Copper Nanoparticles Using Ficus Leaves Extract For Removing Orange G(OG) Dye From Aqueous Medium. Nat Env Poll Tech. 2022; 21(1): 355-365. https://doi.org/10.46488/NEPT.2022.v21i01.043
Atiya MA, Ridha MJ, Saheb MA. Removal of Aniline Blue from Textile Wastewater using Electrocoagulation with the Application of the Response Surface Approach. J Eng Sci Technol. 2020; 61(11): 2797-2811.https://doi.org/10.24996/ijs.2020.61.11.4
Ali J, Ali N, Wang L, Waseem H, Pan G. Revisiting the mechanistic pathways for bacterial mediated synthesis of noble metal nanoparticles. J Microbiol Methods. 2019; 159(2): 18-25.https://doi.org/10.1016/j.mimet.2019.02.010
Mahmoud ZA, Atyia MA, Hassan AK. The Influence of Support Materials on The Photo-Fenton-like Degradation of Azo Dye Using Continuous Nanoparticles Fixed-bed Column. Al-Khwarizmi Eng. 2022; 18(4): 14-31. https://doi.org/10.22153/kej.2022.09.002
Yaseen S, Yassen A, Ismail O, Yassin A. Sustainable fabrication, optical properties and rapid performance of bio-engineered copper nanoparticles in removal of toxic methylene blue dye in an aqueous medium. Curr Res Green Sustain Chemi. 2021; 4: 100103. https://doi.org/10.1016/j.crgsc.2021.100103
Kamli MR, Malik MA, Srivastava V, Sabir JSM, Mattar EH, Ahmad A. Biogenic zno nanoparticles synthesized from origanum vulgare abrogates quorum sensing and biofilm formation in opportunistic pathogen chromobacterium violaceum. Pharmaceutics. 2021; 13(11): 1743. https://doi.org/10.3390/pharmaceutics13111743
Ajormal F, Moradnia F, Taghavi S, Ramazani A. Zinc Ferrite Nanoparticles in Photo-Degradation of Dye : Mini-Review. J Chem Rev. 2020; 2(2): 90-102. https://doi.org/10.33945/SAMI/JCR.2020.2.2
Din MI, Jabbar S, Najeeb J, Khalid R, Ghaffar T, Arshad M K, et al. Green synthesis of zinc ferrite nanoparticles for photocatalysis of methylene blue. Int J Phytoremediation. 2020: 6(10): 1-8. https://doi.org/10.1080/15226514.2020.1781783
Makofane A, Motaung DE, Hintsho-mbita NC. Photocatalytic degradation of methylene blue and sulfisoxazole from water using biosynthesized zinc ferrite nanoparticles. Ceram Int. 2021; 2(4): 0272-8842. https://doi.org/10.1016/j.ceramint.2021.04.274
Madhukara Naik M, Bhojya Naik HS, Nagaraju G, Vinuth M, Raja Naika H, Vinu K. Green synthesis of zinc ferrite nanoparticles in Limonia acidissima juice: Characterization and their application as photocatalytic and antibacterial activities. Microchem J. 2019; 146: 1227-1235. https://doi.org/10.1016/j.microc.2019.02.059
Hassan AK, Atiya MA, Mahmoud ZA. Photo-Fenton-like degradation of direct blue 15 using fixed bed reactor containing bimetallic nanoparticles: Effects and Box–Behnken optimization. Environ Technol Innov. 2022; 28: 102907.https://doi.org/10.1016/j.eti.2022.102907
Abril D, Ferrer V, Mirabal-Gallardo Y, Cabrera-Bajas G, Segura C, Marican A, et al. Comparative Study of Three Dyes Adsorption onto Activated Carbon from Chenopodium quinoa Willd and Quillaja saponaria. Mater. 2022; 15(14): 4898. https://doi.org/10.3390/ma15144898
Atiya MA, Mahmoud ZA, Hassan AK. Fenton-like degradation of direct blue dye using green synthesised Fe / Cu bimetallic nanoparticles. J Environ Eng Sci. 2022; 2(9): 1-16.https://doi.org/10.1680/jenes.22.00025
Aziz EK, Abdelmajid R, Rachid LM, Haddad E. Adsorptive removal of anionic dye from aqueous solutions using powdered and calcined vegetables wastes as low-cost adsorbent. Arab J Basic Appl Sci. 2018; 25(1): 1-10. https://doi.org/10.1080/25765299.2018.1517861
Surendra BS, Nagaswarupa HP, Hemashree MU, Khanum J. Jatropha extract mediated synthesis of ZnFe2O4 nanopowder: Excellent performance as an electrochemical sensor, UV photocatalyst and an antibacterial activity. Chem Phys Lett. 2019; 739(2): 136980.https://doi.org/10.1016/j.cplett.2019.136980
Bora L V, Mewada RK. Visible/solar light active photocatalysts for organic effluent treatment: Fundamentals, mechanisms and parametric review. Renew Sustain Energy Rev. 2017; 76: 1393-1421. https://doi.org/10.1016/j.rser.2017.01.130
Park J.K, Pupa EJ, Arif MH, Li JF, Anandapadmanaban G, Kang JP, et al. Synthesis of zinc oxide nanoparticles from Gynostemma pentaphyllum extracts and assessment of photocatalytic properties through malachite green dye decolorization under UV illumination-A Green Approach. Optik. 2021; 239(8): 166249.https://doi.org/10.1016/j.ijleo.2020.166249
Yagub MT, Sen TK, Afroze S, Ang HM. NU SC. Adsorptive removal of methyl orange dye from aqueous solution using populous leaves: Insights from kinetics, thermodynamics and computational studies. Adv Colloid Interface Sci. 2014; 3(7): 172-181. https://doi.org/10.1016/j.cis.2014.04.002
Akhtar MJ, Alhadlaq HA, Alshamsan A, Khan MAM, Ahamed M. Aluminum doping tunes band gap energy level as well as oxidative stress-mediated cytotoxicity of ZnO nanoparticles in MCF-7 cells. Nat Publ Gr. 2015; 1(9): 1-16. https://doi.org/10.1038/srep13876
Khan MS, Dhavan PP, Jadhav BL, Shimpi NG. Ultrasound-Assisted Green Synthesis of Ag-Decorated ZnO Nanoparticles UsingExcoecaria agallochaLeaf Extract and Evaluation of Their Photocatalytic and Biological Activity. Chemi Eur J. 2020; 41(5): 12660-12671.https://doi.org/10.1002/slct.202002905
Puthukkara P AR, Jose T S, lal S D. Plant mediated synthesis of zero valent iron nanoparticles and its application in water treatment. J Environ Chem Eng. 2021; 9(1): 104569. https://doi.org/10.1016/j.jece.2020.104569
Raghav S, Kumar D. Adsorption Equilibrium, Kinetics, and Thermodynamic Studies of Fluoride Adsorbed by Tetrametallic Oxide Adsorbent. J Chem Eng Data. 2018; 63(5): 1682-1697. https://doi.org/10.1021/acs.jced.8b00024
Ranjith E, Jayaprakash R, Seehra MS, Prakash T, Kumar S. Effect of a -Fe2O3 phase on structural , magnetic and dielectric properties of Mn – Zn ferrite nanoparticles. J Phys Chem Solids. 2013; 74(7): 943-949. https://doi.org/10.1016/j.jpcs.2013.02.013
Selvaraj R, Pai S, Murugesan SP, Pandey S, Bhole R, Gonsalves D, et al. Green synthesis of magnetic a-Fe2O3 nanospheres using Bridelia retusa leaf extract for Fenton-like degradation of crystal violet dye. Appl Nanosci. 2021; 11(8): 2227–2234https://doi.org/10.1007/s13204-021-01952-y
Chen L, Tian J, Qiu H, Yin Y, Wang X, Dai J, et al. Preparation of TiO2 nanofilm via sol-gel process and its photocatalytic activity for degradation of methyl orange. Ceram Int. 2009; 35(8): 3275-3280. https://doi.org/10.1016/j.ceramint.2009.05.021
Lara M, Hussein A, Nguyen VQ, Kumar DR, Sayed MS, Tuma D, et al. Eco-friendly synthesis of recyclable mesoporous zinc ferrite @ reduced graphene oxide nanocomposite for efficient photocatalytic dye degradation under solar radiation. J Colloid Interface Sci. 2019; 1(5): 459-469. https://doi.org/10.1016/j.jcis.2019.11.018
Azizi S, Shahri MM, Mohamad R. Green synthesis of zinc oxide nanoparticles for enhanced adsorption of lead Ions from aqueous solutions: Equilibrium, kinetic and thermodynamic studies. Molecules. 2017; 22(6): 831. https://doi.org/10.3390/molecules22060831
Saleh TA, Al-Ruwayshid SH, Sarı A, Tuzen M. Synthesis of silica nanoparticles grafted with copolymer of acrylic acrylamide for ultra-removal of methylene blue from aquatic solutions. Eur Polym J. 2020; 130(4): 109698. https://doi.org/10.1016/j.eurpolymj.2020.109698
Zafar MN, Dar Q, Nawaz F, Zafar MN, Iqbal M, Nazar MF. Effective adsorptive removal of azo dyes over spherical ZnO nanoparticles. J Mater Res Technol. 2019; 8(1): 713-725. https://doi.org/10.1016/j.jmrt.2018.06.002
Tuzen M, Sarı A, Saleh TA. Response surface optimization, kinetic and thermodynamic studies for effective removal of rhodamine B by magnetic AC/CeO2 nanocomposite. J Environ Manage. 2018; 206: 170-177. https://doi.org/10.1016/j.jenvman.2017.10.016
Liu X, Ye L, Liu S, Li Y, Ji X. Photocatalytic reduction of CO2 by ZnO micro/nanomaterials with different morphologies and ratios of {0001} facets. Sci Rep. 2016; 6(5): 1-9. https://doi.org/10.1038/srep38474
Xiang H, Ren G, Zhong Y, Xu D, Zhang Z, Wang X, et al. Fe3O4 @ C Nanoparticles Synthesized by In Situ Solid-Phase Method for Removal of Methylene Blue. Nanomater. 2021; 11(2): 330. https://doi.org/10.3390/nano11020330
Weldegebrieal GK. Synthesis method, antibacterial and photocatalytic activity of ZnO nanoparticles for azo dyes in wastewater treatment: A review. Inorg Chem Commun. 2020; 120(6): 108140. https://doi.org/10.1016/j.inoche.2020.108140
Ullah, R, Shah S, Muhammad Z, Shah AS, Faisal S, Khattak U, et al. In vitro and in vivo applications of Euphorbia wallichii shoot extract-mediated gold nanospheres. Green Process Synth. 2021; 10(1): 101–111. https://doi.org/10.1515/gps-2021-0013
Kainat, Khan MA, Ali F, Faisal S, Rizwan M, Hussain Z, et al. Exploring the therapeutic potential of Hibiscus rosa sinensis synthesized cobalt oxide (Co3O4-NPs) and magnesium oxide nanoparticles (MgO-NPs). Saudi J Biol Sci. 2021; 28(9): 5157-5167. https://doi.org/10.1016/j.sjbs.2021.05.035
Sonal S, Mishra B K. Role of hybrid systems and their importance in the dye degradation : trend and future aspect. Elsevier, 2021; 4(2) :545–571. https://doi.org/10.1016/b978-0-12-823876-9.00002-0
Romdhane DF, Satlaoui Y, Nasraoui R, Charef A, Azouzi R. Adsorption, Modeling, Thermodynamic, and Kinetic Studies of Methyl Red Removal from Textile-Polluted Water Using Natural and Purified Organic Matter Rich Clays as Low-Cost Adsorbent. J Chem. 2020; 7(5): 2020. https://doi.org/10.1155/2020/4376173
Haryono H, Ishmayana S, Fauziyah I. Synthesis and Characterization of Calcium Oxide Impregnated on Silica from Duck Egg Shells and Rice Husks as Heterogeneous Catalysts for Biodiesel Synthesis. Baghdad Sci J. 2023; 20(5): 1976-1984. https://doi.org/10.21123/bsj.2023.7895
Downloads
Issue
Section
License
Copyright (c) 2024 Zahraa A. Najm , Mohammed A. Atiya, Ahmed K. Hassan
This work is licensed under a Creative Commons Attribution 4.0 International License.
How to Cite
