Synthesis and characterization of novel metal complexes of (pentulose-?-lactone-2,3-enedibenzoate barbituric acid) with some metal ions
محتوى المقالة الرئيسي
الملخص
New (pentulose-?-lactone-2,3-enedibenzoate barbituric acid) (L) have been synthesized by reaction of (5-C-dimethyl malonyl-pentulose-?-lactone-2,3-enedibenzoate) with urea in alkaline media (sodium methoxide). (Ca+2, Co+2, Ni+2, Cu+2, Zn+2, Cd+2 and Hg+2) complexes of (pentulose-?-lactone-2,3-enedibenzoate barbituric acid) (L) have been prepared and characterized by (1H and 13CNMR), FTIR, (U.V-Vis) spectroscopy, Atomic absorption spectrophotometer (A.A.S), Molar conductivity measurements and Magnetic moment measurements, and the following general formula has been given for the prepared complexes [MLCl2(H2O)].XH2O, where M = (Ca+2, Co+2, Ni+2, Cu+2, Zn+2, Cd+2, Hg+2), X = five molecules with (Cd+2) complex, L = (pentulose-?-lactone-2,3-enedibenzoate barbituric acid).
تفاصيل المقالة
كيفية الاقتباس
1.
Synthesis and characterization of novel metal complexes of (pentulose-?-lactone-2,3-enedibenzoate barbituric acid) with some metal ions. Baghdad Sci.J [انترنت]. 1 سبتمبر، 2013 [وثق 19 نوفمبر، 2024];10(3):597-606. موجود في: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2574
القسم
article
كيفية الاقتباس
1.
Synthesis and characterization of novel metal complexes of (pentulose-?-lactone-2,3-enedibenzoate barbituric acid) with some metal ions. Baghdad Sci.J [انترنت]. 1 سبتمبر، 2013 [وثق 19 نوفمبر، 2024];10(3):597-606. موجود في: https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/2574