تحضير وتشخيص طيفي لمعقدات العناصر الانتقالية مع قاعدة شيف 2-]1- (1H-اندول-3-يل)اثيل ايمينو)مثيل[نفثالين-1-ول
محتوى المقالة الرئيسي
الملخص
تم تحضير سلسلة جديدة من معقدات ايونات المعادن الليكاند2-[1-(1H-indol-3-yl)ethylimino)2 المشتق من1-hydroxy-2-naphthaldehyde و 2-(1H-indol-3-yl)ethylaminemethyl]naphthalene-1-olوتم تحضير معقدات احادي النواة عن طريق تفاعل الليكاند مع العناصر النيكل الثنائي والبلاديوم الثنائي والحديدوز الثلاثي وبالتتابع من المعقدات.NiCl2.6H2O, PdCl2, FeCl3 H2PtCl6.6H2Oوقد تم تشخيص المركبات عن طريق قياس الاشعة تحت الحمراء والاشعة الفوق بنفسجية واطياف الBohr Magnetic(B.M.) ,(1HNMR)وتحديد محتوى الفلز ومحتوى الكلور والموصلية المولية. وفقا للنتائج ان الاشكال الهندسية لمعقدات الحديد الثلاثي والبلاتين الرباعي ثمانية السطوح اما النيكل الثنائي رباعي السطوح والبلاديوم الثنائي فيكون مربع مستوي.
Received 28/3/2021
Accepted 6/7/2021
Published Online First 20/3/2022
تفاصيل المقالة
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كيفية الاقتباس
المراجع
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