التحضير والتشخيص والنشاط البيولوجي لمعقدات بوليمرية جديدة Co و Ni و Zn و Cd المشتقة من ليكاند Dithiocarbamate
محتوى المقالة الرئيسي
الملخص
تم تحضير فئة جديدة من ليكاند قاعدة شف حاوي على تترازول على تكوين معقدات فلزية بوليمرية مع أيونات CoII و NiII و ZnII و CdII. تم تحضير الليكاند بعدة خطوات عن طريق اضافة 5-amino-2-chlorobenzonitrile الى سايكلو هكسان -1،3-ديون للحصول على 5,5'-(((1E,3E)-cyclohexane-1,3-diylidene)bis(azanylylidene))bis(2-chlorobenzonitrile) . تم تحضير المادة الأولية (M) من تفاعل 5,5'-(((1E,3E)-cyclohexane-1,3-diylidene)bis(azanylylidene))bis(2-chlorobenzonitrile) مع NaN3 للحصول على: ((1E,3E)-N1,N3-bis(4-chloro-3-(1H-tetrazol-5-yl)phenyl)cyclohexane-1,3-diimine (N).. من خلال تفاعل المشتق (M) مع CS2 / KOH ، تم تحضير الليكاند المطلوب. تنتج أيونات ( Co II و Ni II و Zn II و Cd II) معقدات فلزية بوليمرية ذات الصيغة [[M(L) n عندما تتفاعل مع الليكاند (L). تم تحضير هذه المعقدات واستخدمت نفس الطريقة ، لتحديد هوية الليكاند ومعقداته. تم تحديد الشكل الهندسي للليكند ومعقداته البوليمرية باستخدام FTIR و NMR والتحليل الطيفي الإلكتروني وطيف الكتلة ESMS والقابلية المغناطيسية ومحتوى الفلز ومحتوى الكلوريد وتحليل العناصر الدقيقة والتوصيلة. من النتائج تبين ان الليكاند L ينتج معقدات رباعية التناسق مع شكل هندسي رباعي السطوح لـ (Co (II و (Zn (II و (Cd (II وشكل مربع مستوي لـ Ni (II). قمنا بفحص النشاط المضاد للبكتيريا لكل من الليكاند ومعقداته ضد نوعين من البكتيريا الموجبة (Bacillus stubtili and Staphylococcus aureus ) والسالبة (Escherichia coli and Pseudomonas aeruginosa ) 0.01.
Received 01/11/2022
Revised 10/02/2023
Accepted 12/02/2023
Published Online First 20/07/2023
تفاصيل المقالة
هذا العمل مرخص بموجب Creative Commons Attribution 4.0 International License.
كيفية الاقتباس
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