تحضير و تشخيص و دراسة التحلل الحراري و النشاط المضاد للاكسدة لبعض ايونات المعقدات المعدنية (Ni2+, Pt4+, Pd2+, and Mn2+) مع ليكاند ازو جديد مشتق من quinolin-2-ol و-amino-N-(5-methylisoxazol-3-yl)benzenesulfonamide
محتوى المقالة الرئيسي
الملخص
تم إجراء تفاعل الازوتة بين الكينولين -2-ol و (2-كلورو -1 (4- (N- (5-methylisoxazol-3-yl) sulfamoyl) phenyl) -2l4-diazyn-1-ium مما أدى إلى ligand-HL ، وهذا بدوره يتفاعل مع أيونات الفلزات التالية (Ni+2 ، Pt+4 ، Pd+2 + ، و Mn+2) لتشكيل معقدات مستقرة ذات أشكال هندسية فريدة مثل (رباعي السطوح لكل من Ni+2 + و Mn+2 + ، ثماني السطوح لـ Pt+4 + ومربع مستوي لـ Pd+2). تم الكشف عن المعقدات عن طريق استخدام وسائل طيفية تشمل الأشعة فوق البنفسجية التي أثبتت الأشكال الهندسية التي تم الحصول عليها ، وأثبت نقل فورييه تكوين مجموعة الآزو والتنسيق مع أيون المعدن من خلالها ، أثبتت دراسات الانحلال الحراري (TGA & DSC) تنسيق بقايا الماء مع أيونات المعادن داخل مجال التناسق وكذلك ذرات الكلور.علاوة على ذلك ، فإن التحليل الجزئي للعناصر و AAS الذي أعطى النتيجة المقابلة مع النتائج النظرية. أيون. تم تقييم الأنشطة المضادة للأكسدة لهذه المركبات ضد جذري (DPPH) وتمت مقارنتها بمضادات الأكسدة الطبيعية القياسية ، حمض الأسكوربيك. تظهر النتائج أن هذه المركبات تظهر أنشطة ممتازة في إزالة الجذور
Received 9/9/2022, Revised 28/11/2022, Accepted 30/11/2022, Published Online First 20/4/2023
تفاصيل المقالة
هذا العمل مرخص بموجب Creative Commons Attribution 4.0 International License.
كيفية الاقتباس
المراجع
Al-Daffay RK, Al-Hamdani AA. Synthesis, Characterization, and Thermal Analysis of a New Acidicazo Ligand's Metal Complexes. Baghdad Sci. J.2022;19(3):121-33. http://dx.doi.org/10.21123/bsj.2022.6709
Kakanejadifard A, Esna-ashari F, Hashemi P, Zabardasti A. Synthesis and characterization of an azo dibenzoic acid Schiff base and its Ni (II), Pb (II), Zn (II) and Cd (II) complexes. Spectrochimica Acta Part A: SAA. 2013 Apr 1;106:80-5. https://doi.org/10.1016/j.saa.2012.12.044
Benkhaya S, M'rabet S, El Harfi A. Classifications, properties, recent synthesis and applications of azo dyes. Heliyon. 2020 Jan 1;6(1):e03271. https://doi.org/10.1016/j.heliyon.2020.e03271
Ghanavatkar CW, Mishra VR, Mali SN, Chaudhari HK, Sekar N. Synthesis, bioactivities, DFT and in-silico appraisal of azo clubbed benzothiazole derivativesJ. Mol. Struct. 2019 Sep 15;1192:162-71. https://doi.org/10.1016/j.molstruc.2019.04.123
Maliyappa MR, Keshavayya J, Mallikarjuna NM, Krishna PM, Shivakumara N, Sandeep T, Sailaja K, Nazrulla MA. Synthesis, characterization, pharmacological and computational studies of 4, 5, 6, 7-tetrahydro-1, 3-benzothiazole incorporated azo dyes. J. Mol. Struct. 2019 Mar 5; 1179:630-41. https://doi.org/10.1016/j.molstruc.2018.11.041
Feng J, Zhang S, Shi W, Zhang Y. Activity of sulfa drugs and their combinations against stationary phase B. burgdorferi in vitro. J. Antibiot. 2017;6(1):10. https://doi.org/10.3390/antibiotics6010010
Das D, Sahu N, Mondal S, Roy S, Dutta P, Gupta S, Sinha C. Structures, antimicrobial activity, DNA interaction and molecular docking studies of sulfamethoxazolyl-azo-acetylacetone and its nickel (II) complex. Polyhedron. 2015; 99: 77-86. https://doi.org/10.1016/j.poly.2015.06.027
Winum JY, Maresca A, Carta F, Scozzafava A, Supuran CT. Polypharmacology of sulfonamides: pazopanib, a multitargeted receptor tyrosine kinase inhibitor in clinical use, potently inhibits several mammalian carbonic anhydrases. ChemComm. 2012; 48(66):8177-8179. https://doi.org/10.1039/C2CC33415A
Khan DA, Knowles SR, Shear NH. Sulfonamide hypersensitivity: fact and fiction. JACI: In Practice. 2019; 7(7): 2116-2123. https://doi.org/10.1016/j.jaip.2019.05.034
Dorn JM, Alpern M, McNulty C, Volcheck GW. Sulfonamide drug allergy. Curr. Allergy Asthma Rep. 2018;18(7): 1-10. https://doi.org/10.1007/s11882-018-0791-9
Tailor A, Waddington JC, Hamlett J, Maggs J, Kafu L, Farrell J, et al. Definition of haptens derived from sulfamethoxazole: in vitro and in vivo. Chem. Res. Toxicol. 2019; 32(10): 2095-2106. https://doi.org/10.1021/acs.chemrestox.9b00282
Al‐Fahemi JH, Khedr AM, Althagafi I, El‐Metwaly NM, Saad FA, Katouah HA. Green synthesis approach for novel benzenesulfonamide nanometer complexes with elaborated spectral, theoretical and biological treatments. Appl. Organomet. Chem. 2018;32(9): e4460. https://doi.org/10.1002/aoc.4460
Adnan S. Synthesis, Spectral Characterization and Anticancer Studies of Novel Azo Schiff Base And its Complexes with Ag (I), Au (lll) And Pt (lV) ions. Egypt. J. Chem. 2020 Dec 1;63(12):4749-56. 10.21608/EJCHEM.2020.23312.2438
Chohan ZH, Shad HA. Sulfonamide‐derived compounds and their transition metal complexes: synthesis, biological evaluation and X‐ray structure of 4‐bromo‐2‐[(E)‐{4‐[(3, 4‐dimethylisoxazol‐5 yl) sulfamoyl] phenyl} iminiomethyl] phenolate. Appl. Organomet. Chem. 2011; 25(8): 591-600. https://doi.org/10.1002/aoc.1807
Saad FA, El-Ghamry HA, Kassem MA, Khedr AM. Nano-synthesis, Biological Efficiency and DNA binding affinity of new homo-binuclear metal complexes with sulfa azo dye based ligand for further pharmaceutical applications. J Inorg Organomet Polym Mater. 2019; 29(4): 1337-1348. https://doi.org/10.1007/s10904-019-01098-z
Eugene-Osoikhia TT, Aleem AO, Ayeni F. Synthesis, characterisation and antimicrobial studies of mixed ligands Metal (II) complexes of sulfamethoxazole and N, N-Donors heterocycles. Fudma J. Sci. 2020;4(2): 217-232. https://doi.org/10.33003/fjs-2020-0402-179
- Hadi MA, Kareem IK. synthesis, Characterization and Spectral Studies of a new Azo-Schiff base Ligand Derived from 3, 4-diamino benzophenone and its Complexes with Selected Metal Ions. Research J. Adv. Sci. 2020 Jul 2;1(1). https://royalliteglobal.com/rjas/artic le/view/251
Al-Majidi SM, Al-Khuzaie MG. Synthesis and Characterization of New Azo Compounds Linked to 1, 8-Naphthalimide and Studying Their Ability as Acid-Base Indicators. Iraqi J. Sci. 2019 Nov 27:2341-52. https://doi.org/10.24996/ijs.2019.60.11.4
Al Zoubi W, Vian YJ, Veyan TS, Al‐Hamdani A A S, Suzan Duraid Ahmed, Yang Gon Kim et al. Synthesis and bioactivity studies of novel Schiff bases and their complexes. J. Phys. Org. Chem. 2019; e4004: 1-7. https://doi.org/10.1002/poc.4004
Moamen SR, Altalhi T, Safyah BB, Ghaferah HA, Kehkashan A. New Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Zn(II), Cd(II),and Hg(II) Gibberellate Complexes: Synthesis, Structure,and Inhibitory Activity Against COVID-19 Protease. Russ. J. Gen. Chem. 2021; 91(5): 890–896. https://doi.org/10.1134/S1070363221050194
Kadhim SM, Mahdi SM. Preparation and Characterization of New (Halogenated Azo-Schiff) Ligands with Some of their Transition Metal Ions Complexes. Iraqi J. Sci. 2022 Aug 31:3283-99. https://doi.org/10.24996/ijs.2022.63.8.4
Abd Wannas F, Azooz EA, Ridha RK, Jawad SK. Separation and micro determination of zinc (II) and cadmium (II) in food samples using cloud point extraction method. Iraqi J. Sci. 2023 Feb 28:1049-61. https://doi.org/10.24996/ijs.2023.64.3.2
Almáši M, Vilková M, Bednarčík J. Synthesis, characterization and spectral properties of novel azo-azomethine-tetracarboxylic Schiff base ligand and its Co (II), Ni (II), Cu (II) and Pd (II) complexes. Inorganica Chim. Acta. 2021 Jan 24;515:120064. https://doi.org/10.1016/j.ica.2020.120064
Salem OM, Abdelsalam A, Boroujerdi A. Bioremediation potential of Chlorella vulgaris and Nostoc paludosum on azo dyes with analysis of metabolite changes. Baghdad Sci J. 2021 Sep 1;18(3):445-54. http://dx.doi.org/10.21123/bsj.2021.18.3.0445
Kareem IK, Hadi MA. Synthesis and characterization of some transition metal complexes with new azo-schiff base ligand 3, 4-bis (((1E, 2E)-2-((2-((4-((Z)-(3-Hydroxyphenyl) Diazenyl) Naphthalen-1-yl) amino) ethyl) imino)-1, 2-Diphenylethylidene) Amino) Phenyl)(phenyl) Methanone. Egypt. J. Chem. 2020 Jan 1;63(1):301-13.10.21608/ejchem.2019.18924.2166
Ameer HA, Hussain AF. Spectrophotometric Determination of Micro Amount of Chromium (III) Using Sodium 4-((4, 5-diphenyl-imidazol-2-yl) diazenyl)-3-hydroxynaphthalene-1-sulfonate in the Presence of Surfactant, Study of Thermodynamic Functions and Their Analytical Applications. Baghdad Sci. J. 2023. https://doi.org/10.21123/bsj.2023.7393
Anitha C, Sheela CD, Tharmaraj P, Sumathi S. Spectroscopic studies and biological evaluation of some transition metal complexes of azo Schiff-base ligand derived from (1-phenyl-2, 3-dimethyl-4-aminopyrazol-5-one) and 5-((4-chlorophenyl) diazenyl)-2-hydroxybenzaldehyde. Spectrochimica Acta Part A: SAA. 2012 Oct 1;96:493-500. https://doi.org/10.1016/j.saa.2012.05.053
Kareem MJ, Al-Hamdani AAS, Ko YG, Al Zoubi W, Mohammed SG. Synthesis, characterization, and determination antioxidant activities for new Schiff base complexes derived from 2-(1H-indol-3-yl)- ethylamine and metal ion complexes. J Mol Struct. 2021; 1231(5): 1-30. https://doi.org/10.1016/j.molstruc.2020.129669
Kareem MJ, Al-Hamdani AAS, Jirjees VY, Khan ME, Allaf AW, Al Zoubi W, Preparation, spectroscopic study of Schiff base derived from dopamine and metal Ni (II), Pd (II), and Pt (IV) complexes, and activity determination as antioxidants. J Phys Org Chem. 2020; 34(3): 1-15. https://doi.org/10.1002/poc.4156
Reda SM, Al-Hamdani AA. Mn (II), Fe (III), Co (II) and Rh (III) complexes with azo ligand: Synthesis, characterization, thermal analysis and bioactivity. Baghdad Sci. J. 2022. https://doi.org/10.21123/bsj.2022.7289
Al-Hamdani AAS, Hamoodah RG. Transition metal complexes with tridentate ligand: preparation, spectroscopic characterization, thermal analysis and structural studies. Baghdad sci j. 2016; 13(4): 770-781. http://dx.doi.org/10.21123/bsj.2016.13.4.0770
Deghadi RG, Mahmoud WH, Mohamed GG. Metal complexes of tetradentate azo‐dye ligand derived from 4, 4′‐oxydianiline: Preparation, structural investigation, biological evaluation and MOE studies. Appl. Organomet. Chem. 2020 Oct;34(10):e5883.https://doi.org/10.1002/aoc.5883
Al-Muhanaa SS, Al-Khafagy AH. Preparation and Biological Activities of New Heterocyclic Azo Ligand and Some of Its Chelate Complexes. Nano Biomed. Eng. 2018 Mar 1;10(1):46-55. https://doi.org/10.5101/nbe.v10i1.p46-55 .
Aziz KA, Yousif TY. Characterization Studies on Mn (II), Co (II), Ni (II), Cu (II), Zn (II) and Cd (II) Complexes with New Ligands Derived from Anthraquinone Substance. Iraqi J. Sci. 2022 Jul 31:2804-13. https://doi.org/10.24996/ijs.2022.63.7.5
Venugopal N, Krishnamurthy G, Bhojyanaik HS, Krishna PM. Synthesis, spectral characterization and biological studies of Cu (II), Co (II) and Ni (II) complexes of azo dye ligand containing 4‒amino antipyrine moiety. J. Mol. Struct. 2019 May 5;1183:37-51. https://doi.org/10.1016/j.molstruc.2019.01.031
Mallikarjuna NM, Keshavayya J, Maliyappa MR, Ali RS, Venkatesh T. Synthesis, characterization, thermal and biological evaluation of Cu (II), Co (II) and Ni (II) complexes of azo dye ligand containing sulfamethaxazole moiety. J. Mol. Struct. 2018 Aug 5;1165:28-36. https://doi.org/10.1016/j.molstruc.2018.03.094